scholarly journals Variation of the Hydraulic Conductivity of Clayey Soils in Exposure to Organic Permeants

2017 ◽  
Vol 3 (11) ◽  
pp. 1036 ◽  
Author(s):  
Hanane Mortezaei ◽  
Mehran Karimpour Fard
Keyword(s):  
Dielectric Constant ◽  
Water Content ◽  
Double Layer ◽  
Clayey Soils ◽  
Contamination Control ◽  
Clay Particles ◽  
Soil Plasticity ◽  
Low Dielectric ◽  
Constant Head ◽  
Constant Head Method

Clayey soils are the most common material used in waterproofing and play an essential role in waste and contamination control. Permeability is a key parameter in such problems and its determination is needed in ensuring the satisfactory performance of the soil. Research has shown that a permeant fluid with a low dielectric constant can shrink the double layer around the clay particles which will, in turn, increase the permeability of the soil. In this paper, the permeability of two types of clay with different plasticity, exposed to the flow of water and methanol as polar and miscible solvents and gasoline and car oil as non-polar and immiscible solvents is investigated. In addition, the effect of soil properties such as plasticity and compaction water content on permeability of the samples is examined. To this end, soil samples are prepared and compacted at various water contents. Then, permeability tests are conducted according to the modified constant head method and the effects of parameters such as the fluid dielectric constant, water content of the samples and soil plasticity are examined. The results demonstrate that the lower dielectric constant of the organic fluid decreases the thickness of the double layer, providing more space for the flow of the permeant and as a result, the permeability of the clay increases. The reduction of the permeant dielectric constant from 80.4 to 2.28 led to a remarkable increase in soil permeability.

Influence of temperature on the hydrothermal clay soils' shear strength of the Nizhne-Koshelevsky and Verkhne-Pauzhetsky thermal fields.

2021 ◽  
Author(s):  
Ruslan Kuznetsov ◽  
Mikhail Chernov ◽  
Victoria Krupskaya ◽  
Ruslan Khamidov
Keyword(s):  
Internal Friction ◽  
Double Layer ◽  
Electric Double Layer ◽  
Geothermal Field ◽  
The Other ◽  
Clay Soils ◽  
Clayey Soils ◽  
Clay Particles ◽  
Angle Of Internal Friction ◽  
Thermal Fields

<p>Nizhne-Koshelevskoe and Verkhne-Pauzhetskoe thermal fields are located in the south of Kamchatka, the first - within the Koshelevsky volcanic massif, the second - on the territory of the Pauzhetsky geothermal field. The first horizon from the surface in these fields is formed by clayey soils, that have been formed as a result of hydrothermal alteration of volcanic rocks. And in the natural conditions clayey soils are at temperatures reaching 100 °C.</p><p>Samples of undisturbed clay soils were taken within the thermal fields. The samples are characterized by a density of 1.29 - 1.42 g/cm<sup>3</sup>, rather high values of the weight moisture (90-110%), and temperatures of 50 - 70 °C.</p><p>The samples are dominated by clay minerals: kaolinite and mixed-layer - kaolinite-smectite, their content is about 75%. The other 25% are microcline, cristobalite, anatase, gypsum, pyrite, marcasite, quartz and alunite.</p><p>For samples of undisturbed clay soils, direct shear tests were carried out at a temperature of 20 °C and at a temperatures of the samples close to their natural temperatures (50–70 °C). Thus, the values of cohesion and the angle of internal friction of the samples were determined.</p><p>The obtained results can be interfered as follows: as a result of an increase in the temperature of clayey soils, the thickness of electric double layer on the surface of clay particles decreases. On the one hand, it leads to a decrease of cohesion value between the clay particles and the beginning of shear deformations at lower vertical loads. On the other hand, a smaller thickness of electric double layer brings particles closer to each other, which is the reason for an increasing angle of internal friction and shear resistance at higher vertical loads.</p>

Viscosity and dielectric constant controls on the hydraulic conductivity of clayey soils permeated with water-soluble organics

1988 ◽  
Vol 25 (3) ◽  
pp. 582-589 ◽  
Author(s):  
F. Fernandez ◽  
R. M. Quigley
Keyword(s):  
Dielectric Constant ◽  
Hydraulic Conductivity ◽  
Double Layer ◽  
Pore Space ◽  
Water Soluble ◽  
Organic Liquids ◽  
Clayey Soils ◽  
Compacted Clay ◽  
High Concentrations ◽  
Water Saturated

Water-soluble organic liquids may, under some circumstances, dramatically increase the hydraulic conductivity, k, of water-saturated clayey soils, thus destroying their effectiveness as barriers for contaminants. Double-layer contraction at constant void ratio with resultant increases in the pore space available for flow has been identified as a primary mechanism for such increases in k. This paper shows, however, that the increased viscosity of solutions of some organics in water results in significant decreases in k.Pure alcohols (ethanol and methanol) and other water solubles (dioxane) when permeated through water-compacted clay samples produce an initial decrease in k, followed by a gradual increase to equilibrium values. The "hydrocarbon" front raises the viscosity of the pore fluid and causes an initial drop in k. Tests using aqueous solutions of ethanol and dioxane show decreases in k at concentrations up to ~70%. Only at high concentrations does the dielectric constant, double-layer effect overcome the viscosity effect and produce net increases in k.Effective stresses σ′vof 160 kPa during permeation with ethanol and dioxane prevent the increases in k. Physicochemically induced consolidation and increased K0-shearing effects that close shrinkage cracks are operative. Key words: hydraulic conductivity, liquid hydrocarbons, clay, viscosity, dielectric constant.

Modification of Low ĸ Materials for ULSI Multilevel Interconnects by Ion Implantation

2002 ◽  
Vol 716 ◽  
Author(s):  
Alok Nandini ◽  
U. Roy ◽  
A. Mallikarjunan ◽  
A. Kumar ◽  
J. Fortin ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Ion Implantation ◽  
Dielectric Materials ◽  
Dramatic Improvement ◽  
Force Microscopy ◽  
Low Dielectric ◽  
Quantitative Measurements ◽  
Hardness Increase ◽  
Xerogel Films ◽  
Ion Species

AbstractThin films of low dielectric constant (κ) materials such as Xerogel (ĸ=1.76) and SilkTM (ĸ=2.65) were implanted with argon, neon, nitrogen, carbon and helium with 2 x 1015 cm -2 and 1 x 1016 cm -2 dose at energies varying from 50 to 150 keV at room temperature. In this work we discuss the improvement of hardness as well as elasticity of low ĸ dielectric materials by ion implantation. Ultrasonic Force Microscopy (UFM) [6] and Nano indentation technique [5] have been used for qualitative and quantitative measurements respectively. The hardness increased with increasing ion energy and dose of implantation. For a given energy and dose, the hardness improvement varied with ion species. Dramatic improvement of hardness is seen for multi-dose implantation. Among all the implanted ion species (Helium, Carbon, Nitrogen, Neon and Argon), Argon implantation resulted in 5x hardness increase in Xerogel films, sacrificing only a slight increase (∼ 15%) in dielectric constant.

Skin–core structured fluorinated MWCNTs: a nanofiller towards a broadband dielectric material with a high dielectric constant and low dielectric loss

2018 ◽  
Vol 6 (9) ◽  
pp. 2370-2378 ◽  
Author(s):  
Yang Liu ◽  
Cheng Zhang ◽  
Benyuan Huang ◽  
Xu Wang ◽  
Yulong Li ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
High Dielectric Constant ◽  
Dielectric Material ◽  
Epoxy Composite ◽  
Low Dielectric ◽  
High Dielectric

A novel skin–core structured fluorinated MWCNT nanofiller was prepared to fabricate epoxy composite with broadband high dielectric constant and low dielectric loss.

scholarly journals Debye-Hückel Free Energy of an Electric Double Layer with Discrete Charges Located at a Dielectric Interface

Membranes ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 129
Author(s):  
Guilherme Volpe Bossa ◽  
Sylvio May
Keyword(s):  
Free Energy ◽  
Double Layer ◽  
Electric Double Layer ◽  
Low Dielectric Constant ◽  
Surface Charges ◽  
Dielectric Interface ◽  
Charge Densities ◽  
Low Dielectric ◽  
Poisson Boltzmann ◽  
The Continuum

Poisson–Boltzmann theory provides an established framework to calculate properties and free energies of an electric double layer, especially for simple geometries and interfaces that carry continuous charge densities. At sufficiently small length scales, however, the discreteness of the surface charges cannot be neglected. We consider a planar dielectric interface that separates a salt-containing aqueous phase from a medium of low dielectric constant and carries discrete surface charges of fixed density. Within the linear Debye-Hückel limit of Poisson–Boltzmann theory, we calculate the surface potential inside a Wigner–Seitz cell that is produced by all surface charges outside the cell using a Fourier-Bessel series and a Hankel transformation. From the surface potential, we obtain the Debye-Hückel free energy of the electric double layer, which we compare with the corresponding expression in the continuum limit. Differences arise for sufficiently small charge densities, where we show that the dominating interaction is dipolar, arising from the dipoles formed by the surface charges and associated counterions. This interaction propagates through the medium of a low dielectric constant and alters the continuum power of two dependence of the free energy on the surface charge density to a power of 2.5 law.

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