scholarly journals Synthesis and properties of SiO2 photonic crystals modified by DNA

Background: Photonic crystals are structures characterized by periodic modulations of the refractive index with a period commensurate with the wavelength. This periodicity is associated with the existence of a complete band gap in the spectrum of the electromagnetic states of the crystal. The stop zone is called the band gap for the highlighted direction in the crystal. Globular photonic crystals are called three-dimensional photonic crystals, which consist of the same diameter globules. The pores between the globules in the opal allow one to change the refractive index and optical contrast of the material. The task of controlling the stop-zone frequency limits of a globular photonic crystal without changing its physical structure is of practical interest. The easiest way to control the stop-zone parameters is to fill the pores of the photonic crystals with materials with different refractive indices, for example, DNA. Control of the optical parameters of a globular photonic crystal can be used for the creation of optical detectors, sensors, test systems, a quantum biocomputer as well as analyzing and studying a conformational state of DNA. Objectives: the creation of SiO2 globular photonic crystals modified by DNA and studying of the influence of DNA on their optical properties. Materials and Methods: Ethyl alcohol, distilled water, ammonium hydroxide, tetraethoxysilane and DNA were used to synthesize SiO2 photonic crystals. Aqueous DNA solution was used to infiltrate the photonic crystals. We used a visible range spectroscopy for optical experiments and a finite-difference time-domain (FDTD) method for numerical calculations. Results: SiO2 globular photonic crystals modified by DNA were synthesized with 195 nm globules. The reflection spectra of the obtained photonic crystals were measured. A red-shift of the stop-zone maximum after the infiltration of photonic crystals with DNA molecules was found. The electric field distribution was calculated for the photonic crystal with 200 nm globules. Conclusions: FDTD calculations in the linear mode show that the presence of point defects in the structure of the photonic crystal influences the amplification of the local electric field in the interglobular space of the photonic crystal, which houses the DNA molecule at infiltration. The DNA infiltration into the pores of a photonic crystal changes the effective refractive index of the system by 5.99%. Synthesis SiO2 photonic crystals with DNA leads to the formation of a more ordered structure at the macro levels. Thus, DNA serves as a template-like structure for photonic crystals to be assembled on. In this case, the effective refractive index of the system increases by 6.01%.

Nanomaterials ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 651 ◽  
Author(s):  
Ermolaev ◽  
Kushnir ◽  
Sapoletova ◽  
Napolskii

Photonic crystals based on titanium oxide are promising for optoelectronic applications, for example as components of solar cells and photodetectors. These materials attract great research attention because of the high refractive index of TiO2. One of the promising routes to prepare photonic crystals based on titanium oxide is titanium anodizing at periodically changing voltage or current. However, precise control of the photonic band gap position in anodic titania films is a challenge. To solve this problem, systematic data on the effective refractive index of the porous anodic titanium oxide are required. In this research, we determine quantitatively the dependence of the effective refractive index of porous anodic titanium oxide on the anodizing regime and develop a model which allows one to predict and, therefore, control photonic band gap position in the visible spectrum range with an accuracy better than 98.5%. The prospects of anodic titania photonic crystals implementation as refractive index sensors are demonstrated.


2015 ◽  
Vol 62 (1) ◽  
pp. 7-9 ◽  
Author(s):  
Bratati Ghosh ◽  
Shukufe Rahman ◽  
Ahsan Habib ◽  
Subrata Das

2D Photonic Crystal is investigated to find photonic band gap for the purpose of biosensing at THz frequency region. Several structures, one consisting of air holes in Si background and the others consisting of air holes filled with different analytes of having different Refractive Index (RI) in same Si background are considered. For each structure the change in photonic band gap due to the change in RI is observed and shown graphically. By comparing this plot with a standard chart of RI of different materials, any unknown biological analyte can be identified. Thus a biosensing method is developed by using the relationship between RI and band gap of photonic crystals. By comparing and calculating from the relationship; the maximum sensitivity of the developed biosensor is found to be 66.6%. DOI: http://dx.doi.org/10.3329/dujs.v62i1.21952 Dhaka Univ. J. Sci. 62(1): 7-9, 2014 (January)


Doklady BGUIR ◽  
2019 ◽  
pp. 88-94
Author(s):  
L. S. Khoroshko ◽  
A. V. Baglov ◽  
A. A. Hnitsko

The aim of the work was to study the optical properties of the one-dimensional photonic crystals from ultrathin alternating layers of titanium and silicon oxides with different order of alternating layers to form defective half-wave layers in the bulk of the photonic crystal. The layer thicknesses were optimized by the dispersion of the refractive index and it was shown that for the formation of 16-layer photonic crystal structure without a half-wave layer with a photonic band gap in the UV region, it is necessary to use layers of titanium dioxide and silicon oxide with a thickness of 28.3 and 53.2 nm, respectively. The structure of the 26-layer photonic crystal with a thickness of 2130 nm with two non-equidistant half-wave layers forming resonant transmission bands in the photonic band gap with peaks at 550 and 601 nm is proposed. Due to the dispersion of the refractive index, the ratio of the thicknesses of TiO2:SiO2 layers varies from 1:1.88 in the case of a 16-layer structure with a photonic band gap in the UV region to 1:1.5 in the case of a 26-layer structure with a photonic band gap in the visible range . The effect of a photonic crystal structure without half-wave layers on the emission spectrum of a liquid crystal display manufactured using IPS technology has been demonstrated in order to reduce the intensity of the blue component to increase the safety of the user's vision. The using of the photonic crystals with two half-wave defective layers allows to achieve complete separation of the spectrum components, which can be used to modify the spectra of large liquid crystal panels, their manufacture using AMOLED technology is a very difficult technological task even for leaders in this field.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1225
Author(s):  
Ali Atta ◽  
Mostufa M. Abdelhamied ◽  
Ahmed M. Abdelreheem ◽  
Mohamed R. Berber

In order to potentiate implementations in optical energy applications, flexible polymer composite films comprising methyl cellulose (MC), polyaniline (PANI) and silver nanoparticles (AgNPs) were successfully fabricated through a cast preparation method. The composite structure of the fabricated film was confirmed by X-ray diffraction and infrared spectroscopy, indicating a successful incorporation of AgNPs into the MC/PANI blend. The scanning electron microscope (SEM) images have indicated a homogenous loading and dispersion of AgNPs into the MC/PANI blend. The optical parameters such as band gap (Eg), absorption edge (Ed), number of carbon cluster (N) and Urbach energy (Eu) of pure MC polymer, MC/PANI blend and MC/PANI/Ag films were determined using the UV optical absorbance. The effects of AgNPs and PANI on MC polymer linear optical (LO) and nonlinear optical (NLO) parameters including reflection extinction coefficient, refractive index, dielectric constant, nonlinear refractive index, and nonlinear susceptibility are studied. The results showed a decrease in the band gap of MC/PANI/AgNPs compared to the pure MC film. Meanwhile, the estimated carbon cluster number enhanced with the incorporation of the AgNPs. The inclusion of AgNPs and PANI has enhanced the optical properties of the MC polymer, providing a new composite suitable for energy conversion systems, solar cells, biosensors, and nonlinear optical applications.


Polymers ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1316
Author(s):  
Shujahadeen B. Aziz ◽  
Muaffaq M. Nofal ◽  
Hewa O. Ghareeb ◽  
Elham M. A. Dannoun ◽  
Sarkawt A. Hussen ◽  
...  

The influence of dispersing Al-metal complex on the optical properties of PVA was investigated using UV–visible spectroscopy. Polymer composite films with various Al3+-complex amounts in the PVA matrix were arranged by solution casting technique by means of distilled water as a widespread solvent. The formation of Al3+-metal complex was verified through Ultraviolet–visible (UV-Vis) and Fourier-transform infrared spectroscopy (FTIR) examinations. The addition of Al-complex into the polymer matrix led to the recovery of the optical parameters such as dielectric constant (εr and εi) and refractive index (n). The variations of real and imaginary parts of complex dielectric constant as a function of photon wavelength were studied to calculate localized charge density values (N/m*), high-frequency dielectric constant, relaxation time, optical mobility, optical resistivity, and plasma angular frequency (ωp) of electrons. In proportion with Al3+-complex content, the N/m* values were amplified from 3.68 × 1055 kg−1 m−3 to 109 × 1055 kg−1 m−3. The study of optical parameters may find applications within optical instrument manufacturing. The optical band gap was determined from Tauc’s equation, and the type of electronic transition was specified. A remarkable drop in the optical band gap was observed. The dispersion of static refractive index (no) of the prepared composites was analyzed using the theoretical Wemple–DiDomenico single oscillator model. The average oscillator energy (Eo) and oscillator dispersion energy (Ed) parameters were estimated.


2013 ◽  
Vol 37 (1) ◽  
pp. 83-91 ◽  
Author(s):  
Chitra Das ◽  
Jahanara Begum ◽  
Tahmina Begum ◽  
Shamima Choudhury

Effect of thickness on the optical and electrical properties of gallium arsenide (GaAs) thin films were studied. The films of different thicknesses were prepared by vacuum evaporation method (~10-4 Pa) on glass substrates at a substrate temperature of 323 K. The film thickness was measured in situ by a frequency shift of quartz crystal. The thicknesses were 250, 300 and 500 nm. Absorption spectrum of this thin film had been recorded using UV-VIS-NIR spectrophotometer in the photon wavelength range of 300 - 2500 nm. The values of some important optical parameters of the studied films (absorption coefficient, optical band gap energy and refractive index; extinction co-efficient and real and imaginary parts of dielectric constant) were determined using these spectra. Transmittance peak was observed in the visible region of the solar spectrum. Here transmittance showed better result when thicknesses were being increased. The optical band gap energy was decreased by the increase of thickness. The refractive index increased by increasing thickness while extinction co-efficient and real and imaginary part of dielectric constant decreased. DOI: http://dx.doi.org/10.3329/jbas.v37i1.15684 Journal of Bangladesh Academy of Sciences, Vol. 37, No. 1, 83-91, 2013


Author(s):  
Azka Umar ◽  
Chun Jiang

This paper focuses on manipulating thermal emission and radiation loss of heat energy in a heat waveguide. A One-Dimensional Photonic Crystal is used as a waveguide clad to prohibit the thermal emission from escaping. The model may reduce the radiation loss of heat energy in the waveguide core, and heat energy can be confined to propagate along the waveguide’s longitude axis. The waveguide clad comprises alternative layers of high and low refractive index materials containing sufficient electromagnetic stop bands to trap the thermal emission from escaping out of the waveguide. The numerical simulation of the model shows that the forbidden bandgap of photonic crystal structures with alternative layers of silica and silicon has width enough to make heat energy be confined within the waveguide core so that efficient heat energy transmission can be achieved along the longitude axis of the waveguide.


2010 ◽  
Vol 39 (s1) ◽  
pp. 48-53
Author(s):  
褚博文 CHU Bo-wen ◽  
赵丽明 ZHAO Li-ming ◽  
赵静 ZHAO Jing

Open Physics ◽  
2008 ◽  
Vol 6 (3) ◽  
Author(s):  
Urszula Laudyn ◽  
Katarzyna Rutkowska ◽  
Robert Rutkowski ◽  
Mirosław Karpierz ◽  
Tomasz Woliński ◽  
...  

AbstractWe have investigated the nonlinear propagation of light in photonic crystal fibers filled with nematic liquid crystals. We analyzed a configuration with a periodic modulation of the refractive index corresponding to a matrix of waveguides. Matrices of coupled waveguides allow observing a variety of new phenomena both for low power light beam propagation and with an existence of nonlinear effects. The opportunity for the creation of solitary waves caused by the interplay between diffraction and nonlinear effects in these kinds of fibers is investigated. At low power the propagating light beam spreads as it couples to more and more waveguides. When the intensity is increased the light modifies the refractive index distribution, inducing a defect in the periodic structure. The creation of such a defect can lead to a situation in which the light becomes self-localized and its diffractive broadening is eliminated. Eventually, in the case of positive Kerr-type nonlinearity, a discrete soliton can be created. In the case of negative nonlinearity the refractive index decreases with the optical power and can lead to bandgap shifting. The incident beam, with a frequency initially within the bandgap, is then turned outside the bandgap resulting in the changing of the propagation effect for the discrete diffraction effect. As a consequence the delocalization of the light can be observed.


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