scholarly journals Investigation of Stability of CO2 Microbubbles—Colloidal Gas Aphrons for Enhanced Oil Recovery Using Definitive Screening Design

2020 ◽  
Vol 4 (2) ◽  
pp. 26
Author(s):  
Nam Nguyen Hai Le ◽  
Yuichi Sugai ◽  
Kyuro Sasaki

CO2 microbubbles have recently been used in enhanced oil recovery for blocking the high permeability zone in heterogeneous reservoirs. Microbubbles are colloidal gas aphrons stabilized by thick shells of polymer and surfactant. The stability of CO2 microbubbles plays an important role in improving the performance of enhanced oil recovery. In this study, a new class of design of experiment (DOE)—definitive screening design (DSD) was employed to investigate the effect of five quantitative parameters: xanthan gum polymer concentration, sodium dodecyl sulfate surfactant concentration, salinity, stirring time, and stirring rate. This is a three-level design that required only 11 experimental runs. The results suggest that DSD successfully evaluated how various parameters contribute to CO2 microbubble stability. The definitive screening design revealed a polynomial regression model has ability to estimate the main effect factor, two-factor interactions and pure-quadratic effect of factors with high determination coefficients for its smaller number of experiments compared to traditional design of experiment approach. The experimental results showed that the stability depend primarily on xanthan gum polymer concentration. It was also found that the stability of CO2 microbubbles increases at a higher sodium dodecyl sulfate surfactant concentration and stirring rate, but decreases with increasing salinity. In addition, several interactions are presented to be significant including the polymer–salinity interaction, surfactant–salinity interaction and stirring rate–salinity interaction.

Author(s):  
Muhammad Khan Memon ◽  
Ubedullah Ansari ◽  
Habib U Zaman Memon

The residual oil after primary or secondary oil recovery can be recovered by the methods of EOR (Enhanced Oil Recovery). The objective of this study is screening the surfactants that generate maximum stable foam in the presence of brine salinity at 92oC. Laboratory experiments have been performed to examine and compare the stability of generated foam by individual and blended surfactants in the synthetic brine water. AOS C14-16 (Alpha Olefin Sulfonate) and SDS (Sodium Dodecyl Sulfonate) were selected as main surfactants. Aqueous stability test of AOS C14-16 and SDS with brine water salinity 62070ppm was performed at 92oC. AAS (Alcohol Alkoxy Sulfate) was blended with SDS and AOS C14-16. The solution was stable in the presence of brine salinity at same conditions. Salt tolerance experimental study revealed that AOS C14-16 did not produce precipitates at 92oC. Further, the foam stability of surfactant blend was performed. Result shows that, the maximum life time of generated foam was observed by using blend of 0.2wt% SDS+0.2wt% AOS+0.2wt% AS-1246 and 0.2wt% AOS+0.2wt% IOSC15-18+0.2wt% AAS surfactants as compared to the foam generated by individual surfactants. The success of generated foam by these surfactant solutions in the presence of brine water is the primary screening of surfactant stability and foamability for EOR applications in reservoirs type of reservoirs.


2015 ◽  
Vol 1113 ◽  
pp. 492-497 ◽  
Author(s):  
Effah Yahya ◽  
Nur Hashimah Alias ◽  
Tengku Amran Tengku Mohd ◽  
Nurul Aimi Ghazali ◽  
Tajnor Suriya binti Taju Ariffin

In this study, local isolated Xanthomonas campestries has been used from local cabbage for xanthan gum production via fermentation in shake flask. The product was then recovered with isopropanol and dried. Meanwhile, for extraction and purification of mushroom polysaccharide, we use dead edible mushroom has been used. Polysaccharide mushroom was extracted with NaOH solutions at 100 ͦ C for 24 hrs. Next, polysaccharide was precipitated separately by the addition of ethanol and the resulting polysaccharide extract were dissolved in distilled water. In the present study, different type of biopolymers was used in order to determine the oil recovery with different concentrations. Biopolymers used in this experiment are xanthan gum and mushroom polysaccharide. The properties of both biopolymers were tested for 3000 ppm and 10000 ppm of concentration. The results shown higher oil recovery factor obtained from the mushroom polysaccharide, which is 84.14%. Meanwhile, the highest recovery obtained by xanthan is about 67.44% only. As a conclusion, increasing polymer concentration will increase the oil recovery factor.


Author(s):  
Afeez Gbadamosi ◽  
Adeyinka Yusuff ◽  
Augustine Agi ◽  
Prem Muruga ◽  
Radzuan Junin ◽  
...  

AbstractRecently, nanoparticle additives have been used to improve stability and hence efficiency of chemicals during enhanced oil recovery. Herein, a comparative analysis of the application of nanoparticle-stabilized xanthan gum for oil recovery applications was investigated. The nanoparticles used as additives are silicon oxide (SiO2), metallic aluminium oxide (Al2O3), and titanium oxide (TiO2). Rheological measurements were carried out to examine the shear viscosity of the polymeric nanofluids under a range of salinity typical of reservoir conditions. Interfacial tension (IFT) experiment was conducted using Kruss tensiometer. Oil displacement studies were carried out to examine the incremental recovery factor of the polymeric nanofluids. The polymeric nanofluids exhibited better rheological behaviour compared to bare xanthan gum (XG) polymer. At 0.5 wt.% nanoparticle concentration, 0.5 wt.% polymer concentration, shearing rate of 10 s−1, and 3 wt.% NaCl concentration, rheology result shows that the shear viscosity of SiO2-XG, Al2O3-XG, and TiO2-XG is 423 mPa.s, 299 mPa.s, and 293 mPa.s, respectively. Moreover, the polymeric nanofluids lowered the IFT of the oil/brine interface due to adsorption at the nanoparticles at the interface. Finally, oil displacement result confirms that the incremental oil recovery after water flooding by Al2O3-XG, TiO2-XG, and SiO2-XG is 28.4%, 27.6%, and 25.2%, respectively.


2019 ◽  
Vol 3 (1) ◽  
pp. 31 ◽  
Author(s):  
Seyed Hosseini-Kaldozakh ◽  
Ehsan Khamehchi ◽  
Bahram Dabir ◽  
Ali Alizadeh ◽  
Zohreh Mansoori

Today, the drilling operators use the Colloidal Gas Aphron (CGA) fluids as a part of drilling fluids in their operations to reduce formation damages in low-pressure, mature or depleted reservoirs. In this paper, a Taguchi design of experiment (DOE) has been designed to analyse the effect of salinity, polymer and surfactant types and concentration on the stability of CGA fluids. Poly Anionic Cellulose (PacR) and Xanthan Gum (XG) polymers are employed as viscosifier; Hexadecyl Trimethyl Ammonium Bromide (HTAB) and Sodium Dodecyl Benzene Sulphonate (SDBS) have been also utilized as aphronizer. Moreover, bubble size distributions, rheological and filtration properties of aphronized fluids are investigated. According to the results, the polymer type has the highest effect, whereas the surfactant type has the lowest effect on the stability of CGA drilling fluid. It was also observed that increasing salinity in CGA fluid reduces the stability. Finally, it should be noted that the micro-bubbles generated with HTAB surfactant in an electrolyte system, are more stable than SDBS surfactant.


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