scholarly journals PEMANFAATAN LIMBAH CANGKANG TELUR SEBAGAI BIOSORBEN UNTUK ADSORPSI LOGAM Pb Dan Cd

2017 ◽  
Vol 5 (1) ◽  
pp. 92
Author(s):  
Mamay Maslahat ◽  
Agus Taufik ◽  
Prima Wahyu Subagja

Waste Utilization of Eggs Shell as an Adsorbent for Adsorption of Metal, Pb and Cd        Egg shell waste is one of waste that not be fully utilized. Eggshell can be used as a biosorbent substance because its contain a high CaCO3 and has a natural pore structure. Eggshell waste biosorbent potentially used as an alternative to adsorp heavy metal waste that pollute much in the environment. The purpose of the study was to use the waste to become biosorbent and to investigate its potential in adsorption Pb and Cd. Research methodology were producing biosorbent and getting optimum-sorption condition. They were contact time, biosorbent weights, and the concentration of  Pb and Cd. Measurement of the concentration of Pb and Cd before and after sorption processes using instrument of Atomic Absorption Spectrophotometer (AAS) Agilent 240FS type AA. The results showed that eggshell biosorbent could adsorb heavy metals of Pb 65.99% in concentration of adsorbent of 160 ppm, contact time was 20 minutes, and biosorbent weights of 0.50 g. Adsorption of Cd was 93.16% in concentration of adsorbent was 20 ppm, contact  time  40 minutes, and biosorbent weights 0.25 g.Key words: eggshell biosorbent ,  Pb, Cd, Atomic Absorbtion Spectrophotometer ABSTRAK         Limbah cangkang telur termasuk salah satu limbah yang belum dimanfaatkan secara maksimal. Cangkang telur dapat dimanfaatkan sebagai zat penjerap yang baik karena mengandung CaCO3 yang tinggi dan memiliki struktur pori-pori alami. Limbah cangkang telur berpotensi digunakan sebagai biosorben alternatif untuk mengadsorpsi limbah logam berat yang banyak mencemari lingkungan yaitu logam berat Pb dan Cd. Tujuan penelitian ini adalah memanfaatkan limbah cangkang telur untuk dijadikan biosorben dan meneliti potensinya dalam adsorpsi logam Pb dan Cd. Tahapan penelitian terdiri atas preparasi dan pembuatan biosorben cangkang telur, dan  optimasi adsorpsi biosorben cangkang telur terhadap logam berat Pb dan Cd. Optimasi adsorpsi meliputi variabel waktu kontak optimum, bobot biosorben optimum,  dan konsentrasi adsorbat optimum. Pengukuran konsentrasi logam berat Pb dan Cd sebelum dan setelah proses adsorpsi menggunakan instrumen Atomic Absorption Spectrophotometer (AAS) Agilent tipe 240FS AA. Hasil penelitian menunjukan bahwa biosorben cangkang telur dapat mengadsorpsi logam berat Pb sebesar 65,99% pada kondisi konsentrasi adsorbat 160 ppm, waktu kontak 20 menit, dan berat biosorban sebesar 0,50 gram. Sedangkan untuk logam berat  Cd, persen adsorpsi sebesar 93,16% pada konsentrasi sorbat 20 ppm, waktu kontak 40 menit, dan berat biosorben sebesar 0,25 gram.Kata Kunci: biosorben cangkang telur, Pb, Cd, Atomic Absorption spectrophotometer.

2008 ◽  
Vol 5 (1) ◽  
pp. 16-22 ◽  
Author(s):  
P. Martin Deva Prasath ◽  
T. Hidayathulla Khan

Investigations on the accumulation of heavy metals (Zn, Cu, Fe, Mn, Co, Pb, Cd and Ni) in water, sediments and fish (Mugil cephalus) using Atomic Absorption Spectrophotometer at Poompuhar coast, lying along the southeast coast of India was studied before and after tsunami. Accumulation of heavy metals was observed in the order of Sediments > Fish > Water. In water, the order was found to be Mn > Fe > Zn > Cu > Ni > Cd > Co > Pb; Mn recorded a maximum of 506.9µ. L-1and Pb recorded a minimum of 0.006µ. L-1. In sediments, the order was Mn > Fe > Cu > Zn > Pb ≈Co ≈Cd ≈ Ni; Mn recorded a maximum of 851.1µg.g-1and a minimum of below detectable levels were found in Pb, Co, Cd and Ni. In fish, the order was found to be Fe > Zn > Mn > Cu > Ni > Co ≈ Pb ≈ Cd; Fe recorded a maximum of 529.13 µg. g-1and a minimum of below detectable levels were found in Pb and Cd.


2017 ◽  
Vol 17 (2) ◽  
pp. 131
Author(s):  
Emas Agus Prastyo Wibowo ◽  
Ika Sri Hardyanti ◽  
Isni Nurani ◽  
Dyan Septyaningsih Hardjono HP ◽  
Aden Dhana Rizkita

STUDI PENURUNAN KADAR LOGAM BESI (Fe) DAN LOGAM TEMBAGA (Cu) PADA AIR EMBUNG MENGGUNAKAN ADSORBEN NANOSILIKAABSTRAKPolusi limbah logam berat dalam air merupakan satu permasalahan lingkungan yang penting. Dalam mengatasi permasalahan tersebut dapat dilakukan purifikasi terhadap air tersebut. Metode yang dapat digunakan untuk purifikasi limbah sangat beragam salah satunya adalah absorpsi. Secara umum metode absorpsi telah banyak digunakan dalam purifikasi air limbah. Metode absorpsi dapat menurunkan kadar logam yang terlarut pada limbah. cair dengan cara menyerap logam-logam tersebut ke dalam permukaan absorbennya. Tujuan dilakukan penelitian ini adalah  untuk menurunkan konsentrasi logam besi (Fe) dan tembaga (Cu) menggunakan adsorben nanosilika. Penelitian ini menggunakan variabel bebas yaitu waktu pengadukan (20 menit, 40 menit, dan 60 menit). Hasil akhir filtrat air embung kemudian diukur absorbansinya menggunakan Spektrofotometer Serapan Atom. Berdasarkan hasil analisa menggunakan instrumen SSA diperoleh hasil bahwa tidak terjadi penurunan logam Fe maupun Cu. Dalam hal ini terjadi peningkatan konsentrasi dalam logam Fe maupun Cu, hal ini dikarenakan kurangnya waktu pengadukan dan pengaruh dari adsorben nanosilika.Kata Kunci: limbah, logam berat, nanosilika STUDY OF DECREASING METALS IRON (Fe) AND COPPER (Cu) ON EMBUNG WATER USE OF NANOSILICA ADSORBEN ABSTRACTHeavy waste pollution of heavy metals in the water is an important environment issue. To solve the problem, its can be purified the water. The methods that can be used for waste purification are very diverse, one of which is absorption. In general, the method of absorption has been widely used in wastewater purification. The absorption method can decrease dissolved metal content in the waste. liquid by absorbing the metals into the absorbent surface. Research has been conducted to reduce the concentration of iron (Fe) and copper (Cu) by using nanosilica adsorbent. This research used to independent variable that is stirring time (20 minutes, 40 minutes, and 60 minutes). The final result of filtrate embung water then measured its absorbance using Atomic Absorption Spectrophotometer (AAS). Based on the result of the analysis using SSA instrument, it is found that there is no decrease of Fe and Cu metals. There are several reasons for those problem such as due to lack of stirring time and the influence of nanosilica adsorbent.Keywords: Waste pollution, heavy metal, nanosilica


2021 ◽  
Vol 3 (2) ◽  
pp. 161-167
Author(s):  
Handan Ertürk

In this research, it was aimed to use the Chlorella Vulgaris algae, and eggshell waste (ESW) as different mineral sources for tomato plant nutrition in soilless culture. Algae is seen as safe, sustainable energy source. Egg shell waste is known to be valuable for high calcium content and minerals therefore, has been considered as mineral enrichment source. Although there are several papers on the soil nutrition, there is not as much information on eggshell waste and algae use for plant production in soilless culture. In the controlled atmosphere of the laboratory, a set-up was constructed for pumping the liquid medium (hydroponics) circulating in the tubes holding the tomato plantlets. The liquid nutrient solutions used for soilless culture treatments were media enriched with algae, enriched with ESW and blank (hydroponic only). Research was conducted for 3 months, the final weight of harvested tomatoes and mineral uptake of the plant (stalk and tomato) for different treatments were measured. Algae added medium gave higher results in tomato weight, than ESW added and blank treatments. Results showed that algae and ESW addition led to increased Ca content in harvested tomato, as well as minerals such as B, K, Mg, and Zn. The results were as expected in terms of increase in mineral contents, but the statistics showed no significant difference between treatments.


2018 ◽  
Vol 6 (1) ◽  
pp. 26-37
Author(s):  
Catherina M. Bijang ◽  
Jolantje Latupeirissa ◽  
Marike Ratuhanrasa

The research on the biosorption of Cu2+ metal ions in brown seaweed biosorbent (Padina australis) has been done. This study aims to determine moisture content, ash content, biomass content, pH and optimum contact time of Cu2+  metal ions absorption pH and optimum contact time of Cu2+  metal ions absorption. The method used is batch method. The adsorption result of Cu2+ metal ions was analyzed  by  using  atomic  absorption  spectrophotometer  (AAS).  The  results showed that the optimum pH was 7 with 99.8308 % absorption ability of biosorbent and the optimum contact time was 5 hours with 99.5570 % biosorbent absorbency.


2020 ◽  
Vol 8 (2) ◽  
pp. 149
Author(s):  
NUR ALIM NATSIR ◽  
YUSRIANTI HANIKE ◽  
MUHAMMAD RIJAL ◽  
SUHAEDIR BACHTIAR

Differences in the accumulation of heavy metals lead and cadmium in water, sediments and mangrove organs (roots, stems and leaves) found in the waters of Tulehu, Maluku Province. Samples were taken from three observation stations, namely stopping ships that are not operating (station 1), Tulehu harbor (station 2) and Control (station 3). Pb and Cd were analyzed using Atomic Absorption Spectrophotometer. Pb and Cd content in sediments is higher than in water. The highest Pb and Cd content is found in the stems then in the roots and leaves (stems> roots> leaves). Mangroves are one of the aquatic organisms that have the ability to absorb heavy metals in the aquatic environment. Key words: Mangrove, Pb, Cd, Heavy Metal


The study was conducted on heavy metals contents of water, fish tissues and sediment from Lagos lagoon complex, Nigeria. The aim was to assess the current environmental health/pollution status of the lagoon from three sample stations: Ologe lagoon [1], Badagry creek [2] and Lagos island [3]; each having three (3) hotspots. In all, twelve (11) heavy metals were determined between June and November, 2018. Heavy metals: Zn, Fe, Pb, Cu, Na, Potassium, Ca, Mn, Cd, Hg and Nickel were determined using Atomic absorption spectrophotometer (AAS). Results of mean Heavy metals in fish tissues were: Zn (0.741±0.38), Fe (5.59±8.32), Pb (0.12±0.17mg/l), Cu (0.16±0.25), Na (9.38±0.25), Ca (116.68±41.53), Mn (0.76±0.96), Pb (0.01±0.0), Cd (0.02±0.0), Potassium (12.09±2.34), Ni (0.02±0.02) and Hg (0.01±0.0). Statistical analysis showed variations in the distribution of Heavy metals which are mostly within recommended limits of WHO, FME, & LASEPA. Except for iron (Fe), which was found in excess in fish tissues, and other metals (lead), found in higher conc. in sediments than in water and fish tissues combined. This is indicative of heavy metals bio-accumulation in the study area.


2019 ◽  
Vol 22 (1) ◽  
pp. 1
Author(s):  
Andini Komalasari ◽  
Budi Afriyansyah ◽  
Muhammad Ihsan ◽  
Mohammad Agung Nugraha

Bioaccumulation of Pb and Cu Heavy Metals to Penaeus merguiensis in the Waters of Inner Kelabat BayThe waters of Kelabat Bay has a wealth of marine resources that is quite important in supporting the economy of Bangka Regency and West Bangka Regency. The purpose of this research was to measure the concentration of heavy metals Pb and Cu (sea water, sediment, and Penaeus merguiensis) and measure the ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu. Heavy metals Pb and Cu in Water, sediments and Penaeus merguiensis analyzed using Flame Atomic Absorption Spectrophotometer (Flame AAS). The results showed that concentration of heavy metals in water with an average range of Pb (0,1042-0,1748 mg/L) and Cu (0,000013-0,000021 mg/L). Average concentration of heavy metals in Pb sediments (7,15-7,73 mg/kg) and Cu (0,0016-0,00219 mg/kg ). Average concentration of Pb heavy metals in Penaeus merguiensis (1,34-1,54 mg/kg) and Cu (0,0003-0,00045 mg/kg). The average ability of Penaeus merguiensis in accumulating heavy metals Pb and Cu is 15,83 to water and 0,19 to sediment. The value of the Bioconcentration Factor is below 250 (FBK <250) so it falls into the low category. Penaeus merguiensis is more exposed to heavy metals dissolved in water than those released from sediment.Perairan Teluk Kelabat memiliki kekayaan sumber daya laut yang cukup penting dalam mendukung perekonomian Kabupaten Bangka dan Kabupaten Bangka Barat. Penelitian ini bertujuan untuk mengukur kandungan logam berat Pb dan Cu (air laut, sedimen, dan Penaeus merguiensis) dan mengukur kemampuan Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu. Logam berat Pb dan Cu padaair, sedimen dan Penaeus merguiensisdianalisis menggunakan Flame Atomic Absorption Spectrophotometer (Flame AAS). Hasil penelitian menunjukkan bahwa konsentrasi logam berat dalam air dengan kisaran rata-rata Pb (0,1042-0,1748 mg/L) dan Cu (0,000013-0,000021 mg/L). Kisaran konsentrasi rata-rata logam berat dalam sedimen Pb (7,15-7,73 mg/kg) dan Cu (0,0016-0,00219 mg/kg). Kisaran konsentrasi rata-rata logam berat Pb di Penaeus merguiensis (1,34-1,54 mg/kg) dan Cu (0,0003-0,00045 mg/kg). Kemampuan rata-rata Penaeus merguiensis dalam mengakumulasi logam berat Pb dan Cu yaitu 15,83 terhadap air dan 0,19 terhadap sedimen. Nilai Faktor Biokonsentrasi tersebut di bawah 250 (FBK< 250) sehingga masuk dalam kategori rendah. Penaeus merguiensis lebih banyak terpapar logam berat yang terlarut dalam air daripada yang terlepas dari sedimen. 


2012 ◽  
Vol 610-613 ◽  
pp. 1194-1198
Author(s):  
Yue Han Li ◽  
Ai Rong Zheng ◽  
Zhi Kai Ma

Contents and distributions of heavy metals in surface sediments from the northern Beibu Gulf were analyzed using atomic absorption spectrophotometer. The results showed that the contents of Cu, Pb, Zn, Cr and Cd were 14.22~26.68, 31.85~54.59, 60.19~90.93, 29.95~67.95 and 0.030~0.130 µg•g–1, respectively, and average were 18.21, 38.88, 78.00, 48.46 and 0.09µg•g–1. The reducing environments in northern Beibu Gulf were attributed to organic matters and sulfide. The distributions of heavy metals showed the trend of higher along the coastal area and lower in the offshore area, generally controlled by terrestrial inputs, as well as hydrological conditions, depositional environments and so on.


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