scholarly journals Processing and Preparation Method for High-Quality Opto-Electronic Perovskite Film

2021 ◽  
Vol 8 ◽  
Author(s):  
Zheng Chen ◽  
Ping He ◽  
Dan Wu ◽  
Chen Chen ◽  
Muhammad Mujahid ◽  
...  

The key to improving the energy conversion efficiency of perovskite solar cells lies in the optimization of the film morphology. The optical and electrical properties of the perovskite film, such as light absorption, carrier diffusion length, and charge transport, are all directly affected by the film morphology. Therefore, this review starts from the perovskite solar cells structure, and it summarizes the state-of-art perovskite film fabrication technologies and the caused film morphology to the performance perovskite solar cells. The spin coating method has an enormous waste of materials and only a small area of the device can be utilized. It is difficult to be used in commercial manufacturing. However, due to the high efficiency of this preparation method, it is irreplaceable in the initial research and development of perovskite materials, and so this method will be popular for a long time in the laboratory. Chemical vapor deposition and thermal vapor deposition have high technical requirements and a good repeatability of processing and manufacturing, and large-scale production can be realized. It may be the first technology to admit industrial application; the scratch coating method and slot-die have significant technical aspects. The similarity of the roll-to-roll manufacturing technology is also an efficient preparation method. Still, to achieve high-efficiency devices, it is necessary to consider the thickness control of each functional layer, and to find or prepare perovskite paste. Finally, we summarized the various fabrication processes and the prospects for the commercialization of perovskite solar cells. We predict that to achieve the commercialization of perovskite solar cells, the existing fabrication technologies should be optimized and more studies should be conducted.

2020 ◽  
Vol 2 (1) ◽  
pp. 049-049

Aim & Scope: Metal halide perovskitehave been regarded as promising classes of materials for photovoltaics and optoelectronic devices, owing to the unique characteristics, such as long charge carrier diffusion lengths, precise tunable bandgaps, high light absorption coefficients, and high defect tolerance. Research on perovskite in the fields including photovoltaics, light-emitting diodes, lasers, X-ray imaging, and photodetectors has been gaining increasingly interest over the past years. Up to now, the efficiency of perovskite solar cells has grown from 3.8% in single-junction solar cells in 2009 to more than 25%, catching up the efficiency level of commercial silicon cells. Up to now, the key issues of perovskite photovoltaics and optoelectronic devices have become the stability, performance and large-scale production. This requires optimization of the film morphology, interface, device structure and the fabrication process. A lot work has been done on this issue and has made remarkable progress. We kindly invite you to submit a manuscript(s) for this Special Issue. Full papers, communications, and reviews are all welcome.


Crystals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1521
Author(s):  
Jiabin Hao ◽  
Zeming Wang ◽  
Huiying Hao ◽  
Guanlei Wang ◽  
Hongcheng Gao ◽  
...  

So far, it is still a great challenge to prepare high efficiency organic–inorganic perovskite solar cells in ambient air. Specifically, moisture is easily combined with the perovskite material during the spin-coating process, which result in porous perovskite films with poor surface morphology. In this study, we investigated crystalline Ag-doped perovskite films by a one-step spin-coating method in air with 30–40% relative humidity (RH), in which ethyl acetate (EA) was used as antisolvent can absorb moisture in air to reduced nucleation density. More significantly, EA is a feasible and environmentally friendly solvent to replace highly toxic solvent. Moreover, 1.0% Ag-doped device shows a highest power conversion efficiency (PCE) of 14.36%. The improved performance is not only ascribed to the superior CH3NH3PbI3 film with high crystallinity but to the versatile tunability of energy band structure.


2022 ◽  
Vol 100 ◽  
pp. 106374
Author(s):  
Yinan Lao ◽  
Wei Luo ◽  
Zehao Zhang ◽  
Yuqing Zhang ◽  
Duo Wang ◽  
...  

Crystals ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 295
Author(s):  
Tianzhao Dai ◽  
Qiaojun Cao ◽  
Lifeng Yang ◽  
Mahmoud Aldamasy ◽  
Meng Li ◽  
...  

Perovskite solar cells (PSCs) have received a great deal of attention in the science and technology field due to their outstanding power conversion efficiency (PCE), which increased rapidly from 3.9% to 25.5% in less than a decade, comparable to single crystal silicon solar cells. In the past ten years, much progress has been made, e.g. impressive ideas and advanced technologies have been proposed to enlarge PSC efficiency and stability. However, this outstanding progress has always been referred to as small-area (<0.1 cm2) PSCs. Little attention has been paid to the preparation processes and their micro-mechanisms for large-area (>1 cm2) PSCs. Meanwhile, scaling up is an inevitable way for large-scale application of PSCs. Therefore, we firstly summarize the current achievements for high efficiency and stability large-area perovskite solar cells, including precursor composition, deposition, growth control, interface engineering, packaging technology, etc. Then we include a brief discussion and outlook for the future development of large-area PSCs in commercialization.


2015 ◽  
Vol 3 (23) ◽  
pp. 12443-12451 ◽  
Author(s):  
Paifeng Luo ◽  
Zhaofan Liu ◽  
Wei Xia ◽  
Chenchen Yuan ◽  
Jigui Cheng ◽  
...  

A simple ITCVD method is developed to fabricate PSCs, and their roll-over phenomenon in J–V curves is first investigated.


2020 ◽  
Vol 11 ◽  
pp. 51-60 ◽  
Author(s):  
Xianfeng Dai ◽  
Ke Xu ◽  
Fanan Wei

Perovskite solar cells (PSCs) are set to be game changing components in next-generation photovoltaic technology due to their high efficiency and low cost. In this article, recent progress in the development of perovskite layers, which are the basis of PSCs, is reviewed. Achievements in the fabrication of high-quality perovskite films by various methods and techniques are introduced. The reported works demonstrate that the power conversion efficiency of the perovskite layers depends largely on their morphology and the crystalline quality. Furthermore, recent achievements concerning the scalability of perovskite films are presented. These developments aim at manufacturing large-scale perovskite solar modules at high speed. Moreover, it is shown that the development of low-dimensional perovskites plays an important role in improving the long-term ambient stability of PSCs. Finally, these latest advancements can enhance the competitiveness of PSCs in photovoltaics, paving the way for their commercialization. In the closing section of this review, some future critical challenges are outlined, and the prospect of commercialization of PSCs is presented.


Energies ◽  
2019 ◽  
Vol 12 (23) ◽  
pp. 4508
Author(s):  
Chongqiu Yang ◽  
Xiaobiao Shan ◽  
Tao Xie

Low-cost, high-efficiency perovskite solar cells (PSCs) have the distinguished potential to be next commercialized photovoltaic devices. Chemical vapor deposition (CVD) process was regarded as an excellent choice as compared to solution deposition technique, however, the photovoltaic and stable performance of the former lags behind that of the latter. In this work, we propose a facile CVD pattern to fabricate PSCs, substrates covered by lead iodide (PbI2) sandwich-surrounded by the source methyl-ammonium iodide (CH3NH3I, MAI) powder. Heat and mass transfer, surface reactions are involved in the CVD deposition procedure. Numerical calculations present a uniform distribution of MAI vapor, contributing to homogeneous perovskite films with comparable surface morphologies, crystal structures and photovoltaic performances, despite of the notorious hysteresis. Herein, a PCBM ([6,6]-Phenyl C61 butyric acid methyl ester) interlayer is introduced before the PbI2 coating and the CVD process. Results show that even suffered from the torturous CVD procedure, the PCBM interlayer still works to passivating the bulk and interfacial recombination, reducing the hysteresis, improving the grain structure of perovskite films. Hence, the photovoltaic performance of PSCs enhances by 30%, and the filling factor difference between the forward and the reverse scan reduces to 6%.


2021 ◽  
Author(s):  
Meidan Que ◽  
Boyue Zhang ◽  
Jin Chen ◽  
Xingtian Yin ◽  
Sining Yun

The cost-effective processability and high stability of carbon-based perovskite solar cells (C-PSCs) have shown a tremendous potential to positively devote to the development of large-scale production process. However, prior to...


Sign in / Sign up

Export Citation Format

Share Document