scholarly journals Geopolymers based on plasma incineration waste as a material for circular economy

2021 ◽  
Vol 942 (1) ◽  
pp. 012008
Author(s):  
K Plawecka ◽  
B Figiela ◽  
A Grela ◽  
K E Buczkowska

Abstract Plasma waste treatment technology is one of the promising methods of reducing problematic waste, but the technology itself create other kind of waste that must be effectively used to recognize this technology as a suitable for circular economy. The aim of the article is to show the possibility of using waste materials from a plasma incineration plant as a raw material for the production of geopolymeric materials. The samples were made based on waste from plasma incineration plant in Liberec (Czech Republic), fly ash from thermal power plants in Skawina (Poland) and sand mixed with an aqueous chemical solution. Next they mechanical properties, microstructure and mineralogical composition have been investigated. The results show the combination of these raw materials can increase the strength of the material and, consequently find applications in the utilization of plasma incineration waste. The article show the geopolymerization could be effective process for using waste materials from a plasma incineration plant as a raw material for creating the products for construction industry.

2020 ◽  
Author(s):  
Katarina Šter ◽  
Sabina Kramar

<p>Al-rich mineral resources are one of the essential components for the production of the novel sustainable mineral binders. Belite-sulfoaluminate (BCSA) cements, which are considered as low-carbon and low-energy, allows the substitution of natural raw materials with secondary ones. In East-Southeast European countries (ESEE) there are huge amounts of various industrial and mine residues that are either landfilled or currently have a low recycling rate. These residues are generated from mining activities (mine waste) and as a by product of different types of industry, such as thermal power plants, steel plants or the aluminium industry (slags, ashes, red mud, etc.). Within the framework of the RIS-ALiCE project, in cooperation with 15 project partners from Slovenia, Austria, France, Hungary, Serbia, Bosnia and Herzegovina and Macedonia, a network of relevant stakeholders has been established in the field of currently unused aluminium-containing mine and industrial residues. Inside the created network mine and industrial residues have been mapped and valorised in order to evaluate their suitability for the use in innovative and sustainable low CO<sub>2</sub>-mineral binder production. Aluminium-containing residues are characterized with respect to their chemical, physical and radiological composition using different analytical methods such as X ray fluorescence spectroscopy, ICP optical emission spectrophotometry, gravimetry, X ray powder diffraction, gamma spectroscopy, etc. The long-term activity of network between wastes holders/producers and mineral end users will be enabled via developed Al-rich residues registry, including a study of the potential technological, economic and environmental impacts of applying the innovative methodology of the sustainable secondary raw materials management in ESEE region. Developed registry with the data valuable for both, waste providers as waste users in ESEE region, can be later-on upscaled also to other regions of Europe. It will provide the data on the available and appropriate Al-rich secondary resources, which will enablethe production of innovative low-CO<sub>2 </sub>cements.</p><p><strong>Keywords:</strong> secondary raw material, alternative binders, Al-rich residues, networking, mapping, valorisation, registry.</p>


Author(s):  
L.P. Chernyak ◽  
L.I. Melnyk ◽  
N.O. Dorogan ◽  
I.A. Goloukh

This work used a combination of modern physico-chemical research methods with standardized testing of technological and operational properties of raw materials, clinker, cement and compositions with its application. Results over of research of the silicate systems with rice husk and ash-fly as technogenic raw material for making of cement clinker are driven. The features of the chemical-mineralogical composition, phase transformations during burning and astringent properties of material at the use of 42,5-50,5 % industry wastes in composition initial raw material mixtures are shown. The object of the study were raw material mixtures for the production of Portland cement clinker based on the systems of chalk - clay - man-made raw materials and chalk - man-made raw materials. The possibility of replacing exhaustible and non-renewable natural raw materials with a complex of multi-tonnage wastes of agro-industry and heat energy, which meets the objectives of expanding the raw material base of cement production, resource conservation and environmental protection. Peculiarities of phase formation during firing of silicate systems of chalk-polymineral clay and chalk-technogenic raw materials taking into account changes in the quantitative ratio of components, in particular rice husk and ash-removal of thermal power plants are noted.


2021 ◽  
Vol 24 (6) ◽  
pp. 1271-1284
Author(s):  
L. N. Takaishvili ◽  
G. V. Agafonov

The purpose of the paper is to assess application directions and prospects of Irkutsk region power generating coals for the needs of electric and heat power engineering with regard to the possible export of elect rical energy to the countries of South-East Asia, and use as raw materials for coal chemistry needs. The research is carried out using the methods of system analysis involving analysis and synthesis, formalization and concretization, structuring and restructuring, classification. It is the first time when the category of local power generating coals is distinguished under the analysis of the balance reserves of thermal coals. Their feature is low-quality and remoteness from settlements and transportation lanes. Their resource estimate is also given – 0.54 billion tons. An estimate of the recoverable reserves of local coals is obtained: it is 260 million tons. The potential level of local coal production is calculated. A retrospect of consumption trends of regional thermal coals is given and possible application directions are considered in the long run. It is shown that the most demanded direction is the use of coals for energy needs, mainly at thermal power plants. The calculated volumes of coal consumption of two export TPPs, Mugunskaya and Ishideiskaya, are respectively 11 and 6 million tons. According to the authors' calculations, the percentage of electrical energy generation at coal -fired TPPs depending on its export variant implementation can increase by 1.5 – 2.1 times as compared with the level of 2019. Availability of significant reserves of power generating coals in the region makes them a reliable source of energy resources for the electric and thermal power industry, including the export of electrical energy and a promising raw material for the needs of coal chemistry. Potential capacity of coal mining is estimated at 50-60 million tons per year, including 6.5 million tons of local coals. Production potential of coal significantly exceeds its demand both at present and in the future.


2021 ◽  
Author(s):  
Petrica Vizureanu ◽  
Dumitru Doru Burduhos Nergis ◽  
Andrei Victor Sandu ◽  
Diana Petronela Burduhos Nergis ◽  
Madalina Simona Baltatu

Mine tailings are waste materials that resulted from the extraction and processing of raw materials to form mineral products. These dusty particles present negative environmental effects after being deposited in different types of dumping areas. Based on the circular economy concepts and the presently pushing need of identifying wastes as a potential replacement for natural resources, this chapter aims to present the physical (density, microstructure) and mechanical (compressive strength, flexural strength) characteristics of different types of geopolymers which use mine tailings as precursors or blended systems (mixes of different raw materials). The main reasons of approaching this topic are the need to decrease the consumption of natural resources, reduce environmental pollution and create an economic system aimed to capitalize the mining wastes. Accordingly, this chapter includes information regarding the availability of this waste and its potential utilization as a raw material in civil engineering applications. Therefore, reports of specific agencies and multiple research studies which approach tailing based geopolymers or blended systems have been summarized.


Author(s):  
Suchismita Satapathy

All companies are dependent on their raw material providers. The same applies in the case of thermal power plants. The major raw material for a thermal power plant is the coal. There are a lot of companies which in turn provide this coal to the thermal power plant. Some of these companies are international; some are local, whereas the others are localized. The thermal power plants look into all the aspects of the coal providing company, before settling down for a deal. Some people are specifically assigned to the task of managing the supply chain. The main motive is to optimize the whole process and achieve higher efficiency. There are a lot of things which a thermal power plant looks into before finalizing a deal, such as the price, quality of goods, etc. Thus, it is very important for the raw material providers to understand each and every aspect of the demands of the thermal power plant. A combination of three methods—Delphi, SWARA, and modified SWARA—has been applied to a list of factors, which has later been ranked according to the weight and other relevant calculations.


2019 ◽  
Vol 9 (9) ◽  
pp. 1964 ◽  
Author(s):  
Dinh-Hieu Vu ◽  
Hoang-Bac Bui ◽  
Bahareh Kalantar ◽  
Xuan-Nam Bui ◽  
Dinh-An Nguyen ◽  
...  

Coal-fired power stations are one of the primary sources of power generation in the world. This will produce considerable amounts of fly ash from these power stations each year. To highlight the potential environmental hazards of these materials, this study is carried out to evaluate the characterization of fly ashes produced in thermal power plants in northern Vietnam. Fly ash was firstly fractionated according to size, and the fractions were characterized. Then, each of these fractions was analyzed with regard to their mineralogical features, morphological and physicochemical properties. The analytical results indicate a striking difference in terms of the characteristics of particles. It was found that magnetic fractions are composed of magnetite hematite and, to a lower rate, mullite, and quartz. Chemical analyses indicate that the non-magnetic components mainly consist of quartz and mullite as their primary mineral phases. As the main conclusion of this research, it is found that the magnetic and non-magnetic components differ in terms of shape, carbon content and mineralogical composition. In addition, it was found that magnetic components can be characterized as more spheroidal components compared to non-magnetic ones. This comprehensive characterization not only offers a certain guideline regarding the uses of different ash fractions but it will also provide valuable information on this common combustion process.


2020 ◽  
Vol 8 ◽  
Author(s):  
Duygu Karabelli ◽  
Steffen Kiemel ◽  
Soumya Singh ◽  
Jan Koller ◽  
Simone Ehrenberger ◽  
...  

The growing number of Electric Vehicles poses a serious challenge at the end-of-life for battery manufacturers and recyclers. Manufacturers need access to strategic or critical materials for the production of a battery system. Recycling of end-of-life electric vehicle batteries may ensure a constant supply of critical materials, thereby closing the material cycle in the context of a circular economy. However, the resource-use per cell and thus its chemistry is constantly changing, due to supply disruption or sharply rising costs of certain raw materials along with higher performance expectations from electric vehicle-batteries. It is vital to further explore the nickel-rich cathodes, as they promise to overcome the resource and cost problems. With this study, we aim to analyze the expected development of dominant cell chemistries of Lithium-Ion Batteries until 2030, followed by an analysis of the raw materials availability. This is accomplished with the help of research studies and additional experts’ survey which defines the scenarios to estimate the battery chemistry evolution and the effect it has on a circular economy. In our results, we will discuss the annual demand for global e-mobility by 2030 and the impact of Nickel-Manganese-Cobalt based cathode chemistries on a sustainable economy. Estimations beyond 2030 are subject to high uncertainty due to the potential market penetration of innovative technologies that are currently under research (e.g. solid-state Lithium-Ion and/or sodium-based batteries).


2018 ◽  
Vol 276 ◽  
pp. 110-115
Author(s):  
Martin Ťažký ◽  
Martin Labaj ◽  
Rudolf Hela

The by-products of energy industry are nowadays often affected by new limits governing the production of harmful gases discharged into the air. These stricter and stricter criteria are often met by electricity producers by changing the combustion process in thermal power plants itself. Nowadays, the SNCR (selective non-catalytic reduction) application is quite common in the combustion process in order to help reduce the nitrogen oxide emission. This article deals with the primary measures of thermal power plants, which in particular consist of a modified treatment of raw materials (coal) entering the combustion process. These primary measures then often cause the formation of fly ash with unsuitable fineness for the use in concrete according to EN 450. The paper presents the comparison of the physico-mechanical parameters of several fly ashes with a different fineness values. The primary task is to assess the impact of non-suitable granulometry in terms of EN 450 on the other physico-mechanical parameters of fly ashes sampled within the same thermal power plant. Several fly ashes produced in the Czech Republic and surrounding countries were evaluated in this way.


Metals ◽  
2020 ◽  
Vol 10 (3) ◽  
pp. 316 ◽  
Author(s):  
Denis Werner ◽  
Urs Alexander Peuker ◽  
Thomas Mütze

The recycling of spent lithium-ion batteries (LIB) is becoming increasingly important with regard to environmental, economic, geostrategic, and health aspects due to the increasing amount of LIB produced, introduced into the market, and being spent in the following years. The recycling itself becomes a challenge to face on one hand the special aspects of LIB-technology and on the other hand to reply to the idea of circular economy. In this paper, we analyze the different recycling concepts for spent LIBs and categorize them according to state-of-the-art schemes of waste treatment technology. Therefore, we structure the different processes into process stages and unit processes. Several recycling technologies are treating spent lithium-ion batteries worldwide focusing on one or several process stages or unit processes.


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