scholarly journals Thermoluminescence Analysis of the Clay Core of Bronze Statues: A Re-Appraisal of the Case Studies of Lupa Capitolina and Other Masterpieces in Rome

2021 ◽  
Vol 11 (17) ◽  
pp. 7820
Author(s):  
Marco Martini ◽  
Anna Galli

In this work, we present some new results in applying thermoluminescence (TL) dating to the clay core of bronze statues. This is very important, due to the impossibility of directly dating a metal. Very few cases of indirect dating of clay cores by TL are reported in the literature. We re-considered three cases of dating of clay core from important bronzes in Rome. The parameters to be considered were not easy to calculate in the case of the Lupa Capitolina. However, its traditionally reported Etruscan origin is definitely ruled out, even if the accuracy in the dating is too low to precisely propose a date of the casting. The comparison with radiocarbon results shows good agreement for a Medieval dating. Two other bronze statues were analysed in order to date their casting by TL; a horse from Musei Capitolini resulted to have been cast in the Greek classical period, excluding its casting in the Rome imperial period. A third study shows that, in particularly favourable situations, TL dating of clay core can give rather precise results. This is the case where in the clay core are present materials that behave like good dosimeters, as generally happens in dating ceramics. Furthermore, the possibility of measuring all the parameters influencing the calculation of the dose rate is essential; both the external radiation sources and the radiation reduction by the water content must be taken into account. This was the case of Saint Peter in the Vatican that turned out to be a cast from the beginning of the XIV century.

ANRI ◽  
2020 ◽  
pp. 31-44
Author(s):  
Aleksey Ekidin ◽  
Aleksey Vasil'ev ◽  
Maksim Vasyanovich ◽  
Evgeniy Nazarov ◽  
Mariya Pyshkina ◽  
...  

The article presents the results of field studies in the area of the Belarusian NPP in the pre-operational period. The «background» contents of gamma-emitting radionuclides in individual components of the environment are determined. The main array of dose rate measurements in the area of the NPP construction site is in the range 0.048 ÷ 0.089 μSv/h. External radiation in the surveyed area is formed at 96% due to 40K, 226Ra and 232Th. The information obtained can be used to correctly interpret the data of future radiation monitoring during normal operation of nuclear power plants.


Author(s):  
Tomoharu Hashimoto ◽  
Masahiro Kondo ◽  
Ryuichi Tayama ◽  
Hideho Gamo

The Japanese government plans to conduct decontamination tasks in radioactively contaminated areas. For such a situation, we developed a system that evaluates radiation dose rates in a wide radioactively contaminated area by utilizing our radiation dose evaluation technology. This system can not only generate present maps of radiation dose rate in the air based on the dose rate measured at the surface of the contaminated areas, but can also quickly calculate the reduction effect of dose rate due to decontamination tasks by entering decontamination factors. The system can then formulate decontamination plans and make it possible to plan measures to reduce radiation exposure for workers and local residents. Radioactive nuclides that contribute to gamma-ray dose rate are mainly Cs-134 and Cs-137 in soil, on trees, buildings, and elsewhere. Shapes of such radiation sources are assumed to be 10m square or 100m square. If it is unsuitable that the radiation sources assume to squares, the radiation sources can assume to point. The relation between distance from the surface or point source and the radiation dose rate is calculated using MCNP5 code (A General Monte Carlo N-Particle Transport Code - Version 5), and approximated using four-parameter empirical formula proposed by Harima et al. In addition, the system can consider shielding such as soil, concrete, and iron. When setting such shielding, the skyshine dose rate is taken into account in dose rate calculation.


2019 ◽  
Vol 187 (2) ◽  
pp. 249-261
Author(s):  
J Lahtinen ◽  
J Koivukoski

Abstract Finland has a long history in monitoring external radiation. Regular monitoring began in the early 1960s when the first networks measuring exposure rates were established. Today the nation-wide network is fully automatic and consists of about 260 stations with Geiger-Műller (GM) tubes. Some 25 stations also have a LaBr3 spectrometer. In this article the authors describe the history, experiences and major development stages of the Finnish dose rate monitoring arrangements and also have a brief look at the possible future.


2011 ◽  
Vol 11 (3) ◽  
pp. 911-920 ◽  
Author(s):  
G. J. Engelhart ◽  
L. Hildebrandt ◽  
E. Kostenidou ◽  
N. Mihalopoulos ◽  
N. M. Donahue ◽  
...  

Abstract. The composition and physical properties of aged atmospheric aerosol were characterized at a remote sampling site on the northern coast of Crete, Greece during the Finokalia Aerosol Measurement Experiment in May 2008 (FAME-2008). A reduced Dry-Ambient Aerosol Size Spectrometer (DAASS) was deployed to measure the aerosol water content and volumetric growth factor of fine particulate matter. The particles remained wet even at relative humidity (RH) as low as 20%. The aerosol was acidic during most of the measurement campaign, which likely contributed to the water uptake at low RH. The water content observations were compared to the thermodynamic model E-AIM, neglecting any contribution of the organics to aerosol water content. There was good agreement between the water measurements and the model predictions. Adding the small amount of water associated with the organic aerosol based on monoterpene water absorption did not change the quality of the agreement. These results strongly suggest that the water uptake by aged organic aerosol is relatively small (a few percent of the total water for the conditions during FAME-08) and generally consistent with what has been observed in laboratory experiments. The water concentration measured by a Q-AMS was well correlated with the DAASS measurements and in good agreement with the predicted values for the RH of the Q-AMS inlet. This suggests that, at least for the conditions of the study, the Q-AMS can provide valuable information about the aerosol water concentrations if the sample is not dried.


2015 ◽  
Vol 749 ◽  
pp. 8-12
Author(s):  
Eva Scholtzová ◽  
Daniel Tunega

The DFT method was used for modeling a partial decomposition of the structure of the thaumasite mineral. The four models with a consecutive decreasing of water content were prepared (T12 – 100 %, T9 – 75 %, T6 – 50 %, T3 – 25 %) and corresponding decomposition enthalpies were calculated. The results showed a good agreement with available experimental data for the decomposition reaction of the thaumasite structure.


1972 ◽  
Vol 27 (8-9) ◽  
pp. 1323-1328 ◽  
Author(s):  
C. Donner ◽  
T. Tamberg

Abstract Alkyl iodides especially methyl iodide from the offgas of reactors and of reprocessing plants are difficult to remove.In earlier investigations it was shown that silver zeolites are qualified for a total fixation of methyl iodide, only when these sieves were exhaustively loaded with silver ions.In order to explain why only exhaustively loaded silver zeolites of type X are able to remove methyl iodide completely from the air, the reaction products from the chemisorption reaction were identified. The proportion of the silver ions that had reacted was calculated.Exhaustively loaded Ag-LMS-X pellets heat-treated at 400 °C (water content 0.94% by wt.) react with CH3I to form dimethylether.If the same pellets were gently dried with P2O5 (water content 15% by wt.) dimethylether and methanol were the products.The identification was done by gas chromatography and infrared spectroscopy.The chemisorption reaction can be described in the following way:a) CH3I + HOH+Ag+ →AgI + CH3OH + H+b) CH3I + CH3OH+Ag+ → AgI + CH3OCH3 + H+If only small concentrations of methyl-iodide and an excess of water vapour are present only methanol is expected.The experimental results are in good agreement with the assumptions.


Sign in / Sign up

Export Citation Format

Share Document