scholarly journals Hydrogen-Assisted Thermocatalysis over Titanium Nanotube for Oxidative Desulfurization

Catalysts ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 29
Author(s):  
Weiwei Tang ◽  
Yue Yao ◽  
Xiaoqiao Huang
Keyword(s):  
Diffuse Reflectance ◽  
Oxidative Desulfurization ◽  
Molar Ratio ◽  
Optimal Conditions ◽  
X Ray Diffraction ◽  
Step Method ◽  
X Ray ◽  
Diffuse Reflectance Spectra ◽  
Ft Ir ◽  
Catalyst Dosage

Titanium nanotubes were hydrothermally synthesized via a two-step method for ODS (oxidative desulfurization). The catalysts’ structures were characterized by XRD (X-ray diffraction), FT-IR, UV-Vis (UV-Vis diffuse reflectance spectra), NH3-TPD, etc. The effects of O/S molar ratio and catalyst dosage, etc., were systematically investigated. The catalyst exhibited remarkable performance, so that the removal of DBT (dibenzothiophene) was nearly 100% under the optimal conditions in 10 min. Also, the catalysts could be easily reused for six consecutive cycles. The hydrogen-assisted thermocatalytic mechanism over titanium nanotubes for ODS was also studied and an effective reactant concentration (ERC) number of 70.8 was calculated.

Reaction of 2-[(2-aminoethyl)amino]ethanol with pyridine-2-carbaldehyde and complexation of the products with CuII and CdII along with docking studies

2019 ◽  
Vol 75 (7) ◽  
pp. 951-959 ◽  
Author(s):  
Zahra Mardani ◽  
Mohammad Hakimi ◽  
Keyvan Moeini ◽  
Fabian Mohr
Keyword(s):  
Crystal Packing ◽  
Docking Studies ◽  
Molar Ratio ◽  
Distorted Octahedral Geometry ◽  
X Ray Diffraction ◽  
Donor Ligand ◽  
X Ray ◽  
H Nmr ◽  
Distorted Octahedral ◽  
Ft Ir

The reaction between 2-[2-(aminoethyl)amino]ethanol and pyridine-2-carbaldehyde in a 1:2 molar ratio affords a mixture containing 2-({2-[(pyridin-2-ylmethylidene)amino]ethyl}amino)ethanol (PMAE) and 2-[2-(pyridin-2-yl)oxazolidin-3-yl]-N-(pyridin-2-ylmethylidene)ethanamine (POPME). Treatment of this mixture with copper(II) chloride or cadmium(II) chloride gave trichlorido[(2-hydroxyethyl)({2-[(pyridin-2-ylmethylidene)amino]ethyl})azanium]copper(II) monohydrate, [Cu(C10H16N3O)Cl3]·H2O or [Cu(HPMAE)Cl3]·H2O, 1, and dichlorido{2-[2-(pyridin-2-yl)oxazolidin-3-yl]-N-(pyridin-2-ylmethylidene)ethanamine}cadmium(II), [CdCl2(C16H18N4O)] or [CdCl2(POPME)], 2, which were characterized by elemental analysis, FT–IR, Raman and 1H NMR spectroscopy and single-crystal X-ray diffraction. PMAE is potentially a tetradentate N3O-donor ligand but coordinates to copper here as an N2 donor. In the structure of 1, the geometry around the Cu atom is distorted square pyramidal. In 2, the Cd atom has a distorted octahedral geometry. In addition to the hydrogen bonds, there are π–π stacking interactions between the pyridine rings in the crystal packing of 1 and 2. The ability of PMAE, POPME and 1 to interact with ten selected biomolecules (BRAF kinase, CatB, DNA gyrase, HDAC7, rHA, RNR, TrxR, TS, Top II and B-DNA) was investigated by docking studies and compared with doxorubicin.

Synthesis of Posnjakite Nanoparticles in the Presence of a New Capping Agent

2016 ◽  
Vol 35 (5) ◽  
pp. 457-462 ◽  
Author(s):  
Mehdi Bazarganipour ◽  
Mahnaz Sahebi-Harandi ◽  
Masoud Salavati-Niasari
Keyword(s):  
Microwave Power ◽  
Irradiation Time ◽  
Heating Time ◽  
Molar Ratio ◽  
Capping Agent ◽  
X Ray Diffraction ◽  
X Ray ◽  
Methylene Orange ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

AbstractPosnjakite nanoparticles, Cu4SO4(OH)6 · H2O, were synthesized by utilizing a new thio-Schiff base ligand as new capping agent via a microwave approach. The effects of molar ratio, surfactants, heating time and microwave power on morphology of the product were investigated. The as-synthesized posnjakite nanoparticles were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared (FT-IR) spectroscopy and energy dispersive X-ray analysis (EDAX). The effects of different parameters such as the molar ratio, surfactants, microwave power and irradiation time on the morphology of the products were investigated. Moreover, adsorption of methylene orange dye on posnjakite nanoparticles was considered and the uptake percent was determined to be >65% in 200 min.

scholarly journals Ultrasound-Assisted Rapid ZIF-8 Synthesis, Porous ZnO Preparation by Heating ZIF-8, and Their Photocatalytic Activity

2021 ◽  
Vol 2021 ◽  
pp. 1-12
Author(s):  
Pham Dinh Du ◽  
Nguyen Trung Hieu ◽  
Tran Vinh Thien
Keyword(s):  
Photocatalytic Activity ◽  
Room Temperature ◽  
Diffuse Reflectance ◽  
Nitrogen Adsorption ◽  
X Ray Diffraction ◽  
Zeolitic Imidazolate Framework ◽  
X Ray ◽  
Photocatalytic Activities ◽  
Ft Ir ◽  
Adsorption Desorption

Zeolitic imidazolate framework-8 (ZIF-8) is synthesized quickly at room temperature in methanol with the support of ultrasound. Porous ZnO is also prepared via the thermal treatment of ZIF-8. The photocatalytic activities of the obtained materials are demonstrated via methylene blue (MB) decomposition under UV radiation. The obtained materials are characterized by means of X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), nitrogen adsorption/desorption isotherms, UV-Vis diffuse reflectance spectra (DR-UV-Vis), and photoluminescence spectra. The results indicate that ZIF-8 and the materials obtained from ZIF-8 by heating in the air have photocatalytic activity under UV irradiation. The ZnO sample obtained by ZIF-8 calcination at 660°C for 5 h has the highest photocatalytic activity. However, the MB degradation photocatalytic efficiency of the ZnO samples is even lower than that of the ZIF-8 samples, indicating that ZIF-8 is an effective photocatalyst in the treatment of environmental pollution.

scholarly journals Synthesis and Characterization of Zeolite X from Boiler Ash and Aluminum Foil Waste

2021 ◽  
Vol 4 (1) ◽  
pp. 15
Author(s):  
Intan Ayu Safitri ◽  
Iis Siti Jahro
Keyword(s):  
Aluminum Foil ◽  
Degree Of Crystallinity ◽  
Molar Ratio ◽  
X Ray Diffraction ◽  
Zeolite X ◽  
X Ray ◽  
X Zeolite ◽  
Ft Ir ◽  
Boiler Ash

This study aims to determine the effect of the Si/Al molar ratio and the number of Na2EDTA additions on the purity and crystallinity levels of the synthesized zeolite X. zeolite X was synthesized by hydrothermal method at 70°C and 120°C for 3 and 6 hours, respectively. In the synthesis of zeolite X used boiler ash and aluminum foil waste. The results of characterization using Fourier Transform Infra Red (FT-IR) and X-Ray Diffraction (XRD) showed that the level of purity and crystallinity of the synthesized zeolite X was influenced by the variation of Si/Al molar rasio and amount of Na2EDTA addition. The zeolite with the best quality was obtained from the synthesis with a Si/Al molar ratio of 1.6 and the amount of Na2EDTA added as much as 3.0 g. The synthesized zeolite X has a purity level of 75% and a degree of crystallinity with a total intensity of 845.

One- and two-dimensional PbII compounds resulting from reaction of PbBr2 and Pb(SCN)2 with pyrimidine-2-thione

2021 ◽  
Vol 77 (7) ◽  
Author(s):  
Vânia Denise Schwade ◽  
Bárbara Tirloni
Keyword(s):  
Structural Characterization ◽  
Diffuse Reflectance ◽  
Tautomeric Form ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Ft Ir ◽  
Compound Ii

Pyrimidine-2-thione (HSpym) reacts with lead(II) thiocyanate and lead(II) bromide in N,N-dimethylformamide (DMF) to form poly[(μ-isothiocyanato-κ2 N:S)(μ4-pyrimidine-2-thiolato-κ6 N 1,S:S:S:S,N 3)lead(II)], [Pb(C4H3N2S)(NCS)] n or [Pb(Spym)(NCS)] n , (I), and the polymeric one-dimensional (1D) compound catena-poly[[μ4-bromido-di-μ-bromido-(μ-pyrimidine-2-thiolato-κ3 N 1,S:S)(μ-pyrimidine-2-thione-κ3 N 1,S:S)dilead(II)] N,N-dimethylformamide monosolvate], {[Pb2Br3(C4H3N2S)(C4H4N2S)]·C3H7NO} n or {[Pb2Br3(Spym)(HSpym)]·DMF} n , (IIa), respectively. Poly[μ4-bromido-di-μ3-bromido-(μ-pyrimidine-2-thiolato-κ3 N 1,S:S)(μ-pyrimidine-2-thione-κ3 N 1,S:S)dilead(II)], [Pb2Br3(C4H3N2S)(C4H4N2S)] n or [Pb2Br3(Spym)(HSpym)] n , (IIb), could be obtained as a mixture with (IIa) when using a lesser amount of solvent. In the crystal structures of the pseudohalide/halide PbII stable compounds, coordination of anionic and neutral HSpym has been observed. Both Spym− (in the thiolate tautomeric form) and NCS− ligands were responsible for the two-dimensional (2D) arrangement in (I). The Br− ligands establish the 1D polymeric arrangement in (IIa). Eight-coordinated metal centres have been observed in both compounds, when considering the Pb...S and Pb...Br interactions. Both compounds were characterized by FT–IR and diffuse reflectance spectroscopies, as well as by powder X-ray diffraction. Compound (IIa) and its desolvated version (IIb) represent the first structurally characterized PbII compounds containing neutral HSpym and anionic Spym− ligands. After a prolonged time in solution, (IIa) is converted to another compound due to complete deprotonation of HSpym. The structural characterization of (I) and (II) suggests HSpym as a good candidate for the removal of PbII ions from solutions containing thiocyanate or bromide ions.

scholarly journals Pyrolysis Synthesized g-C3N4for Photocatalytic Degradation of Methylene Blue

2013 ◽  
Vol 2013 ◽  
pp. 1-5 ◽  
Author(s):  
Gang Xin ◽  
Yali Meng
Keyword(s):  
Methylene Blue ◽  
Fourier Transform ◽  
Photocatalytic Activity ◽  
Carbon Nitride ◽  
Diffuse Reflectance ◽  
Photogenerated Electron ◽  
X Ray Diffraction ◽  
X Ray ◽  
Ft Ir ◽  
Uv Visible

Graphitic carbon nitride (g-C3N4) was synthesized at 520°C by the pyrolysis of cyanamide, dicyandiamide, and melamine. The samples were characterized by X–ray diffraction (XRD), UV-visible diffuse reflectance spectra, Fourier transform infrared spectroscopy (FT-IR), and elemental analyzer. The photocatalytic activity of g-C3N4was evaluated by the photodegrading experiments of methylene blue (MB). The results indicated that g-C3N4. A photocatalytic mechanism presumed the MB photodegradation over the C3N4photocatalyst is attributed to photogenerated electron impelled multistep reduction of O2.

scholarly journals Sintesis dan Karakterisasi Sifat Optik Eosin Y@Metal- Organic Framework Zirkonium Naftalendikarboksilat

2017 ◽  
Vol 6 (1) ◽  
Author(s):  
R. F. Kesuma ◽  
L. Yuliati ◽  
T. H. P. Brotosudarmo
Keyword(s):  
Diffuse Reflectance ◽  
Metal Organic Framework ◽  
Reflectance Spectra ◽  
Eosin Y ◽  
X Ray Diffraction ◽  
X Ray ◽  
Diffuse Reflectance Spectra ◽  
Metal Organic ◽  
Organic Framework

Eosin Y telah berhasil diembankan pada Metal-Organic Framework Zirkonium Naftalendikarboksilat (MOF Zr-NDC) dengan cara menambahkan Eosin Y dalam pelarut etanol (0,034 ml, 10-4 M) pada MOF Zr-NDC (0,3 g). Pengukuran Powder X-Ray Diffraction (PXRD) dilakukan untuk mengkonfirmasi pembentukan MOF Zr-NDC dengan puncak khas pada 2θ di 6.47 dan 7.45. Spektra UV-vis Diffuse Reflectance Spectra diperoleh dengan menggunakan spektrofotometer UV-vis. MOF Zr-NDC memberikan serapan pada 274 nm yang berhubungan dengan energi celah sebesar 4.32 eV, sedangkan Eosin Y menunjukkan serapan pada 524 nm. Di sisi lain, Eosin Y@MOF Zr-NDC menunjukkan puncak-puncak serapan pada 300, 357, dan 524 nm yang berkorelasi dengan energi celah masing-masing sebesar 3,65, 3,15, dan 2,19 eV

Preparation, Characterization of Phosphorus Doped Titania Photocatalysts with High Photocatalystic Properties

2010 ◽  
Vol 113-116 ◽  
pp. 2154-2157 ◽  
Author(s):  
Si Yao Guo ◽  
Jin Bing Sun ◽  
Feng Lu Wang ◽  
Lin Yang ◽  
Feng Zhang ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Titania Nanoparticles ◽  
Molar Ratio ◽  
X Ray Diffraction ◽  
Step Method ◽  
X Ray ◽  
One Step ◽  
Titania Photocatalyst ◽  
Calcination Method ◽  
Doped Titania

Phosphor-doped titania nanoparticles were synthesized by a one step method, which were prepared by conventional calcination method. These samples have much higher photocatalytic activity for methylene blue degradation. The resulting materials were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), etc. Moreover, we use high P/TiO2 molar ratio to get the most suitable proportion for the synthesis of P-doped titania photocatalyst.

scholarly journals Deep Oxidative Desulfurization of Fuels in the Presence of Brönsted Acidic Polyoxometalate-Based Ionic Liquids

Molecules ◽  
2020 ◽  
Vol 25 (3) ◽  
pp. 536 ◽  
Author(s):  
Argam Akopyan ◽  
Ekaterina Eseva ◽  
Polina Polikarpova ◽  
Anastasia Kedalo ◽  
Anna Vutolkina ◽  
...  
Keyword(s):  
Oxidative Desulfurization ◽  
Acid Sites ◽  
Molar Ratio ◽  
Optimal Conditions ◽  
Factors Affecting ◽  
Diesel Fuels ◽  
Pyridinium Cation ◽  
Nicotinic Acid Derivative ◽  
Main Factors ◽  
Catalyst Dosage

Polyoxometalate-based ionic liquid hybrid materials with a pyridinium cation, containing Brönsted acid sites, were synthesized and used as catalysts for the oxidation of model and real diesel fuels. Keggin-type polyoxometalates with the formulae [PMo12O40]3−, [PVMo11O40]4−, [PV2Mo10O40]4−, [PW12O40]3− were used as anions. It was shown that increasing the acid site strength leads to an increase of dibenzothiophene conversion to the corresponding sulfone. The best results were obtained in the presence of a catalyst, containing a nicotinic acid derivative as cation and phosphomolybdate as anion. The main factors affecting the process consisting of catalyst dosage, temperature, reaction time, oxidant dosage were investigated in detail. Under optimal conditions full oxidation of dibenzothiophene and more than a 90% desulfurization degree of real diesel fuel (initial sulfur content of 2050 ppm) were obtained (the oxidation conditions: NK-1 catalyst, molar ratio H2O2:S 10:1, molar ratio S:Mo 8:1, 1 mL MeCN, 70 °C, 1 h). The synthesized catalysts could be used five times with a slight decrease in activity.

scholarly journals Sintesis dan Karakterisasi TiO2 Terdoping Nitrogen (N-Doped TiO2) dengan Metode Sol–Gel

2016 ◽  
Vol 19 (2) ◽  
pp. 63-67
Author(s):  
Slamet Karim ◽  
Pardoyo Pardoyo ◽  
Agus Subagio
Keyword(s):  
Fourier Transform ◽  
Diffuse Reflectance ◽  
Sol Gel ◽  
Reflectance Spectra ◽  
X Ray Diffraction ◽  
Doped Tio2 ◽  
X Ray ◽  
Diffuse Reflectance Spectra ◽  
Infra Red ◽  
Uv Visible

Energi celah pita yang lebar dari semikonduktor TiO2 yang setara dengan cahaya ultraviolet (l<380 nm) membatasi aplikasi fotokatalitik hanya terbatas pada daerah ultraviolet dan tidak pada daerah cahaya tampak (l = 400 nm–700 nm). Pada penelitian ini dilakukan sintesis TiO2 teremban nitrogen yang dipreparasi melalui metode sol-gel. Prekursor TiCl4 digunakan sebagai sumber titanium dioksida dan CO(NH2)2 sebagai sumber nitrogen dan divariasi pada jumlah konsentrasi N dengan variasi 20 g, 30 g, 40 g dan 50 g. Refluks dilakukan pada suhu 100oC selama 7 jam dilanjutkan dengan pengeringan selama 3 jam pada suhu 100oC, dan kalsinasi pada suhu 500oC selama 7 jam . Karakterisasi N-doped TiO2 dilakukan menggunakan X-ray Diffraction (XRD), Fourier Transform–Infra Red spectroscopy (FTIR), dan UV- Visible diffuse reflectance spectra (UV-Vis DRS). Berdasarkan data XRD diketahui bahwa kristal N- doped TiO2 berstruktur anatase dengan indeks Miller 101. Spektra FTIR menunjukkan pergeseran serapan vibrasi O-Ti-O pada bilangan gelombang 400-1050 cm-1, diperkirakan sebagai akibat terbentuknya ikatan N-Ti-O. Spektrum DRS-UV–tampak menunjukkan penurunan energi celah pita dari TiO2 yakni 3,2 eV. Dapat disimpulkan bahwa penambahan konsentrasi nitrogen mengakibatkan penurunan energi celah pita, pada variasi 20g sebesar 3,12 eV, 30 g sebesar 3,09 eV, 40 g sebesar 3,082 eV, dan 50 g sebesar 3,08 eV.

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