scholarly journals Controlled Release of Zinc from Soy Protein-Based Matrices to Plants

Agronomy ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 580
Author(s):  
Mercedes Jiménez-Rosado ◽  
Victor Perez-Puyana ◽  
Antonio Guerrero ◽  
Alberto Romero

Controlled release systems are increasing their presence on the market. However, their use is not generating a great impact on horticultural production, mainly due to their price, which makes crop production more expensive. This work proposes a cheaper alternative for the manufacture of these devices. Thus, an agri-food byproduct (soy protein isolate) and a thermomechanical processing were used to create devices (matrices) that can compete in price with the use of conventional fertilizers (0.50–2.00 €/kg). First, different processing methods were evaluated to obtain the matrix with the most optimal mechanical, functional (zinc and water retention/release, biodegradability) and morphological (zinc distribution) properties for the supply of zinc (micronutrient). This was achieved by incorporating an ethanol immersion step into the processing to remove the plasticizer before its use in horticulture. Finally, the efficiency of these matrices was verified in crops (lettuce and peppers), improving up to 60% the assimilation of zinc by plants that conventional fertilization achieves. In addition, these matrices allow a 33% reduction in the water used during cultivation. This work has opened a new possibility of creating more efficient devices for the incorporation of fertilizers into crops, also having an affordable price for industrial use.

2009 ◽  
Vol 13 (1) ◽  
pp. 8-21 ◽  
Author(s):  
Abhisek Sasmal ◽  
Preetishree Nayak ◽  
Rajashree Nanda ◽  
P. L. Nayak ◽  
S. Sasmal ◽  
...  

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1807
Author(s):  
Estefanía Álvarez-Castillo ◽  
José Manuel Aguilar ◽  
Carlos Bengoechea ◽  
María Luisa López-Castejón ◽  
Antonio Guerrero

Composite materials based on proteins and carbohydrates normally offer improved water solubility, biodegradability, and biocompatibility, which make them attractive for a wide range of applications. Soy protein isolate (SPI) has shown superabsorbent properties that are useful in fields such as agriculture. Alginate salts (ALG) are linear anionic polysaccharides obtained at a low cost from brown algae, displaying a good enough biocompatibility to be considered for medical applications. As alginates are quite hydrophilic, the exchange of ions from guluronic acid present in its molecular structure with divalent cations, particularly Ca2+, may induce its gelation, which would inhibit its solubilization in water. Both biopolymers SPI and ALG were used to produce composites through injection moulding using glycerol (Gly) as a plasticizer. Different biopolymer/plasticizer ratios were employed, and the SPI/ALG ratio within the biopolymer fraction was also varied. Furthermore, composites were immersed in different CaCl2 solutions to inhibit the amount of soluble matter loss and to enhance the mechanical properties of the resulting porous matrices. The main goal of the present work was the development and characterization of green porous matrices with inhibited solubility thanks to the gelation of alginate.


Author(s):  
Ozan Tas ◽  
Ulku Ertugrul ◽  
Mecit Halil Oztop ◽  
Bekir Gokcen Mazı

e-Polymers ◽  
2021 ◽  
Vol 21 (1) ◽  
pp. 433-442
Author(s):  
Hua He ◽  
Rui-jing Jia ◽  
Kai-qiang Dong ◽  
Jia-wen Huang ◽  
Zhi-yong Qin

Abstract A novel biodegradable protein-based material (UMSPIE) that consists of natural polymer soy protein isolate (SPI), ultrasonic-modified montmorillonite (UMMT), and ethylene glycol diglycidyl ether (EGDE) was produced by solution casting. Fourier infrared spectroscopy (FTIR), X-ray diffraction (XRD), thermogravimetric analysis (TG), and scanning electron microscopy (SEM) were used to characterize the chemical structure and micro-morphologies of as-synthesized protein-based composite films. The results showed that the interlayer structure of MMT was destroyed by ultrasonic treatment, and the hydrogen bonding between SPI chains and the ultrasound-treated MMT plates was enhanced. The synergistic effect of UMMT and EGDE on SPI molecules made the network structure of the UMSPIE film denser. In addition, the mechanical and barrier properties of the as-synthesized films were explored. Compared with pure soy protein film, the tensile strength of the UMSPIE film has an increase of 266.82% (increasing from 4.4 to 16.14 MPa). From the above, the modified strategy of layered silicates filling combining crosslinking agents is considered as an effective method to improve the functional properties of bio-based polymer composites.


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