scholarly journals Ambient conditions and fate and transport simulations of dissolved solids, chloride, and sulfate in Beaver Lake, Arkansas, 2006--10

2013 ◽  
Author(s):  
W. Reed Green
Keyword(s):  
Fate And Transport ◽  
Ambient Conditions ◽  
Dissolved Solids ◽  
Beaver Lake

Hydrogen bonding in liquid methanol at ambient conditions and at high pressure

2000 ◽  
Vol 98 (3) ◽  
pp. 125-134 ◽  
Author(s):  
T. Weitkamp, J. Neuefeind, H. E. Fisch
Keyword(s):  
High Pressure ◽  
Hydrogen Bonding ◽  
Ambient Conditions

PHYSICO-CHEMICAL ASPECTS OF YAMUNA RIVER AT GOKUL BARRAGE, MATHURA (UP) INDIA

2017 ◽  
Vol 23 (2) ◽  
Author(s):  
AJAY KUMAR RAJAWAT ◽  
PRAVEEN KUMAR
Keyword(s):  
Water Samples ◽  
Suspended Solids ◽  
Total Dissolved Solids ◽  
Tolerance Limit ◽  
Chemical Condition ◽  
Yamuna River ◽  
Dissolved Solids ◽  
Time Period ◽  
Physico Chemical ◽  
Almost All

An attempt has been made to study the Physico-chemical condition of water of Yamuna River at Gokul Barrage, Mathura, (UP). The time period of study was July 2015 to June 2016. Three water samples were selected from different sites in each month for study. The parameters studied were Temperature, Turbidity, pH, DO, BOD, COD, Total Dissolved Solids and Suspended Solids. Almost all the parameters were found above the tolerance limit.

Hybrid Micro-Optical Sensors via Sol-Gel Soft Lithography

2000 ◽  
Vol 628 ◽  
Author(s):  
Mark A. Clarner ◽  
Michael J. Lochhead
Keyword(s):  
Optical Sensors ◽  
Soft Lithography ◽  
Sol Gel ◽  
Silica Gels ◽  
Ph Sensing ◽  
Ambient Conditions ◽  
Sensor Applications ◽  
Patterned Structures ◽  
Biological Functionality ◽  
Indicator Dyes

ABSTRACTOrganically modified silica gels and dye-doped silica gels have been patterned into micrometer-scale structures on a substrate using micro molding in capillaries (MIMIC). This approach is from a class of elastomeric stamping and molding techniques collectively known as soft lithography. Soft lithography and sol-gel processing share attractive features in that they are relatively benign processes performed at ambient conditions, which makes both techniques compatible with a wide variety of organic molecules, molecular assemblies, and biomolecules. The combination of sol-gel and soft lithography, therefore, holds enormous promise as a tool for microfabrication of materials with optical, chemical, or biological functionality that are not readily patterned with conventional methods. This paper describes our investigation of micro-patterned organic-inorganic hybrid materials containing indicator dyes for microfluidic sensor applications. Reversible colorimetric pH sensing via entrapped reagents is demonstrated in a prototype microfluidic sensor element. Patterned structures range from one to tens of micrometers in cross-section and are up to centimeters in length. Fundamental chemical processing issues associated with mold filling, cracking and sensor stability are discussed.

Performance Study of Some Reverse Osmosis Systems for Removal of Uranium and Total Dissolved Solids in Underground Waters of Punjab State, India

2014 ◽  
Vol 4 (2) ◽  
pp. 467-476
Author(s):  
Nisha Sharma ◽  
Jaspal Singh ◽  
Barjinder Kaur
Keyword(s):  
Drinking Water ◽  
Reverse Osmosis ◽  
State Government ◽  
Total Dissolved Solids ◽  
Internal Exposure ◽  
Drinking Water Source ◽  
Performance Study ◽  
Dissolved Solids ◽  
Underground Waters ◽  
High Concentrations

Radionuclides (uranium, thorium, radium, radon gas etc.) are found naturally in air, water, soil and rock. Everyday, we ingest and inhale these radionuclides through the air we breathe and through food and water we take. Out of the internal exposure via ingestion of radionuclides, water contributes the major portion. The natural radioactivity of water is due to the activity transfer from bed rock and soils. In our surveys carried out in the past few years, we have observed high concentrations of uranium and total dissolved solids (TDS) in drinking waters of some southern parts of Punjab State exceeding the safe limits recommended by national and international agencies. The main drinking water source is the underground water procured from different depths. Due to the highly saline taste, disorders in their digestive systems and other ailments, people are installing reverse osmosis (RO) systems in their houses. Some RO systems have been installed on commercial basis. The state government is also in the process of installing community RO systems at the village level. As high values of uranium are also undesired and may pose health hazards due to radioactivity and toxicity of uranium, we have conducted a survey in the field to study the performance of various RO systems for removal of uranium and TDS. Water samples from about forty RO systems from Faridkot, Mansa, Bathinda and Amritsar districts of Punjab State were collected and analyzed. Our results show that some RO systems are able to remove more than 99% of uranium in the underground waters used for drinking purposes. TDS values are also reduced considerably to the desired levels. So RO systems can be used to avoid the risk of unduly health problems posed by high concentrations of uranium and TDS in drinking water.

Fluorescence of BODIPY Dyes in Gas Phase at near Ambient Conditions

2020 ◽  
Author(s):  
Kseniya A. Mariewskaya ◽  
Denis Larkin ◽  
Yuri Samoilichenko ◽  
Vladimir Korshun ◽  
Alex Ustinov
Keyword(s):  
Gas Phase ◽  
Molecular Interactions ◽  
Atmospheric Pressure ◽  
Fluorescence Spectra ◽  
Visible Range ◽  
Intrinsic Properties ◽  
Ambient Conditions ◽  
Ideal Model ◽  
Molecular Fluorescence ◽  
Tesla Coil

Molecular fluorescence is a phenomenon that is usually observed in condensed phase. It is strongly affected by molecular interactions. The study of fluorescence spectra in the gas phase can provide a nearly-ideal model for the evaluation of intrinsic properties of the fluorophores. Unfortunately, most conventional fluorophores are not volatile enough to allow study of their fluorescence in the gas phase. Here we report very bright gas phase fluorescence of simple BODIPY dyes that can be readily observed at atmospheric pressure using conventional fluorescence instrumentation. To our knowledge, this is the first example of visible range gas phase fluorescence at near ambient conditions. Evaporation of the dye in vacuum allowed us to demonstrate organic molecular electroluminescence in gas discharge excited by electric field produced by a Tesla coil.

Yttrium Oxyhydrides for Photochromic Applications: Correlating Composition and Optical Response

2018 ◽  
Author(s):  
Dmitrii Moldarev ◽  
Elbruz M. Baba ◽  
Marcos V. Moro ◽  
Chang C. You ◽  
Smagul Zh. Karazhanov ◽  
...  
Keyword(s):  
Medical Devices ◽  
Ternary Diagram ◽  
Optical And Electrical Properties ◽  
Ambient Conditions ◽  
Elastic Recoil ◽  
Elastic Recoil Detection Analysis ◽  
Photochromic Properties ◽  
Smart Windows ◽  
Elastic Recoil Detection ◽  
Detection Analysis

It has been recently demonstrated that yttrium oxyhydride(YHO) films can exhibit reversible photochromic properties when exposed to illumination at ambient conditions. This switchable optical propertyenables their utilization in many technological applications, such as smart windows, sensors, goggles, medical devices, etc. However, how the composition of the films affects their optical properties is not fully clear and therefore demands a straightforward investigation. In this work, the composition of YHO films manufactured by reactive magnetron sputtering under different conditions is deduced in a ternary diagram from Time-of-Flight Elastic Recoil Detection Analysis (ToF-ERDA). The results suggest that stable compounds are formed with a specificchemical formula – YH<sub>2-δ</sub>O<sub>δ</sub>. In addition, optical and electrical properties of the films are investigated, and a correlation with their compositions is established. The corresponding photochromic response is found in a specific oxygen concentration range (0.45 < δ < 1.5) with maximum and minimum of magnitude on the lower and higher border, respectively.

Bringing Biocatalysis into the Deuteration Toolbox

2019 ◽  
Author(s):  
Jack Rowbotham ◽  
Oliver Lenz ◽  
Holly Reeve ◽  
Kylie Vincent
Keyword(s):  
Late Stage ◽  
Hydrogen Isotope ◽  
Reductive Amination ◽  
Mechanistic Studies ◽  
Ambient Conditions ◽  
Synthetic Pathway ◽  
Drug Candidates ◽  
Isotopic Selectivity ◽  
Reducing Equivalents

<p></p><p>Chemicals labelled with the heavy hydrogen isotope deuterium (<sup>2</sup>H) have long been used in chemical and biochemical mechanistic studies, spectroscopy, and as analytical tracers. More recently, demonstration of selectively deuterated drug candidates that exhibit advantageous pharmacological traits has spurred innovations in metal-catalysed <sup>2</sup>H insertion at targeted sites, but asymmetric deuteration remains a key challenge. Here we demonstrate an easy-to-implement biocatalytic deuteration strategy, achieving high chemo-, enantio- and isotopic selectivity, requiring only <sup>2</sup>H<sub>2</sub>O (D<sub>2</sub>O) and unlabelled dihydrogen under ambient conditions. The vast library of enzymes established for NADH-dependent C=O, C=C, and C=N bond reductions have yet to appear in the toolbox of commonly employed <sup>2</sup>H-labelling techniques due to requirements for suitable deuterated reducing equivalents. By facilitating transfer of deuterium atoms from <sup>2</sup>H<sub>2</sub>O solvent to NAD<sup>+</sup>, with H<sub>2</sub> gas as a clean reductant, we open up biocatalysis for asymmetric reductive deuteration as part of a synthetic pathway or in late stage functionalisation. We demonstrate enantioselective deuteration via ketone and alkene reductions and reductive amination, as well as exquisite chemo-control for deuteration of compounds with multiple unsaturated sites.</p><p></p>

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