scholarly journals EXCESS THERMODYNAMIC PARAMETERS OF 1-[2-(DIMETHYLAMINO)-1-(4-METHOXYPHENYL) ETHYL] CYCLOHEXAN-1-OL IN AQUEOUS NA2SO4

Author(s):  
N P Mohabansi A K Satone Gulafsha A I Sheikh Komal Vairagade N P Mohabansi A K Satone Gulafsha A I Sheikh Komal Vairagade ◽  
2018 ◽  
Vol 83 (10) ◽  
pp. 1131-1142 ◽  
Author(s):  
Krishnamoorthy Umasivakami ◽  
Sundararajan Vaideeswaran ◽  
Venis Rose

Densities, viscosities and ultrasonic velocities were measured for the two ternary liquid mixtures containing morpholine (1) + 1,4-dioxane (2) + nitrobenzene (3) or + toluene (3) at 308.15 K over the entire range of mole fractions. Thermodynamic parameters, such as excess volume (VE), deviations in adiabatic compressibility (?KS), free length (?LF), isothermal compressibility (??T), free volume (?VF) and viscosity (??) were calculated and applied to the Redlich? Kister polynomial equation to determine the appropriate coefficients. The deviations of the ternary liquid mixtures from their ideal behaviour were determined from the measured and calculated thermodynamic properties. In addition, an insight into the molecular structure and possible interactions for the investigated mixtures was attempted.


1979 ◽  
Vol 44 ◽  
pp. 349-355
Author(s):  
R.W. Milkey

The focus of discussion in Working Group 3 was on the Thermodynamic Properties as determined spectroscopically, including the observational techniques and the theoretical modeling of physical processes responsible for the emission spectrum. Recent advances in observational techniques and theoretical concepts make this discussion particularly timely. It is wise to remember that the determination of thermodynamic parameters is not an end in itself and that these are interesting chiefly for what they can tell us about the energetics and mass transport in prominences.


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