scholarly journals Analysis of technological conditions for the formation and burnout of carcinogenic pahs in boiler flue gases

Author(s):  
M. S. Ivanitskiy

THE PURPOSE. The necessity of establishing emission standards for highly toxic substances with carcinogenic properties in the context of the implementation of new principles of state regulation of environmental protection activities at energy enterprises is substantiated and confirmed. The analysis of the features of the formation and burnout of carcinogenic polycyclic aromatic hydrocarbons in the flue gases of boilers during the combustion of coals in lowtemperature conditions of the furnace process is carried out. Based on the analysis, the total and partial indicators of the harmfulness of flue gases were calculated in order to assess and predict the overall toxicity of coal combustion products, taking into account the contribution of carcinogenic substances.METHODS. When calculating the overall toxicity of flue gases, a systematic analysis and generalization of experimental data on the content of carcinogenic and non-carcinogenic polycyclic aromatic hydrocarbons in the combustion products of low-power boilers was applied.RESULTS. As a result of the performed study, the contribution of carcinogenic and non-carcinogenic polycyclic hydrocarbons to the overall toxicity of boiler flue gases during the combustion of Azeysky, Mugunsky, Cheremkhovsky and Tugnuy coal was determined. It is shown that substances such as benz(a)pyrene, fluoranthene, pyrene and phenanthrene significantly affect the level of the total indicator of the harmfulness of combustion products from 38.8 to 53.6%.CONCLUSION. The obtained research results can be applied at energy enterprises at the stage of substantiating the introduction of regime-technological and environmental measures in order to develop measures to improve environmental efficiency through technological rationing of carcinogenic emissions.

Author(s):  
M. Assad ◽  
V. V. Grushevski ◽  
O. G. Penyazkov ◽  
I. N. Tarasenko

The concentration of 16 polycyclic aromatic hydrocarbons (PAHs) in the gasoline combustion products emitted into the atmosphere by internal combustion engines (ICE) has been measured using the gas chromatography method. The concentrations of PAHs in the exhaust gases sampled behind a catalytic converter has been determined when the ICE operates in five modes: idle mode, high speed mode, load mode, ICE cold start mode (engine warm-up) and transient mode. Using 92 RON, 95 RON and 98 RON gasoline the effect of the octane number of gasoline on the PAHs content in the exhaust gases has been revealed. The concentration of the most carcinogenic component (benzo(α)pyrene) in the exhaust gases behind a catalytic converter significantly exceeds a reference value of benzo(α)pyrene in the atmospheric air established by the WHO and the EU for ICE in the load mode.


2012 ◽  
Vol 468-471 ◽  
pp. 2993-2997
Author(s):  
Xiao Juan Liang ◽  
Xi Qin Li

Polycyclic aromatic hydrocarbons are harmful to human body and environment. In order to know the formatting rules of benzene and polycyclic aromatic hydrocarbons in gasoline combustion process, a series of tests are done in a constant volume combustion bomb. The emissions of benzene and polycyclic aromatic hydrocarbons are measured by a gas chromatography-mass spectrometry analyzer. The test results show that the benzene in combustion products comes from the incomplete combustion fuel. The free radicals out of cracking fuel may also become benzene in combustion process. Adding ethanol in fuels does not necessarily increase the emission of benzene. Formation of polycyclic aromatic hydrocarbons varies with temperature.


2018 ◽  
Vol 15 (2) ◽  
pp. 74
Author(s):  
Michela Mannozzi ◽  
Giorgio Famiglini ◽  
Achille Cappiello ◽  
Chiara Maggi ◽  
Pierangela Palma ◽  
...  

Environmental contextMarine mining activities are potential sources of environmental pollution. Diethylene glycol used in offshore platforms has been suspected to facilitate the release of toxic substances into the sea. The results obtained elucidate that this release is not significant for the metals examined here, apart from iron, nor for polycyclic aromatic hydrocarbons, even at very high diethylene glycol concentrations. AbstractThe role of diethylene glycol (DEG) as a co-solvent for selected organic and inorganic pollutants adsorbed onto the particulate matter in produced formation water (PFW) from offshore gas platforms is thoroughly evaluated. Artificial seawater samples were spiked with certified sediments containing several polycyclic aromatic hydrocarbons (PAH) and metals. Aliquots (1 L) containing no DEG and DEG at 3500 and 5000 mg L−1 were kept in static and dynamic modes for 24 h before analysis to allow sufficient partitioning time between solid and liquid phases for the selected analytes. The Italian legislation on this matter sets 3500 mg L−1 as the highest concentration for DEG in PFW. In our experiments, concentrations equal to and above the set limit were chosen to enhance any possible co-solvent effect. Real PFW samples were also analysed, both with and without DEG. The analyses were conducted by using GC-MS for the PAH, and ICP-MS for the metals. A minor co-solvent effect was observed for low-molecular-weight PAH in the artificial seawater in static mode. Among metals, only iron showed an increase in solubility in the presence of DEG, demonstrating the co-solvent effect of DEG. The experiments in dynamic mode revealed no increase in the solubility of any other analytes in the liquid phase compared with static mode.


Author(s):  
I. Semjonova ◽  
E. Teirumnieks

This review describes methods which can be used for the reduction of the polycyclic aromatic hydrocarbon (PAH) emissions from wastewater and flue gases including principles of operation of the methods and studies of their effectiveness. There are discussed both methods, which nowadays are already used industrially, and their improvement opportunities as well as recent technological trends in this field. The methods have been classified into two main categories: flue gas treatment and wastewater treatment.


2015 ◽  
Vol 768 ◽  
pp. 204-211
Author(s):  
Song Tao Liu ◽  
Jia Liu ◽  
Li Na Zhu ◽  
Hong Wei Cao ◽  
Chuan Min Chen

Waste pollutions and disposal problems of transformer substation in electric power industry were paid more and more attention by people. Waste transformer oil contained many kinds of toxic substances. Transformer oil belongs to hazardous waste according to the definition of the United Nations Environment Programme (UNEP) and the National Hazardous Waste Inventory in China. The related research on environmental pollutants in waste transformer oil was less. The composition and content of particular pollutants which is harmful to human health and ecological environment in waste transformer oil was studied in this paper. Gas chromatography-mass spectrometry was chosen to detect the organic pollution composition and content of particular pollutants in transformer oil, based on investigation and analysis. Transformer oil samples running different time under 10KV voltage level were detected. The test results showed that with turbidity of oil rising, the content of polycyclic aromatic hydrocarbons in waste transformer oil increased, while benzene content changed in the opposite trend. Complex composition, different origin and different operating conditions were the reasons of difficulty to separate organic components in transformer oil during detection. This study is helpful for safe disposal of waste transformer oil. And it also can provide some theoretical support to eliminate the harm of the polycyclic aromatic hydrocarbons and benzene series.


2000 ◽  
Vol 13 (4) ◽  
pp. 379-402 ◽  
Author(s):  
Nathan D. Marsh ◽  
Mary J. Wornat ◽  
Lawrence T. Scott ◽  
Atena Necula ◽  
Arthur L. Lafleur ◽  
...  

2021 ◽  
Vol 14 (10) ◽  
pp. e245165
Author(s):  
Nicola Magnavita ◽  
Maria Teresa Congedo ◽  
Reparata Rosa Di Prinzio ◽  
Angela Iuliano

Apart from the risk of accidents, war theatres present a hazard related to numerous long-lasting toxic agents. For 10 years, a >60-year-old male journalist worked in war theatres in the Far and Near East where he was exposed to asbestos and other toxic substances (metals, silica, clays, polycyclic aromatic hydrocarbons and other organic substances) contained in dust and smoke of destroyed buildings. More than 15 years later, he developed a mucoepidermoid carcinoma of the soft palate and, subsequently, a pleural malignant mesothelioma. The safety of war journalists should focus not only on preventing the risk of being killed, but also on providing protection from toxic and carcinogenic agents. Exposure to substances released during the destruction of buildings can also pose a carcinogenic risk for survivors.


2018 ◽  
Vol 16 (10) ◽  
pp. 805-816
Author(s):  
Rithy KAN ◽  
Thaniya KAOSOL ◽  
Perapong TEKASAKUL ◽  
Surajit TEKASAKUL

Risk assessment of emitted particle polycyclic aromatic hydrocarbons (PAHs) from lignite-biomass pelletization burning focusing on size distribution and human health effects are investigated. The particles and PAHs are experimented by a tube furnace and high performance liquid chromatography coupled diode array and fluorescence detectors (HPLC-DAD/FLD), respectively. The carcinogenic, mutagenic, and toxic potencies of PAHs are also discussed in relative to the size distribution of emitted particle PAHs. The results indicate that the carcinogenic, mutagenic, and toxic potencies of PAHs are like to accumulate in the ultrafine particles finer than 0.65 µm. The ultrafine particles contribute the largest PAHs existences of carcinogenic, mutagenic and toxic substances; even though they register in the small mass fraction of PAHs.  Moreover, the co-pellets burning can reduce the values of carcinogenic PAHs, carcinogenic equivalency quotients (BaP-TEQ), mutagenic equivalency quotients (BaP-MEQ), and toxic equivalency quotients (TCDD-TEQ) by more than 60%.


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