Assessment of High-Temperature Hydrogen Attack Using Advanced Ultrasonic Array Techniques

2020 ◽  
pp. 1223-1238
Author(s):  
Mark G. Lozev ◽  
G.A. Neau ◽  
L. Yu ◽  
T.J. Eason ◽  
S.E. Orwig ◽  
...  

The ability to measure early-stage high-temperature hydrogen attack (HTHA) has been improved by the use of optimized ultrasonic array probes and techniques. First, ultrasonic modeling and simulations were performed to design a set of array probes. The data was then collected using phased array ultrasonic testing (PAUT) and full matrix capture (FMC) techniques. Damage visualization, characterization, and sizing was completed with PAUT, total focusing method (TFM), and adaptive total focusing method (ATFM) advanced algorithms. The detection and sizing capabilities were initially validated on steel calibration samples with micromachined defects and synthetic HTHA damage. Vessels with suspected HTHA damage were removed from service, inspected with multiple array techniques, and then destructively evaluated for a results comparison with metallographic images. This study concluded that the FMC/TFM/ATFM techniques and algorithms improve detectability, characterization, and sizing of early-stage HTHA damage as compared to PAUT.

Author(s):  
Charles Le Nevé ◽  
Sophie Loyan ◽  
Léonard Le Jeune ◽  
Steve Mahaut ◽  
Serge Demonte ◽  
...  

Abstract In petroleum industry, hydrogen is used in many assets. With temperature and pressure, hydrogen can damage materials. This damage is called High Temperature Hydrogen Attack (HTHA) and is a time dependent degradation mechanism that can affect the integrity of steels used for pressure containment operating above about 400°F (204°C). HTHA has caused major accidents in Petroleum Industry. API RP 941 [1] currently provides guidance for steel selection (and so susceptibility to attack) in relation to temperature and ppH2 via Nelson curves. In the last edition, 4 stages of degradation for both base metal and weld metal are described. In the past, only stage III was detectable by the combination of different Ultrasonic methods which were known as AUBT – Advanced Ultrasonic Backscatter Technique. But, capability of detection was limited to defects above 500–1000μm, correspondent to small fissures. So, it was impossible to detect early stage of degradation as steel grain size (around 50μm). For several years, performances of non-destructive techniques have rapidly increased and new advanced ultrasonic technologies are available such as: - Phased Array Ultrasonic Techniques (PAUT) - Time Of Flight Diffraction (TOFD) - Total Focusing Method (TFM) This paper describes latest techniques and results obtained by Total and French Welding Institute in laboratory, and discuss the efficiency of the methods, over real HTHA degradation blocks. An overview of TFM is also proposed by CEA who work on innovating development to increase the performance of this technique.


2021 ◽  
Author(s):  
Xuemei Cheng ◽  
Shuyun Cao

<p>Within orogenic zone and continental extensional area, it often developed metamorphic complex or metamorphic gneiss dome that widely exposed continental mid-lower crustal rocks, which is an ideal place to study exhumation processes of deep-seated metamorphic complex and rheology. The Yuanmou metamorphic complex is located in the south-central part of the "Kangdian Axis" in the western margin of Qiangtang Block and Yangtze Block, which is a part of the anticline of the Sichuan-Yunnan platform. Many research works mainly focus on the discussion of intrusion ages, aeromagnetic anomalies, and polymetallic deposits. However, the exhumation process and mechanism of the Yuanmou metamorphic complex are rarely discussed and still unclear. This study, based on detailed field geological observations, optical microscopy (OM), cathodoluminescence (CL), electron backscatter diffraction (EBSD) and electron probe (EMPA) were performed to illustrate the geological structure features, deformation-metamorphic evolution process and its tectonic significance of Yuanmou metamorphic complex during the exhumation process. All these analysis results indicate that the Yuanmou metamorphic complex generally exhibits a dome structure with deep metamorphic rocks and deformed rocks of varying degrees widely developed. Mylonitic gneiss and granitic intrusions are located in the footwall of the Yuanmou, which have suffered high-temperature shearing. The mylonitic fabrics and mineral stretching lineations in the deformed rock are strongly developed, forming typical S-L or L-shaped structural features. The high-temperature ductile deformation-metamorphism environment is high amphibolite facies, that is, the temperature range is between 620 ~ 690 ℃ and the pressure is between 0.8 ~ 0.95 Gpa. In the deformed rocks closed to the detachment fault, some of the mylonite fabric features are retained, but most of them have experienced a strongly overprinted retrogression metamorphism and deformation. At the top of the detachment fault zone, it is mainly composed of cataclasites and fault gouge. The comprehensive macro- and microstructural characteristics, geometry, kinematics, and mineral (amphibole, quartz and calcite) EBSD textures indicate that the Yuanmou metamorphic complex has undergone a progressive exhumation process during regional extension, obvious high-temperature plastic deformation-metamorphism in the early stage, and superimposed of low-temperature plastic-brittle and brittle deformation in the subsequent stage, which is also accompanied by strong fluid activities during the exhumation process.</p>


Author(s):  
Jia Qianqian ◽  
Guo Chao ◽  
Li Jianghai ◽  
Qu Ronghong

The nuclear power plant with two modular high-temperature gas-cooled reactors (HTR-PM) is under construction now. The control room of HTR-PM is designed. This paper introduces the alarm displays in the control room, and describes some verification and validation (V&V) activities of the alarm system, especially verification for some new human factor issues of the alarm system in the two modular design. In HTR-PM, besides the regular V&V similar to other NPPs, the interference effect of the alarm rings of the two reactor modules at the same time, and the potential discomfort of the two reactor operators after shift between them are focused. Verifications at early stage of the two issues are carried on the verification platform of the control room before the integrated system validation (ISV), and all the human machine interfaces (HMIs) in the control room, including the alarm system are validated in ISV. The test results on the verification platform show that the alarm displays and rings can support the operators understand the alarm information without confusion of the two reactors, and the shift between the two reactor operators have no adverse impact on operation. The results in ISV also show that the alarm system can support the operators well.


2010 ◽  
Author(s):  
Yoshikazu Ohara ◽  
Yohei Shintaku ◽  
Satoshi Horinouchi ◽  
Makoto Hashimoto ◽  
Yuichi Yamaguchi ◽  
...  

2021 ◽  
Author(s):  
Ehsan Mohseni ◽  
Randika Vithanage ◽  
Zhen Qiu ◽  
Yashar Javadi ◽  
David Lines ◽  
...  

2021 ◽  
Vol 1035 ◽  
pp. 539-544
Author(s):  
Zhao Ran Zheng ◽  
Kang Yuan

MCrAlY can be used as bond coats for thermal barrier coatings (TBCs) with good ductility and excellent resistance against high temperature oxidation and hot corrosion. The behavior of the thermally grown oxide (TGO) scale formed at the MCrAlY coatings plays a key role on the oxidation resistance. In this paper, the oxidation kinetic curves of a MCrAlY coating at 900~1000 °C were obtained by measuring the thickness of the TGO scales. The curves basically conveyed parabolic laws, indicating a diffusion-controlled mechanism of the TGO growth. The thickness of TGO was positively correlated with the consumption of β phase during the early stage of the oxidation processes. After about the half-life of the β phase consumption, the depletion of the β phase significantly accelerated, which was caused by coating-substrate interdiffusion. In addition, the microstructure of the TGO was analyzed


Materials ◽  
2020 ◽  
Vol 13 (9) ◽  
pp. 2104 ◽  
Author(s):  
Hediyeh Dabbaghi ◽  
Keyvan Safaei ◽  
Mohammadreza Nematollahi ◽  
Parisa Bayati ◽  
Mohammad Elahinia

In this study, the effect of the addition of Hf on the oxidation behavior of NiTi alloy, which was processed using additive manufacturing and casting, is studied. Thermogravimetric analyses (TGA) were performed at the temperature of 500, 800, and 900 °C to assess the isothermal and dynamic oxidation behavior of the Ni50.4Ti29.6Hf20 at.% alloys for 75 h in dry air. After oxidation, X-ray diffraction, scanning electron microscopy, and energy-dispersive X-ray spectroscopy were used to analyze the oxide scale formed on the surface of the samples during the high-temperature oxidation. Two stages of oxidation were observed for the NiTiHf samples, an increasing oxidation rate during the early stage of oxidation followed by a lower oxidation rate after approximately 10 h. The isothermal oxidation curves were well matched with a logarithmic rate law in the initial stage and then by parabolic rate law for the next stage. The formation of multi-layered oxide was observed for NiTiHf, which consists of Ti oxide, Hf oxide, and NiTiO3. For the binary alloys, results show that by increasing the temperature, the oxidation rate increased significantly and fitted with parabolic rate law. Activation energy of 175.25 kJ/mol for additively manufactured (AM) NiTi and 60.634 kJ/mol for AM NiTiHf was obtained.


2010 ◽  
Vol 645-648 ◽  
pp. 375-378 ◽  
Author(s):  
Valdas Jokubavicius ◽  
Justinas Palisaitis ◽  
Remigijus Vasiliauskas ◽  
Rositza Yakimova ◽  
Mikael Syväjärvi

Different sublimation growth conditions of 3C-SiC approaching a bulk process have been investigated with the focus on appearance of macrodefects. The growth rate of 3C-SiC crystals grown on 6H-SiC varied from 380 to 460 μm/h with the thickness of the crystals from 190 to 230 μm, respectively. The formation of macrodefects with void character was revealed at the early stage of 3C-SiC crystal growth. The highest concentration of macrodefects appears in the vicinity of the domain in samples grown under high temperature gradient and fastest temperature ramp up. The formation of macrodefects was related to carbon deficiency which appear due to high Si/C ratio which is used to enable formation of the 3C-SiC polytype.


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