scholarly journals Integrated use of technogenic raw materials in cement technology

Author(s):  
L.P. Chernyak ◽  
L.I. Melnyk ◽  
N.O. Dorogan ◽  
I.A. Goloukh

This work used a combination of modern physico-chemical research methods with standardized testing of technological and operational properties of raw materials, clinker, cement and compositions with its application. Results over of research of the silicate systems with rice husk and ash-fly as technogenic raw material for making of cement clinker are driven. The features of the chemical-mineralogical composition, phase transformations during burning and astringent properties of material at the use of 42,5-50,5 % industry wastes in composition initial raw material mixtures are shown. The object of the study were raw material mixtures for the production of Portland cement clinker based on the systems of chalk - clay - man-made raw materials and chalk - man-made raw materials. The possibility of replacing exhaustible and non-renewable natural raw materials with a complex of multi-tonnage wastes of agro-industry and heat energy, which meets the objectives of expanding the raw material base of cement production, resource conservation and environmental protection. Peculiarities of phase formation during firing of silicate systems of chalk-polymineral clay and chalk-technogenic raw materials taking into account changes in the quantitative ratio of components, in particular rice husk and ash-removal of thermal power plants are noted.

2021 ◽  
Vol 316 ◽  
pp. 1050-1054
Author(s):  
V.N. Zyryanova ◽  
E.V. Lytkina ◽  
A.P. Ochur-Ool

Increasing water resistance and mechanical strength of hardening magnesian binders’ products can be achieved by introducing microfillings into a hardening dispersed system. It is shown that serpentine provides an increase strength and water resistance in hydration and hardening process, being as a structure-forming component, it intensifies this process. It allows expanding the raw material base for the production of magnesia binders for construction purposes.


2020 ◽  
Author(s):  
Katarina Šter ◽  
Sabina Kramar

<p>Al-rich mineral resources are one of the essential components for the production of the novel sustainable mineral binders. Belite-sulfoaluminate (BCSA) cements, which are considered as low-carbon and low-energy, allows the substitution of natural raw materials with secondary ones. In East-Southeast European countries (ESEE) there are huge amounts of various industrial and mine residues that are either landfilled or currently have a low recycling rate. These residues are generated from mining activities (mine waste) and as a by product of different types of industry, such as thermal power plants, steel plants or the aluminium industry (slags, ashes, red mud, etc.). Within the framework of the RIS-ALiCE project, in cooperation with 15 project partners from Slovenia, Austria, France, Hungary, Serbia, Bosnia and Herzegovina and Macedonia, a network of relevant stakeholders has been established in the field of currently unused aluminium-containing mine and industrial residues. Inside the created network mine and industrial residues have been mapped and valorised in order to evaluate their suitability for the use in innovative and sustainable low CO<sub>2</sub>-mineral binder production. Aluminium-containing residues are characterized with respect to their chemical, physical and radiological composition using different analytical methods such as X ray fluorescence spectroscopy, ICP optical emission spectrophotometry, gravimetry, X ray powder diffraction, gamma spectroscopy, etc. The long-term activity of network between wastes holders/producers and mineral end users will be enabled via developed Al-rich residues registry, including a study of the potential technological, economic and environmental impacts of applying the innovative methodology of the sustainable secondary raw materials management in ESEE region. Developed registry with the data valuable for both, waste providers as waste users in ESEE region, can be later-on upscaled also to other regions of Europe. It will provide the data on the available and appropriate Al-rich secondary resources, which will enablethe production of innovative low-CO<sub>2 </sub>cements.</p><p><strong>Keywords:</strong> secondary raw material, alternative binders, Al-rich residues, networking, mapping, valorisation, registry.</p>


2021 ◽  
Vol 942 (1) ◽  
pp. 012008
Author(s):  
K Plawecka ◽  
B Figiela ◽  
A Grela ◽  
K E Buczkowska

Abstract Plasma waste treatment technology is one of the promising methods of reducing problematic waste, but the technology itself create other kind of waste that must be effectively used to recognize this technology as a suitable for circular economy. The aim of the article is to show the possibility of using waste materials from a plasma incineration plant as a raw material for the production of geopolymeric materials. The samples were made based on waste from plasma incineration plant in Liberec (Czech Republic), fly ash from thermal power plants in Skawina (Poland) and sand mixed with an aqueous chemical solution. Next they mechanical properties, microstructure and mineralogical composition have been investigated. The results show the combination of these raw materials can increase the strength of the material and, consequently find applications in the utilization of plasma incineration waste. The article show the geopolymerization could be effective process for using waste materials from a plasma incineration plant as a raw material for creating the products for construction industry.


2021 ◽  
Vol 24 (6) ◽  
pp. 1271-1284
Author(s):  
L. N. Takaishvili ◽  
G. V. Agafonov

The purpose of the paper is to assess application directions and prospects of Irkutsk region power generating coals for the needs of electric and heat power engineering with regard to the possible export of elect rical energy to the countries of South-East Asia, and use as raw materials for coal chemistry needs. The research is carried out using the methods of system analysis involving analysis and synthesis, formalization and concretization, structuring and restructuring, classification. It is the first time when the category of local power generating coals is distinguished under the analysis of the balance reserves of thermal coals. Their feature is low-quality and remoteness from settlements and transportation lanes. Their resource estimate is also given – 0.54 billion tons. An estimate of the recoverable reserves of local coals is obtained: it is 260 million tons. The potential level of local coal production is calculated. A retrospect of consumption trends of regional thermal coals is given and possible application directions are considered in the long run. It is shown that the most demanded direction is the use of coals for energy needs, mainly at thermal power plants. The calculated volumes of coal consumption of two export TPPs, Mugunskaya and Ishideiskaya, are respectively 11 and 6 million tons. According to the authors' calculations, the percentage of electrical energy generation at coal -fired TPPs depending on its export variant implementation can increase by 1.5 – 2.1 times as compared with the level of 2019. Availability of significant reserves of power generating coals in the region makes them a reliable source of energy resources for the electric and thermal power industry, including the export of electrical energy and a promising raw material for the needs of coal chemistry. Potential capacity of coal mining is estimated at 50-60 million tons per year, including 6.5 million tons of local coals. Production potential of coal significantly exceeds its demand both at present and in the future.


Author(s):  
Aitkazinova Sh.A., ◽  
◽  
Bek А.А., ◽  
Derbisov K.T., ◽  
Donenbayeva N.S., ◽  
...  

Results of longstanding researches of Satbayev University scientists on the development of modified building materials to strengthen cracked mountain structures based on industrial waste are considered. Industrial processing of technogenic raw materials (enrichment and processing waste, overburden and enclosing rocks), which is similar in composition to natural and used in conventional trend, scarcely different from industrial processing of mineral raw materials. Creation of effective technologies for the processing of technogenic raw materials is an urgent task, which make it possible to obtain competitive products from it for various industries. Various methods of preparing solutions for strengthening of fractured rocks and building structures are analyzed. Research results of tailings of the Balkhash Mining and Metallurgical Combine and preparing solutions for strengthening fractured rocks and underground mining structures are presented. Rock mass strengthening in cracked areas is achieved by adding substances into the cracks, which after hardening and solidification with rocks, increase its shearing resistance characteristics. The most widespread hardening methods were cementation during mine workings (underground structures) in fractured rocks. Significance of obtained results for construction industry is in expansion and reproduction of raw material base of building materials industry through the use of Mining and metallurgical complex waste (tailings) and development of resource-saving technologies. Practical significance of work is in the detailed development of modified method for the production of building materials and products.


2019 ◽  
Vol 23 (7) ◽  
pp. 31-35
Author(s):  
M.S. Saydumov ◽  
S.-A.Y. Murtazaev ◽  
A.Kh. Alaskhanov ◽  
I.S. Dagin ◽  
M.R. Nakhayev

The results of tests of secondary construction materials derived from man-made materials are presented. The granulometric and chemical compositions of secondary products from technogenic raw materials are investigated. The analysis of local natural and man-made raw materials base of the Chechen Republic. The possibilities of using local natural raw materials (crushed stone from gravel, natural sand, gravel, gypsum, cement, etc.) in the technology of building composite materials are shown. The suitability and efficiency of the use of technogenic raw materials in concrete and mortar technology, justified by the complex economic and environmental effect of its use in the practice of building materials science, have been experimentally proved. It has been established that with the introduction of advanced innovations in the field of concrete science it is possible to produce competitive products that are not inferior to foreign analogues.


2020 ◽  
Vol 24 (4) ◽  
pp. 36-41
Author(s):  
O.A. Miryuk

There are presented the results of physicochemical studies of the composition and thermal transformations og large-tonnage wastes of beneficiation of scarnified-magnetite ores from Kazakhstan. To determine the composition of materials and thermal transformations, the following methods were used: X-ray phase analysis, differential-thermal analysis, Mцssbauer and infrared spectroscopy. There was revealed the stepwise nature of the transformation of anthropogenic material during roasting, due to polymineral composition of ore beneficiation. It has been established that the chemical-mineral characteristics of natural silicates determine the formation processes and properties of clinker phases. An integrated approach to the study of technogenic raw materials allowed not only to substantiate the possibility and expedience of using scarnified-magnetite ore beneficiation wastes in cement production, but also to determine the preference for the phase composition of cement clinker. Research result from the basis for the development of low-energy cement clinkers with a high content of belite phase.


2021 ◽  
Vol 27 (3) ◽  
pp. 16-25
Author(s):  
А. Masalimov ◽  
◽  
А. Smirnov ◽  
N. Orekhova ◽  
I. Grishin ◽  
...  

The article contains the analyse of the raw material base of magnesia raw materials in Russia and its relationship with the existing deficit of high-purity magnesium oxide. Existing and promising sources of magnesia raw materials and their distribution by regions are considered in order to discover new sources that could be involved in the enrichment processes. The existing methods of enrichment of natural magnesites and the possibility of their application for technogenic raw materials are analyzed


2006 ◽  
Vol 60 (9-10) ◽  
pp. 245-252 ◽  
Author(s):  
Zvezdana Bascarevic ◽  
Miroslav Komljenovic ◽  
Ljiljana Petrasinovic-Stojkanovic ◽  
Natasa Jovanovic ◽  
Aleksandra Rosic ◽  
...  

In this paper the results of the investigated properties of fly ash from four thermal power plants in Serbia are presented. The physical, chemical, mineralogical and thermal characterization of fly ash was carried out, in order to determine the possibility to utilize this material in the building materials industry, foremost in the cement industry. It was determined that, although there are differences concerning the physical, chemical, and mineralogical characteristics of the investigated samples, they are very similar concerning their thermal characteristics. It was concluded that using fly ash as one of the raw components in the mixture for Portland cement clinker synthesis, not only enables the substitution of natural resources, but it might have a positive effect on the lowering of the sintering temperature.


2013 ◽  
Vol 652-654 ◽  
pp. 2570-2575 ◽  
Author(s):  
Jun Min Sun ◽  
Ping Chen

High-alumina fly ash in central and western regions of Inner Mongolia is a very valuable renewable mineral resource resulting from the content of Al2O3 up to 50% and some available elements, such as gallium, titanium and light rare earth. According to the resource characteristics of high-alumina fly ash and the market demand of the non-ferrous metals and chemical products in national economic development, a technique route was researched and developed, which included high-alumina fly ash as the main raw material, extraction of alumina co-generated with active calcium silicate (chemical packing) and calcium silicon slag cement clinker. It is the process characteristics that according to the development concept about circular economy, making full use of fly ash and recycling water as sewage disposal from thermal power plants, calcium carbide slag from chemical plants and other disused resources, and achieving the separation of alumina and silica and their respective resource utilization.


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