scholarly journals Luminescence Properties of Co-doped Eu3+, Bi3+ Lu2O3/Polyvinylpyrrolidone Films

Coatings ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 434 ◽  
Author(s):  
Ángel de Jesús Morales-Ramírez ◽  
Margarita García-Hernández ◽  
Dulce Yolotzin Medina-Velázquez ◽  
María del Rosario Ruiz-Guerrero ◽  
Fernando Juárez-López ◽  
...  

The effect of the polyvinylpyrrolidone (PVP, MW = 130,000) molar content, PVP/Lu = 1, 2.5, 4 and 5; on the photoluminescent and structural properties of sol-gel derived Lu2O3:Eu3+, Bi3+ has been analyzed. Thin hybrid films were deposited by means of the dip-coating technique on silica quartz substrates. Films deposited at 700 °C presented a cubic structure, with non-preferential orientation, even with the presence of PVP. The photoluminescence (PL) spectrum and Comission Internationale de l’Éclairage (CIE) chromaticity diagram of films revealed a reddish Eu3+ emission at 612 nm (5D0 →7F2) with an excitation at 320 nm of the Bi ions (6s2→6s6p), showing a highly-effective energy transfer process form Bi3+ to Eu3+ luminescent centers. On the other hand, the color temperature of the samples is strongly dependent on the PVP content, as a consequence of the observed difference on the branching ratios of 5D0 →7FJ transitions of europium ions. Lifetime studies present two different behaviors for the thin films: A non-exponential nature for the lower PVP contents, and a simple exponential nature for the highest PVP one, showing that the PVP tends to promote a better dissolution of segregates and, therefore, increases the lifetime of the Eu3+ emission.

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1554
Author(s):  
Justinas Januskevicius ◽  
Zivile Stankeviciute ◽  
Dalis Baltrunas ◽  
Kęstutis Mažeika ◽  
Aldona Beganskiene ◽  
...  

In this study, an aqueous sol-gel synthesis method and subsequent dip-coating technique were applied for the preparation of yttrium iron garnet (YIG), yttrium iron perovskite (YIP), and terbium iron perovskite (TIP) bulk and thin films. The monophasic highly crystalline different iron ferrite powders have been synthesized using this simple aqueous sol-gel process displaying the suitability of the method. In the next step, the same sol-gel solution was used for the fabrication of coatings on monocrystalline silicon (100) using a dip-coating procedure. This resulted, likely due to substrate surface influence, in all coatings having mixed phases of both garnet and perovskite. Thermogravimetric (TG) analysis of the precursor gels was carried out. All the samples were investigated by X-ray powder diffraction (XRD) analysis. The coatings were also investigated by scanning electron microscopy (SEM), atomic force microscopy (AFM) and Mössbauer spectroscopy. Magnetic measurements were also carried out.


Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 243
Author(s):  
Diana Horkavcová ◽  
Quentin Doubet ◽  
Gisèle Laure Lecomte-Nana ◽  
Eva Jablonská ◽  
Aleš Helebrant

The sol-gel method provides a wide variety of applications in the medical field. One of these applications is the formation of coatings on the metal implants. The coatings containing specific additive can enhance or improve the existing surface properties of the substrate. In this work, titania sol-gel coatings were doped with two forms of silver (AgNO3, Ag3PO4) and synthetic hydroxyapatite and applied on the titanium samples by dip-coating technique. After drying and slow firing, all coatings were characterized with scanning electron microscopy. Thin coatings were successfully prepared with excellent adhesion to the substrate (measured by ASTM D 3359-2), despite cracks. Coatings containing silver and hydroxyapatite demonstrated a 100% antibacterial effect against Escherichia coli after 24 h. The bioactivity of the coatings containing hydroxyapatite tested in modified simulated body fluid under static-dynamic conditions was confirmed by bone-like hydroxyapatite precipitation. To better understand the interaction of the coatings with simulated body fluid (SBF), changes of Ca2+ and (PO4)3− ions concentrations and pH values were studied.


2007 ◽  
Vol 336-338 ◽  
pp. 593-596
Author(s):  
Chun Yang ◽  
Jun Ying Zhang ◽  
Hai Bing Feng ◽  
Wei Chang Hao ◽  
Tian Min Wang

Y2O3:Eu3+ thin film was synthesized by sol-gel method with inorganic salt raw materials, and the crystal structure and luminescent properties were investigated. By adding organic additive to the sol, a homogeneous film with high luminescent intensity could be obtained by dip-coating technique on the surface of alumina sheet and quartz glass. Structures of the films were studied by XRD and SEM. The excitation spectra of the films showed a wide excitation peak from 200nm to 260nm, and the emission spectra had a strongest emission peak at 611nm which revealed a close relationship with the calcining temperature.


ChemPhotoChem ◽  
2017 ◽  
Vol 1 (6) ◽  
pp. 273-280 ◽  
Author(s):  
Samantha Hilliard ◽  
Dennis Friedrich ◽  
Stéphane Kressman ◽  
Henri Strub ◽  
Vincent Artero ◽  
...  

RSC Advances ◽  
2018 ◽  
Vol 8 (51) ◽  
pp. 28953-28959 ◽  
Author(s):  
Maodong Zhu ◽  
Hongji Qi ◽  
Bin Wang ◽  
Hu Wang ◽  
Dongping Zhang ◽  
...  

Index-tunable anti-reflection SiO2 coatings prepared on the surface of VO2 films by sol–gel dip-coating technique to enhance the visible and infrared transmittance of SiO2/VO2 films.


2019 ◽  
Vol 25 (4) ◽  
pp. 365-368
Author(s):  
Pranas USINSKAS ◽  
Živilė STANKEVIČIŪTĖ ◽  
Gediminas NIAURA ◽  
Justinas ČEPONKUS ◽  
Aivaras KAREIVA

In this study we demonstrate, that sol–gel route is suitable to quicker obtain calcium hydroxyapatite (Ca10(PO4)6(OH)2, CHAp) coatings on crystalline Si substrate by modified dip-coating technique. The substrate was dip-coated by precursor and dried for 10 minutes at 200 °C with following cooling using the heating block for 110 min and annealing at 650 °C. Ethylendiamintetraacetic acid and 1,2-ethandiol, and triethanolamine and polyvinyl alcohol were used as complexing agents and as gel network forming agents, respectively. The obtained coatings were characterized by X-ray diffraction (XRD) analysis, scanning electron microscopy (SEM), FTIR spectroscopy and contact angle measurements (CAM).


2011 ◽  
Vol 148-149 ◽  
pp. 534-537
Author(s):  
Chun Xiang Gao

A very effective approach to improve the oxidation resistance of Ti-6Al-4V alloy was proposed. The Ti-6Al-4V alloy was firstly phosphated and then coated by silica using sol-gel dip-coating technique. A duplex layer of TiP2O7 and amorphous silica was synthesized at the alloy surface. The isothermal and cyclic oxidation behavior of the treated alloy with silica coating and the corresponding bare alloy was investigated at 600 oC in static air to investigate the synergetic effect of phosphorization and amorphous SiO2 coating on the oxidation resistance of the alloy. The isothermal and cyclic oxidation resistances of the alloy were greatly improved.


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