scholarly journals Application of GGBFS and Bentonite to Auto-Healing Cracks of Cement Paste

2018 ◽  
Vol 1 (1) ◽  
pp. 38 ◽  
Author(s):  
J J Ekaputri ◽  
M S Anam ◽  
Y Luan ◽  
C Fujiyama ◽  
N Chijiwa ◽  
...  

Cracks are caused by many factors. Shrinkage and external loading are the most common reason. It becomes a problem when the ingression of aggressive and harmful substance penetrates to the concrete gap. This problem reduces the durability of the structures. It is well known that self – healing of cracks significantly improves the durability of the concrete structure. This paper presents self-healing cracks of cement paste containing bentonite associated with ground granulated blast furnace slag. The self-healing properties were evaluated with four parameters: crack width on the surface, crack depth, tensile strength recovery, and flexural recovery. In combination with microscopic observation, a healing process over time is also performed. The results show that bentonite improves the healing properties, in terms of surface crack width and crack depth. On the other hand, GGBFS could also improve the healing process, in terms of crack depth, direst tensile recovery, and flexural stiffness recovery. Carbonation reaction is believed as the main mechanism, which contributes the self-healing process as well as the continuous hydration progress.

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3711
Author(s):  
Mohammad Fahimizadeh ◽  
Ayesha Diane Abeyratne ◽  
Lee Sui Mae ◽  
R. K. Raman Singh ◽  
Pooria Pasbakhsh

Crack formation in concrete is one of the main reasons for concrete degradation. Calcium alginate capsules containing biological self-healing agents for cementitious materials were studied for the self-healing of cement paste and mortars through in vitro characterizations such as healing agent survivability and retention, material stability, and biomineralization, followed by in situ self-healing observation in pre-cracked cement paste and mortar specimens. Our results showed that bacterial spores fully survived the encapsulation process and would not leach out during cement mixing. Encapsulated bacteria precipitated CaCO3 when exposed to water, oxygen, and calcium under alkaline conditions by releasing CO32− ions into the cement environment. Capsule rupture is not required for the initiation of the healing process, but exposure to the right conditions are. After 56 days of wet–dry cycles, the capsules resulted in flexural strength regain as high as 39.6% for the cement mortar and 32.5% for the cement paste specimens. Full crack closure was observed at 28 days for cement mortars with the healing agents. The self-healing system acted as a biological CO32− pump that can keep the bio-agents retained, protected, and active for up to 56 days of wet-dry incubation. This promising self-healing strategy requires further research and optimization.


2020 ◽  
Vol 309 ◽  
pp. 38-43
Author(s):  
Konstantinos Aspiotis ◽  
Konstantinos Sotiriadis ◽  
Ivana Kumpová ◽  
Petra Mácová ◽  
Efstratios Badogiannis ◽  
...  

In the present work, the self-healing process in concrete was evaluated using analytical techniques. For this purpose, two concrete mixes of different composition (one used as control) were prepared with a water-to-binder ratio of 0.45. The self-healing process was triggered by the introduction in the concrete mix of a commercial expansive admixture (calcium sulfo-aluminate), two dicarboxylic acids, and sodium carbonate salt. After 28 days curing in water, the specimens were artificially cracked (crack width ≤ 900 μm) and then again water-cured for further 60 days until self-healing occurred. The progress of self-healing was investigated with a stereomicroscope at 40, 50, and 60 days, after cracking, to identify the quality and the degree of the healing. The efficiency of the self-healing process was also evaluated using micro-Raman spectroscopy and X-ray micro-computed tomography. Significant reduction in the crack width was observed as a result of a calcite filling, generated during the self-healing process. In some cases (crack width < 400 μm), the crack was completely healed. The experimental methodology used provided new insights into the evolution of the self-healing phenomenon in concrete.


2017 ◽  
Vol 39 (2) ◽  
pp. 73-80 ◽  
Author(s):  
Kamil Tomczak ◽  
Jacek Jakubowski ◽  
Przemysław Fiołek

Abstract Crack width measurement is an important element of research on the progress of self-healing cement composites. Due to the nature of this research, the method of measuring the width of cracks and their changes over time must meet specific requirements. The article presents a novel method of measuring crack width based on images from a scanner with an optical resolution of 6400 dpi, subject to initial image processing in the ImageJ development environment and further processing and analysis of results. After registering a series of images of the cracks at different times using SIFT conversion (Scale-Invariant Feature Transform), a dense network of line segments is created in all images, intersecting the cracks perpendicular to the local axes. Along these line segments, brightness profiles are extracted, which are the basis for determination of crack width. The distribution and rotation of the line of intersection in a regular layout, automation of transformations, management of images and profiles of brightness, and data analysis to determine the width of cracks and their changes over time are made automatically by own code in the ImageJ and VBA environment. The article describes the method, tests on its properties, sources of measurement uncertainty. It also presents an example of application of the method in research on autogenous self-healing of concrete, specifically the ability to reduce a sample crack width and its full closure within 28 days of the self-healing process.


2020 ◽  
Vol 90 (17-18) ◽  
pp. 1974-1986
Author(s):  
Emilia Irzmańska ◽  
Anna Bacciarelli-Ulacha ◽  
Agnieszka Adamus-Włodarczyk ◽  
Anna Strąkowska

In the environment where glove material is exposed to harmful chemicals, hazards related to faster penetration of dangerous substances into the glove interior may cause microdamage. One of the solutions to overcome this problem is to use the self-healing polymeric materials that can minimize economic loss and accidents in the workplace. The current work aims to present the impact of different types of textile reinforcement on the effectiveness and efficiency of the self-healing process of methyl vinyl silicone rubber containing hybrid molecules with an inorganic silsesquioxane intended for use on all-rubber gloves. Three knitted fabrics with a similar structure and differentiated raw material composition were selected: polyamide, cotton–polyamide, and cotton. Evaluation of the self-healing process of the elastomeric composite to personal protective equipment was performed. For this purpose the assessment of the surface morphology of materials has been performed before and after the self-healing process. The implementation of knitted fabric into the polymeric composite in the tested samples allowed us to obtain the best results in all tests. The studied composite samples exhibited an increased resistance to three types of damage: penetration, abrasion and puncture. The samples also underwent the self-healing processes and regeneration after a proper conditioning period. Thus, the obtained results confirmed the possibility of using tested elastomeric composites in the construction of protective gloves and showed an effectivity of the self-healing process for the long-term usage of that protective equipment.


2020 ◽  
Vol 22 (31) ◽  
pp. 17620-17631
Author(s):  
Xianling Chen ◽  
Jing Zhu ◽  
Yanlong Luo ◽  
Jun Chen ◽  
Xiaofeng Ma ◽  
...  

The changes in the type and number of hydrogen bonds as well as the microscopic behavior of molecular diffusion in the self-healing process of polyurethane are revealed.


2021 ◽  
Vol 7 ◽  
Author(s):  
Yan Gong ◽  
Jian Xu ◽  
Er-hu Yan ◽  
Jun-hua Cai

In this study, the molecular dynamics simulation was used to explore the effects of carbon-based nanomaterials as binder modifiers on self-healing capability of asphalt binder and to investigate the microscopic self-healing process of modified asphalt binders under different temperature. An asphalt average molecular structure model of PEN70 asphalt binder was constructed firstly. Further, three kinds of carbon-based nanomaterials were added at three different percentages ranging from 0.5 to 1.5% to the base binder to study their effects on the self-healing capability, including two carbon nanotubes (CNT1 and CNT2) and graphene nanoflakes. Combining with the three-dimensional (3D) microcrack model to simulate the asphalt self-healing process, the density analysis, relative concentration analysis along OZ direction, and mean square displacement analysis were performed to investigate the temperature sensitive self-healing characters. Results showed that the additions of CNTs were effective in enhancing the self-healing efficiency of the plain asphalt binder. By adding 0.5% CNT1 and 0.5% CNT2, about 652% and 230% of the mean square displacement of plain asphalt binder were enhanced at the optimal temperatures. However, the use of graphene nanoflakes as an asphalt modifier did not provide any noticeable changes on the self-healing efficiency. It can be found that the self-healing capability of the asphalt was closely related to the temperature. For base asphalt, the self-healing effect became especially high at the phase transition temperature range, while, for the modified asphalt, the enhancement of the self-healing capability at the low phase transition temperature (15°C) became negligible. In general, the optimal healing temperature range of the CNTs modified asphalt binders is determined as 45–55°C and the optimal dosage of the CNTs is about 0.5% over the total weight of the asphalt binder. Considering the effect of carbon-based nanomaterials on the self-healing properties, the recommended carbon-based nanomaterials modifier is CNT1 with the aspect ratio of 1.81.


Coatings ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 421 ◽  
Author(s):  
Lei Peng ◽  
Musong Lin ◽  
Sheng Zhang ◽  
Li Li ◽  
Qiang Fu ◽  
...  

A self-healing coating with UV-shielding property was prepared in this paper. The self-healing property was based on the inclusion between a host (β-CD-TiO2) and a guest HEMA-Ad). After inclusion of the host and guest, the host–guest complex (HEMA-Ad/β-CD-TiO2) was polymerized with other reactive monomers (HEMA and BA) to obtain the final coating. The coating had good hydrophobicity (water contact angle >90°, moisture absorption rate <2%) and excellent UV-shielding performance (ultra-violet protect factor >90%), and could be firmly bonded to a soft substrate. In addition, the coating had good self-healing property, which means that cracks in the material can recover many times after being damaged and that the UV-shielding ability can be fully restored with the self-healing process.


Author(s):  
Romario P. Santos ◽  
Tatiane M. Ramos ◽  
Brendo M. Borges ◽  
Luciana M. Hollanda ◽  
Álvaro S. Lima ◽  
...  

2015 ◽  
Vol 3 (10) ◽  
pp. 5599-5607 ◽  
Author(s):  
Wei Wang ◽  
Likun Xu ◽  
Huyuan Sun ◽  
Xiangbo Li ◽  
Shouhuan Zhao ◽  
...  

ACSECM monitored the self-healing process of scratched epoxy resin coatings with hexamethylene diisocyanate trimer microcapsules as functional additives.


Sign in / Sign up

Export Citation Format

Share Document