scholarly journals Dissolution precipitation creep as a process for the strain localisation in mafic rocks

2021 ◽  
Author(s):  
Amicia Lee ◽  
Holger Stünitz ◽  
Mathieu Soret ◽  
Matheus Battisti

Unaltered mafic rocks consist of mechanically strong minerals (e.g. pyroxene, plagioclase and garnet) that can be deformed by crystal plastic mechanisms only at high temperatures (>800°C). Yet, many mafic rocks do show extensive deformation by non-brittle mechanisms when they have been subjected to lower temperature conditions. In such cases, the deformation typically is assisted by mineral reactions. Here we show that dissolution-precipitation creep (as a type of diffusion creep) plays a major role in deformation of gabbro lenses at upper amphibolite facies conditions. The Kågen gabbro exposed on south Arnøya is comprised of almost undeformed gabbro lenses with sheared margins wrapping around them. The shearing has taken place at temperatures of 690 ± 25 °C and pressures of 1.0 to 1.1 GPa. This contribution analyses the evolution of the microstructures and fabric of the low strain gabbro to high strain margins. Microstructural and crystallographic preferred orientation (CPO) data indicate that dissolution-precipitation creep is the dominant deformation mechanism, where dissolution of the gabbro took place in reacting phases of clinopyroxene and plagioclase, and precipitation took place in the form of new minerals: new plagioclase and clinopyroxene (with different composition), amphibole, and garnet. Amphibole shows a strong CPO that is primarily controlled by its preferential growth in the stretching direction. Synchronous deformation and mineral reactions of clinopyroxene suggest that mafic rocks can become mechanically weak during a general transformation weakening process, i.e. the interaction of mineral reaction and deformation by diffusion creep. The weakening is directly connected to a fluid-assisted transformation process that facilitates diffusion creep deformation of strong minerals at far lower stresses and temperatures than dislocation creep. Initially strong lithologies can become weak, provided that reactions can proceed during deformation; the transformation process itself is an important weakening mechanism in mafic (and other) rocks, facilitating deformation at low differential stresses and low stress exponents.

2021 ◽  
Author(s):  
Amicia Lee ◽  
Holger Stünitz ◽  
Mathieu Soret ◽  
Matheus Ariel Battisti ◽  
Jiří Konopásek

<p>Mafic rocks consist of strong minerals (e.g. clinopyroxene, plagioclase) that can only be deformed by crystal plastic mechanisms at high temperatures (>800°C). Yet, mafic rocks do show extensive deformation by non-brittle mechanisms when they have only reached lower temperatures (~650°C). In many of such cases, the deformation is accommodated by an interaction of deformation with simultaneous mineral reactions. Here we show that dissolution-precipitation creep plays a major role in deformation of gabbro lenses at mid and upper amphibolite facies conditions.</p><p>The Kågen gabbro in the North Norwegian Caledonides intruded the Vaddas Nappe at 439 Ma at pressures of 7-9 kbar, temperatures of 650-900°C, and depths of ∼26-34 km. The Kågen gabbro on south Arnøya is comprised of undeformed gabbro lenses with sheared margins wrapping around them. This contribution analyses the evolution of the microstructures and metamorphism from the low strain gabbro lenses to high strain mylonites at margins of the lenses. Microstructural and textural data indicate that dissolution-precipitation creep is the dominant deformation mechanism, where dissolution of the gabbro took place in reacting phases of clinopyroxene and plagioclase, and precipitation took place in the form of new minerals: new plagioclase and clinopyroxene, amphibole, and garnet. Amphibole shows a strong CPO that is primarily controlled by its preferential growth in the extension direction. Synchronous deformation and mineral reactions of clinopyroxene suggests mafic rocks can become mechanically weak during the general transformation weakening process, i.e. the interaction of mineral reaction and deformation by diffusion creep. The weakening is directly connected to a fluid-assisted transformation process that facilitates diffusion creep deformation of strong minerals at far lower stresses and temperatures than dislocation creep. Initially strong lithologies can become weak, provided that reactions can proceed during deformation, the transformation process itself is an important weakening mechanism in mafic (and other) rocks, facilitating deformation at low differential stresses.</p>


2020 ◽  
Author(s):  
Amicia Lee ◽  
Holger Stunitz ◽  
Matheus Ariel Battisti ◽  
Jiri Konopasek

<p>Strain localisation and fabric development in the lower crust is controlled by the active deformation mechanisms. Understanding the driving forces of such deformation aids in quantifying the stresses and rates of the deformation processes. Here we show that diffusion creep plays a major role in deformation of gabbro lenses at upper amphibolite facies conditions. The Kågen gabbro in the North Norwegian Caledonides intruded the Vaddas Nappe at 439 Ma at pressures of 7-9 kbar, temperatures of 650-900°C (depths of ∼26-34 km). The Kågen gabbro on south Arnøya is made up of undeformed gabbro lenses with sheared margins wrapping around them. This contribution analyses the evolution of the microstructures and fabric of the low strain gabbro to high strain margins. Microstructural and textural data indicate that preferential crystal growth of amphibole grains in the extension direction has produced the deformation microstructure and the CPO. Dissolution precipitation creep is inferred to be the dominant deformation mechanism, where dissolution of the gabbro took place in reacting phases of clinopyroxene and plagioclase, and precipitation took place in the form of new minerals: amphibole, garnet and zoisite. Synchronous deformation and mineral reactions of clinopyroxene suggests mafic rocks can become mechanically weak during the general transformation weakening process, i.e. the interaction of mineral reaction and deformation by diffusion creep. Deformation and metamorphic reaction were both important transformation processes during diffusion creep deformation of the margins of the gabbro lenses. The weakening is directly connected to a transformation process that facilitates diffusion creep deformation of strong minerals (pyroxene, garnet, zoisite) at far lower stresses than dislocation creep. Initially strong lithologies can become weak, provided that reactions can proceed during deformation, the transformation process itself is an important weakening mechanism in mafic (and other) rocks, facilitating deformation at low differential stresses.</p>


2019 ◽  
Vol 116 (52) ◽  
pp. 26389-26393
Author(s):  
David P. Dobson ◽  
Alexander Lindsay-Scott ◽  
Simon A. Hunt ◽  
Edward Bailey ◽  
Ian G. Wood ◽  
...  

The lowermost portion of Earth’s mantle (D″) above the core−mantle boundary shows anomalous seismic features, such as strong seismic anisotropy, related to the properties of the main mineral MgSiO3postperovskite. But, after over a decade of investigations, the seismic observations still cannot be explained simply by flow models which assume dislocation creep in postperovskite. We have investigated the chemical diffusivity of perovskite and postperovskite phases by experiment and ab initio simulation, and derive equations for the observed anisotropic diffusion creep. There is excellent agreement between experiments and simulations for both phases in all of the chemical systems studied. Single-crystal diffusivity in postperovskite displays at least 3 orders of magnitude of anisotropy by experiment and simulation (Da= 1,000Db;Db≈Dc) in zinc fluoride, and an even more extreme anisotropy is predicted (Da= 10,000Dc;Dc= 10,000Db) in the natural MgSiO3system. Anisotropic chemical diffusivity results in anisotropic diffusion creep, texture generation, and a strain-weakening rheology. The results for MgSiO3postperovskite strongly imply that regions within the D″ region of Earth dominated by postperovskite will 1) be substantially weaker than regions dominated by perovskite and 2) develop a strain-induced crystallographic-preferred orientation with strain-weakening rheology. This leads to strain localization and the possibility to bring regions with significantly varying textures into close proximity by strain on narrow shear zones. Anisotropic diffusion creep therefore provides an attractive alternative explanation for the complexity in observed seismic anisotropy and the rapid lateral changes in seismic velocities in D″.


2018 ◽  
Author(s):  
Sina Marti ◽  
Holger Stünitz ◽  
Renée Heilbronner ◽  
Oliver Plümper ◽  
Rüdiger Kilian

Abstract. While it is widely observed that mafic rocks are able to exeprience high strains by viscous flow, details on their rheology and deformation mechanisms are poorly constrained. Here, rock deformation experiments on four different, water-added plagioclase-pyroxene mixtures are presented: (i) plagioclase(An60-70) – clinopyroxene – orthopyroxene, (ii) plagioclase(An60) – diopside, (iii) plagioclase(An60) – enstatite and (iv) plagioclase(An01) – enstatite. Samples were deformed in general shear at strain rates of 3 × 10−5 to 3 × 10−6 s−1, 800 °C and confining pressure of 1.0 or 1.5 GPa. Results indicate that dissolution-precipitation creep (DPC) and grain boundary sliding (GBS) are the dominant deformation mechanisms. Coinciding with sample deformation, syn-kinematic mineral reactions yield abundant nucleation of new grains; the resulting intense grain size reduction is considered crucial for the activity of DPC and GBS. In high strain zones dominated by plagioclase, a weak, non-random and geometrically consistent crystallographic preferred orientation (CPO) is observed. Usually, a CPO is considered a consequence of dislocation creep, but the experiments presented here demonstrate that a CPO can develop during DPC and GBS. This study provides new evidence for the importance of DPC and GBS in mid-crustal shear zones within mafic rocks, which has important implications on understanding and modelling of mid-crustal rheology and flow.


2021 ◽  
Author(s):  
Jonas Ruh ◽  
Leif Tokle ◽  
Whitney Behr

Abstract Geodynamic numerical models often employ solely grain-size-independent dislocation creep to describe upper mantle dynamics. However, observations from nature and rock deformation experiments suggest that shear zones can transition to a grain-size-dependent creep mechanism due to dynamic grain size evolution, with important implications for the overall strength of plate boundaries. We apply a two-dimensional thermo-mechanical numerical model with a composite diffusion-dislocation creep rheology coupled to a dynamic grain size evolution model based on the paleowattmeter. Results indicate average olivine grain sizes of 3–12 cm for the upper mantle below the LAB, while in the lithosphere grain size ranges from 0.3–3 mm at the Moho to 6–15 cm at the LAB. Such a grain size distribution results in dislocation creep being the dominant deformation mechanism in the upper mantle. However, deformation-related grain size reduction below 100 μm activates diffusion creep along lithospheric-scale shear zones during rifting, affecting the overall strength of tectonic plate boundaries.


Solid Earth ◽  
2018 ◽  
Vol 9 (4) ◽  
pp. 985-1009 ◽  
Author(s):  
Sina Marti ◽  
Holger Stünitz ◽  
Renée Heilbronner ◽  
Oliver Plümper ◽  
Rüdiger Kilian

Abstract. It is widely observed that mafic rocks are able to accommodate high strains by viscous flow. Yet, a number of questions concerning the exact nature of the involved deformation mechanisms continue to be debated. In this contribution, rock deformation experiments on four different water-added plagioclase–pyroxene mixtures are presented: (i) plagioclase(An60–70)–clinopyroxene–orthopyroxene, (ii) plagioclase(An60)–diopside, (iii) plagioclase(An60)–enstatite, and (iv) plagioclase(An01)–enstatite. Samples were deformed in general shear at strain rates of 3×10−5 to 3×10−6 s−1, 800 °C, and confining pressure of 1.0 or 1.5 GPa. Results indicate that dissolution–precipitation creep (DPC) and grain boundary sliding (GBS) are the dominant deformation mechanisms and operate simultaneously. Coinciding with sample deformation, syn-kinematic mineral reactions yield abundant nucleation of new grains; the resulting intense grain size reduction is considered crucial for the activity of DPC and GBS. In high strain zones dominated by plagioclase, a weak, nonrandom, and geometrically consistent crystallographic preferred orientation (CPO) is observed. Usually, a CPO is considered a consequence of dislocation creep, but the experiments presented here demonstrate that a CPO can develop during DPC and GBS. This study provides new evidence for the importance of DPC and GBS in mid-crustal shear zones within mafic rocks, which has important implications for understanding and modeling mid-crustal rheology and flow.


Minerals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 995
Author(s):  
Yuval Boneh ◽  
Emily J. Chin ◽  
Greg Hirth

Combined observations from natural and experimental deformation microstructures are often used to constrain the rheological properties of the upper mantle. However, relating natural and experimental deformation processes typically requires orders of magnitude extrapolation in strain rate due to vastly different time scales between nature and the lab. We examined a sheared peridotite xenolith that was deformed under strain rates comparable to laboratory shearing time scales. Microstructure analysis using an optical microscope and electron backscatter diffraction (EBSD) was done to characterize the bulk crystallographic preferred orientation (CPO), intragrain misorientations, subgrain boundaries, and spatial distribution of grains. We found that the microstructure varied between monophase (olivine) and multiphase (i.e., olivine, pyroxene, and garnet) bands. Olivine grains in the monophase bands had stronger CPO, larger grain size, and higher internal misorientations compared with olivine grains in the multiphase bands. The bulk olivine CPO suggests a dominant (010)[100] and secondary activated (001)[100] that are consistent with the experimentally observed transition of the A to E-types. The bulk CPO and intragrain misorientations of olivine and orthopyroxene suggest that a coarser-grained initial fabric was deformed by dislocation creep coeval with the reduction of grain size due to dynamic recrystallization. Comparing the deformation mechanisms inferred from the microstructure with experimental flow laws indicates that the reduction of grain size in orthopyroxene promotes activation of diffusion creep and suggests a high activation volume for wet orthopyroxene dislocation creep.


2019 ◽  
Vol 38 (2019) ◽  
pp. 590-600
Author(s):  
Marie Kvapilova ◽  
Jiri Dvorak ◽  
Petr Kral ◽  
Karel Hrbacek ◽  
Vaclav Sklenicka

AbstractThe cast nickel-base MAR-M247 superalloy has been widely used for high-temperature components. In this work, the creep behaviour of two alternates of MAR-M247 superalloy with different grain size processed at different temperatures of casting are compared. Under the creep testing conditions used in this study, only negligible differences of creep behaviour of the alternate alloys were found and the evaluated creep characteristics correspond to the power-law or dislocation creep. The microstructure of the alloys consists of a𝛾matrix with a eutectic,𝛾'strengthening cubic precipitates, and M6C and M23C6carbides. Increasing the temperature induces the dissolution of some M23C6carbides. Fractures of both variants of alloys exhibit a more ductile character at higher temperatures, while at lower temperature a mixture of brittle and ductile fracture modes was observed, which changes the creep fracture ductility.


2021 ◽  
Author(s):  
Lisa Marie Brückner ◽  
Claudia A. Trepmann

<p>Pseudotachylyte-bearing amphibole-rich gneisses with concordant quartz-rich layers from the base of the Silvretta nappe, Austria, are analyzed by polarized light microscopy, scanning electron microscopy and electron back scattered diffraction. Amphibole grains show microfractures, undulatory extinction, deformation lamellae, kink bands, mechanical twins and locally recrystallized grains restricted to sites of high strain, e.g. along microshear zones and twin boundaries. The twins are characterized by a twin plane parallel to (-101), a rotation axis parallel to [101] and a misorientation angle of 178°. The (-101) amphibole twins document the high differential stresses during crystal plasticity coeval with pseudotachylyte formation, given their high critical resolved shear stress of 200 MPa. Directly at the contact to twinned amphibole within the gneisses, quartz grains commonly show subbasal deformation lamellae, short-wavelength undulatory extinction and cleavage cracks mostly parallel to {10-11} rhombohedral planes that are decorated by recrystallized grains with a diameter of < 10 µm. The small recrystallized grains show a crystallographic preferred orientation (CPO) that is controlled by the orientation of the host grains. This quartz microstructure consistently indicates high-stress crystal plasticity of quartz concurrent with high-stress crystal plasticity of amphibole and pseudotachylyte formation.</p><p>Quartz-rich layers (>90% quartz) concordant to the foliation of the gneisses commonly show evidence of dynamic recrystallization in the regime of dislocation creep. The recrystallized grain microstructure is mostly homogenous without a gradient towards the lithological contact to the amphibole-rich gneisses. Locally, however, a gradient of decreasing strain towards the contact can be observed as indicated by a decreasing number of recrystallized grains. Close to the contact, quartz grains are coarse with long axes of a few mm. A core-and-mantle structure, where recrystallized grains surround a few hundred µm wide and mm-long porphyroclasts, is occurring in transition towards an almost completely recrystallized microstructure. The recrystallized grains show a CPO indicating rhombohedral <a> dislocation glide. Recrystallized grains are isometric and subgrains in porphyroclasts are of similar shape and size, indicating dynamic subgrain rotation recrystallization. Stresses on the order of hundred MPa are suggested by the diameter of recrystallized grains of in average about 10 µm. Locally, the recrystallized quartz aggregate is affected by subsequent low-temperature plasticity, as indicated by shear fractures offsetting the recrystallized microstructure. The missing or decreasing strain gradients of dislocation creep within the quartz-rich layers towards the amphibole-rich gneisses indicate that dislocation creep in the quartz-rich layers cannot be responsible for transferring high stresses required for high-stress crystal-plasticity of quartz and amphibole as well as pseudotachylyte-formation and suggest that dislocation creep of quartz represents an independent earlier stage of deformation.</p>


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