scholarly journals Efficient N2- and O2-Sensing Properties of PtSe2 With Proper Intrinsic Defects

2021 ◽  
Vol 9 ◽  
Author(s):  
Xin Yong ◽  
Jianqi Zhang ◽  
Xiangchao Ma ◽  
Weiming He

Developing efficient N2 and O2 gas sensors is of great importance to our daily life and industrial technology. In this work, first-principles calculations are performed to study the N2 and O2 gas-sensing properties of pure and defected PtSe2. It is found that both N2 and O2 adsorb weakly on pure PtSe2, and adsorption of the molecules induces negligible changes in the electrical and optical properties. Whereas the Pt@Se anti-site defect significantly improves the N2 adsorption capacity of PtSe2 and induces notable changes in the electrical property. Similar results are also observed for the Pt and Se vacancies and Pt@Se anti-site defects when examining O2 adsorption. In addition, notable changes in the optical absorption spectra of the PtSe2 with Pt@Se defect are induced upon N2 adsorption, which also occurs for PtSe2 with Pt and Se vacancies and Pt@Se anti-site defects upon O2 adsorption. These results demonstrate that PtSe2 with the corresponding defects can be both excellent electrical and optical sensors for detecting N2 and O2 gases. Our work offers a new avenue for preparing efficient gas sensors.

2019 ◽  
Vol 21 (21) ◽  
pp. 11455-11463 ◽  
Author(s):  
Wenfeng Pan ◽  
Ning Qi ◽  
Bin Zhao ◽  
Sheng Chang ◽  
Shizhuo Ye ◽  
...  

An investigation of the transport and optical properties of buckled bismuthene with different adsorbed gas molecules.


2019 ◽  
Vol 806 ◽  
pp. 1052-1059 ◽  
Author(s):  
Zhong Li ◽  
ZhengJun Yao ◽  
Azhar Ali Haidry ◽  
Tomas Plecenik ◽  
Branislav Grancic ◽  
...  

Sensors ◽  
2019 ◽  
Vol 19 (15) ◽  
pp. 3323 ◽  
Author(s):  
Jae-Hyoung Lee ◽  
Thanh-Binh Nguyen ◽  
Duy-Khoi Nguyen ◽  
Jae-Hun Kim ◽  
Jin-Young Kim ◽  
...  

The gas sensing properties of two novel series of Mg-incorporated metal–organic frameworks (MOFs), termed Mg-MOFs-I and -II, were assessed. The synthesized iso-reticular type Mg-MOFs exhibited good crystallinity, high thermal stability, needle-shape morphology and high surface area (up to 2900 m2·g−1), which are promising for gas sensing applications. Gas-sensing studies of gas sensors fabricated from Mg-MOFs-II revealed better sensing performance, in terms of the sensor dynamics and sensor response, at an optimal operating temperature of 200 °C. The MOF gas sensor with a larger pore size and volume showed shorter response and recovery times, demonstrating the importance of the pore size and volume on the kinetic properties of MOF-based gas sensors. The gas-sensing results obtained in this study highlight the potential of Mg-MOFs gas sensors for the practical monitoring of toxic gases in a range of environments.


1999 ◽  
Vol 119 (2) ◽  
pp. 103-107 ◽  
Author(s):  
Takeo Hyodo ◽  
Keiko Okamoto ◽  
Yuji Takao ◽  
Yasuhiro Shimizu ◽  
Makoto Egashira

2020 ◽  
Vol MA2020-01 (28) ◽  
pp. 2114-2114
Author(s):  
Mykhailo Vorokhta ◽  
Pavel Hozak ◽  
Ivan Khalakhan ◽  
Martin Vrnata ◽  
Ján Lančok ◽  
...  

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 785 ◽  
Author(s):  
Wen-Dong Zhou ◽  
Davoud Dastan ◽  
Jing Li ◽  
Xi-Tao Yin ◽  
Qi Wang

Metal oxide semiconductor (MOS) gas sensors have the advantages of high sensitivity, short response-recovery time and long-term stability. However, the shortcoming of poor discriminability of homogeneous gases limits their applications in gas sensors. It is well-known that the MOS materials have similar gas sensing responses to homogeneous gases such as CO and H2, so it is difficult for these gas sensors to distinguish the two gases. In this paper, simple sol–gel method was employed to obtain the ZnO–xNiO composites. Gas sensing performance results illustrated that the gas sensing properties of composites with x > 0.425 showed a p-type response to both CO and H2, while the gas sensing properties of composites with x < 0.425 showed an n-type response to both CO and H2. However, it was interesting that ZnO–0.425NiO showed a p-type response to CO but an discriminable response (n-type) to H2, which indicated that modulating the p-type or n-type semiconductor concentration in p-n composites could be an effective method with which to improve the discriminability of this type of gas sensor regarding CO and H2. The phenomenon of the special gas sensing behavior of ZnO–0.425NiO was explained based on the experimental observations and a range of characterization techniques, including XRD, HRTEM and XPS, in detail.


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