scholarly journals DISTRIBUTION OF SEVERAL HEAVY METALS (Cu, Zn, Ni, Co, Cr, Pb, Fe AND Mn) IN SURFACE LAYER OF B SEDIMENTS OF THE MIDDLE AND SOUTHERN CASPIAN SEA

2019 ◽  
Vol 47 (5) ◽  
pp. 26-51
Author(s):  
V. V. Gordeev ◽  
N. V. Kozina ◽  
G. N. Baturin

Atomic absorption determinations of a group of heavy metals (Cu, Zn, Ni, Co, Cr, Pb, Fe, Mn) in 190 samples of surface bottom sediments of the Middle and Southern Caspian Sea that were sampled by crab in middle of XX century (the collection of G.N. Baturin) and in 30 samples of recent sampling by grab also (2012–2015) were carried out. The aim of the investigations was to construct the schematic maps of heavy metal distribution in bottom sediments of both parts of the Caspian Sea on the materials of a half of century prescription that may serve as a base for comparison with the data of recent researches in frameworks of the program “The Caspian Sea System” under leadership of academic A.P.Lisitzin from 2012 till present time. The comparison between chemical composition of old and new sediment samples was realized, their similarities and divergences were revealed and probable reasons of divergences were presented. The maps of distribution of several metals (Fe, Mn, Co, Cr) are submitted together with necessary for interpretation maps of CaCO3, Corg and some other. It was shown that the structure of maps for all metals investigated was very similar because all these metals had concern to the group of iron.

2019 ◽  
Vol 14 (3) ◽  
pp. 138-143
Author(s):  
V. A. Chaplygin ◽  
T. S. Ershova ◽  
V. F. Zaitsev

Aim. Identification of metal transference characteristics in components of the ecosystem of the north‐western part of the Caspian Sea.   Material and Methods. Sampling was carried out according to generally accepted  methods and the determination of heavy metals was carried out by atomic absorption spectroscopy using an atomic absorption spectrometer with electro‐thermal  atomization MGA‐915 MD.   Results. In studying the migration of trace elements in the trophic chains of the  Caspian Sea sturgeon species it was found that: (a) chromium, manganese and iron  do not accumulate along the trophic chain researched; (b) accumulation of lead and  cobalt above the trophic level occupied by benthic invertebrates did not occur; (c)  cadmium, nickel and copper were accumulated primarily by benthic organisms,  while cadmium and nickel accumulated in the kidneys of Russian and Persian sturgeons and copper accumulated in the liver of both species (d) bioaccumulation of  zinc occurs sequentially in the links: soil‐water‐benthic invertebrates‐benthophage  fish (in Russian and Persian sturgeons in their kidneys, liver and muscles) and (e)  mercury migrates along the links of the food chain, accumulation coefficients increasing progressively in the system: soil‐Didacna mollusc‐benthophage fish (in  Russian and Persian sturgeons in their kidneys, liver and muscles).   Conclusion. The accumulation of heavy metals from water amongst aquatic organisms depends on the properties of the metal, its involvement in biochemical processes, species, biological status and the nature of abiotic living conditions. 


Author(s):  
Marcin Frankowski ◽  
Mariusz Sojka ◽  
Anetta Zioła-Frankowska ◽  
Marcin Siepak ◽  
Sadżide Murat-Błażejewska

Distribution of heavy metals in the Mała Wełna River system (western Poland)This paper reports the results of measurements of heavy metal concentrations in water, suspension, and bottom sediment samples collected at eight sites along the Mała Wełna River (western Poland). The samples were collected once a month from May to August 2006. The highest variations in the water of the Mała Wełna River were noted in the concentrations of Zn, Pb, and Cu. The results indicate that the suspension plays an important role in the transportation of pollutants contaminating the water and later in the accumulation of pollutants in the bottom sediments. The concentration of heavy metals in the bottom sediments were determined individually in grain size fractions: >2, 2-1, 1-0.5, 0.5-0.25, 0.25-0.1, 0.1-0.063, <0.063 mm. Concentrations of them were the lowest in the 0.5-0.25 and 0.25-0.1 mm fractions, and were the highest in the 0.1-0.063 and <0.063 fractions.


Author(s):  
Ngo The Cuong ◽  
Tran Hoan Quoc ◽  
Svetlana Vasilievna Zolotokopova

The article focuses on the study of change of containing heavy metals (zinc, copper, iron, cadmium, lead, arsenic) in the abiotic and biotic components of the Serepok river (Vietman) influenced by wastewater discharge from industrial areas. Heavy metal content was determined in the river water and bottom sediments in the four zones: above and within the boundaries of industrial regions Xoa Phu and Tam Thang and in two water reservoirs situated below the boundaries of those industrial areas. Tilapia Galilean ( Sarotherodon galilaeus ), Hemibagrus ( Hemibagrus ), and sazan ( Cyprinus carpio ) caught in these areas were the hydrobionts under study in which liver, gills, skeleton and muscles accumulation of heavy metals was detected. In the organs of fish caught in the river within industrial region, heavy metals concentration was 3-7 times higher. The greatest concentration of heavy metals was found in the liver and gills of fish caught in the boundaries of industrial regions, the least concentration was in the muscles. In most cases, significant correlation between heavy metal concentration in organs of fishes and in river water, bottom sediments has been revealed.


Author(s):  
N Derugina ◽  
N Derugina ◽  
А Grigoriev ◽  
A Grigoriev ◽  
Дарья Рябчук ◽  
...  

This project defines the pre-industrial quantities of heavy metals in sediment sequences of the Late Holocene from the Eastern Gulf of Finland. A comparative analysis reveals differences and similarities in the current concentrations of heavy metals in bottom sediments and pre-industrial levels. It is found that the maximum concentrations of heavy metals in the bottom sediments of the Gulf of Finland and Neva Bay occurred in the period of 1950-1990. Since the 1990s, the trend has been a slow decline in the contamination levels; however, the concentrations of some heavy metals in bottom sediments remain high.


2003 ◽  
Vol 2 (3) ◽  
pp. 575-591
Author(s):  
Hooman Peimani

AbstractThe absence of an acceptable legal regime for the division of the Caspian Sea among its five littoral states has created grounds for conflicts, crises, and wars in the Caspian region, a situation worsened since 2001 when Iran, Azerbaijan, and Turkmenistan found each other on a collision course over the ownership of certain offshore oilfields. The region has since been heading towards militarization, while the persistence of conflicts over the Caspian Sea's division has prepared the ground for military conflicts. Fear of lagging behind in an arms and the manipulation of conflicts by the United States and Turkey have further encouraged militarization. Against this background, certain factors, including Turkey's efforts to deny Iran political and economic gains in the Caspian region, the growing American military presence in Eurasia, and the expanding American-Azeri military ties since 11 September 2001 will likely contribute to the creation of a suitable ground for a military conflict in the Caspian region.


2017 ◽  
Vol 17 (2) ◽  
pp. 131
Author(s):  
Emas Agus Prastyo Wibowo ◽  
Ika Sri Hardyanti ◽  
Isni Nurani ◽  
Dyan Septyaningsih Hardjono HP ◽  
Aden Dhana Rizkita

STUDI PENURUNAN KADAR LOGAM BESI (Fe) DAN LOGAM TEMBAGA (Cu) PADA AIR EMBUNG MENGGUNAKAN ADSORBEN NANOSILIKAABSTRAKPolusi limbah logam berat dalam air merupakan satu permasalahan lingkungan yang penting. Dalam mengatasi permasalahan tersebut dapat dilakukan purifikasi terhadap air tersebut. Metode yang dapat digunakan untuk purifikasi limbah sangat beragam salah satunya adalah absorpsi. Secara umum metode absorpsi telah banyak digunakan dalam purifikasi air limbah. Metode absorpsi dapat menurunkan kadar logam yang terlarut pada limbah. cair dengan cara menyerap logam-logam tersebut ke dalam permukaan absorbennya. Tujuan dilakukan penelitian ini adalah  untuk menurunkan konsentrasi logam besi (Fe) dan tembaga (Cu) menggunakan adsorben nanosilika. Penelitian ini menggunakan variabel bebas yaitu waktu pengadukan (20 menit, 40 menit, dan 60 menit). Hasil akhir filtrat air embung kemudian diukur absorbansinya menggunakan Spektrofotometer Serapan Atom. Berdasarkan hasil analisa menggunakan instrumen SSA diperoleh hasil bahwa tidak terjadi penurunan logam Fe maupun Cu. Dalam hal ini terjadi peningkatan konsentrasi dalam logam Fe maupun Cu, hal ini dikarenakan kurangnya waktu pengadukan dan pengaruh dari adsorben nanosilika.Kata Kunci: limbah, logam berat, nanosilika STUDY OF DECREASING METALS IRON (Fe) AND COPPER (Cu) ON EMBUNG WATER USE OF NANOSILICA ADSORBEN ABSTRACTHeavy waste pollution of heavy metals in the water is an important environment issue. To solve the problem, its can be purified the water. The methods that can be used for waste purification are very diverse, one of which is absorption. In general, the method of absorption has been widely used in wastewater purification. The absorption method can decrease dissolved metal content in the waste. liquid by absorbing the metals into the absorbent surface. Research has been conducted to reduce the concentration of iron (Fe) and copper (Cu) by using nanosilica adsorbent. This research used to independent variable that is stirring time (20 minutes, 40 minutes, and 60 minutes). The final result of filtrate embung water then measured its absorbance using Atomic Absorption Spectrophotometer (AAS). Based on the result of the analysis using SSA instrument, it is found that there is no decrease of Fe and Cu metals. There are several reasons for those problem such as due to lack of stirring time and the influence of nanosilica adsorbent.Keywords: Waste pollution, heavy metal, nanosilica


2015 ◽  
Vol 18 (1) ◽  
Author(s):  
Endang Supriyantini ◽  
Hadi Endrawati

Logam berat Fe merupakan logam berat essensial yang keberadaannya dalam jumlah tertentu sangat dibutuhkan oleh organisme hidup, namun dalam jumlah yang berlebih dapat menimbulkan efek racun.Penelitian ini bertujuan untuk menganalisis kandungan dan tingkat pencemaran logam berat Fe pada air, sedimen, dan kerang hijau (Perna viridis) di perairan Tanjung Emas Semarang. Penelitian ini dilaksanakan pada tanggal 7 November dan 7 Desember 2013 dengan metode penelitian deskriptif. Logam berat Fe dalam sampel air, sedimen dan kerang hijau dianalisis di Laboratorium Balai Besar Teknologi Pencegahan Pencemaran Industri (BTPPI) Semarang dengan menggunakan metode AAS (AtomicAbsorption Spectrophotometry). Hasil penelitian menunjukkan bahwa perairan Tanjung Emas masih dalam taraf terkontaminasi logam Fe. Sedangkan pada sedimen dan pada kerang hijau (Perna viridis) sudah terindikasi tercemar logam Fe.Meskipun demikian variasi faktor lingkungan seperti suhu, salinitas, pH, kecepatan arus dan jenis sedimen juga memberikan kontribusi yang cukup penting terhadap kandungan logam Fe.Kata Kunci: logam Fe, Air, Sedimen, Perna viridis, metode AAS Heavy metalsiron(Fe) is anessentialheavy metalswhose presencein a certain amountis neededby living organisms, but inexcessiveamountscan causetoxic effects.The aims of the research is to analyze the heavy metals coccentration and the pollution level of Fe in water, sediment, and green mussels (Perna viridis) at Tanjung Emas Semarang. This research was conducted from 7 November and 7 December 2013 using the Atomic Absorption Spectrophotometry (AAS) and research methodswithdescriptive. The results showed that the waters of the Tanjung Emas is still in the stage of heavy metals contaminated iron (Fe). Sediment and green mussels (Perna viridis)already indicated heavy metal contaminatediron. However, variations inenvironmental factorssuch astemperature, salinity, pH, flow velocity an dsediment types also providean important contributionto heavy metal contentof iron(Fe).Key Words: Fe, water, sediment, Perna viridis, metode AAS


2016 ◽  
Vol 2016 ◽  
pp. 1-12 ◽  
Author(s):  
Mohamed Anouar Nouioui ◽  
Salah Mahjoubi ◽  
Asma Ghorbel ◽  
Marouen Ben Haj Yahia ◽  
Dorra Amira ◽  
...  

This study was undertaken in order to determine heavy metal contents in twelve (n=12) henna brands and eleven (n=11) kohl products. An analytical test was performed for Pb, Cd, Cu, and Zn in henna and kohl products using atomic absorption spectrophotometery. The overall mean concentrations of heavy metals in henna varied between 1.2 and 8.9 μg g−1 for Pb; 0.8 and 18.6 μg g−1 for Cd; 0.5 μg g−1 and 3.3 μg g−1 for Cu; and 3.7 μg g−1 and 90.0 μg g−1 for Zn. As for kohl products, Pb concentrations ranged between 51.1 μg g−1 and 4839.5 μg g−1, Cd concentrations ranged between 1.0 μg g−1 and 158.6 μg g−1, Cu concentrations ranged between 2.5 μg g−1 and 162.5 μg g−1, and Zn concentrations ranged between 0.7 μg g−1 and 185.0 μg g−1. The results of our study revealed that Pb, Cd, Cu, and Zn contents in investigated samples were high, making from the prolonged use of such products a potential threat to human health. Therefore, major quality controls are recommended in order to enforce acceptable limits of potential contaminants in cosmetics and good manufacturing practice.


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