Flooding with Biopolymer from Microbes Derived from Mushroom and Cabbage to Enhance Sweep Efficiency in Enhanced Oil Recovery

2015 ◽  
Vol 1113 ◽  
pp. 492-497 ◽  
Author(s):  
Effah Yahya ◽  
Nur Hashimah Alias ◽  
Tengku Amran Tengku Mohd ◽  
Nurul Aimi Ghazali ◽  
Tajnor Suriya binti Taju Ariffin
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Xanthan Gum ◽  
Shake Flask ◽  
Polymer Concentration ◽  
Edible Mushroom ◽  
Recovery Factor ◽  
Distilled Water ◽  
Sweep Efficiency ◽  
Extraction And Purification

In this study, local isolated Xanthomonas campestries has been used from local cabbage for xanthan gum production via fermentation in shake flask. The product was then recovered with isopropanol and dried. Meanwhile, for extraction and purification of mushroom polysaccharide, we use dead edible mushroom has been used. Polysaccharide mushroom was extracted with NaOH solutions at 100 ͦ C for 24 hrs. Next, polysaccharide was precipitated separately by the addition of ethanol and the resulting polysaccharide extract were dissolved in distilled water. In the present study, different type of biopolymers was used in order to determine the oil recovery with different concentrations. Biopolymers used in this experiment are xanthan gum and mushroom polysaccharide. The properties of both biopolymers were tested for 3000 ppm and 10000 ppm of concentration. The results shown higher oil recovery factor obtained from the mushroom polysaccharide, which is 84.14%. Meanwhile, the highest recovery obtained by xanthan is about 67.44% only. As a conclusion, increasing polymer concentration will increase the oil recovery factor.

scholarly journals Polymer viscosifier systems with potential application for enhanced oil recovery: a review

2021 ◽  
Vol 76 ◽  
pp. 65
Author(s):  
Kelly Lúcia Nazareth Pinho de Aguiar ◽  
Luiz Carlos Magalhães Palermo ◽  
Claudia Regina Elias Mansur
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Polymer Concentration ◽  
High Viscosity ◽  
Water Soluble ◽  
Recovery Factor ◽  
Sweep Efficiency ◽  
Polymeric Fluids ◽  
Excellent Thermal Stability ◽  
Reservoir Conditions

Due to the growing demand for oil and the large number of mature oil fields, Enhanced Oil Recovery (EOR) techniques are increasingly used to increase the oil recovery factor. Among the chemical methods, the use of polymers stands out to increase the viscosity of the injection fluid and harmonize the advance of this fluid in the reservoir to provide greater sweep efficiency. Synthetic polymers based on acrylamide are widely used for EOR, with Partially Hydrolyzed Polyacrylamide (PHPA) being used the most. However, this polymer has low stability under harsh reservoir conditions (High Temperature and Salinity – HTHS). In order to improve the sweep efficiency of polymeric fluids under these conditions, Hydrophobically Modified Associative Polymers (HMAPs) and Thermo-Viscosifying Polymers (TVPs) are being developed. HMAPs contain small amounts of hydrophobic groups in their water-soluble polymeric chains, and above the Critical Association Concentration (CAC), form hydrophobic microdomains that increase the viscosity of the polymer solution. TVPs contain blocks or thermosensitive grafts that self-assemble and form microdomains, substantially increasing the solution’s viscosity. The performance of these systems is strongly influenced by the chemical group inserted in their structures, polymer concentration, salinity and temperature, among other factors. Furthermore, the application of nanoparticles is being investigated to improve the performance of injection polymers applied in EOR. In general, these systems have excellent thermal stability and salinity tolerance along with high viscosity, and therefore increase the oil recovery factor. Thus, these systems can be considered promising agents for enhanced oil recovery applications under harsh conditions, such as high salinity and temperature. Moreover, stands out the use of genetic programming and artificial intelligence to estimate important parameters for reservoir engineering, process improvement, and optimize polymer flooding in enhanced oil recovery.

scholarly journals Investigation of Stability of CO2 Microbubbles—Colloidal Gas Aphrons for Enhanced Oil Recovery Using Definitive Screening Design

2020 ◽  
Vol 4 (2) ◽  
pp. 26
Author(s):  
Nam Nguyen Hai Le ◽  
Yuichi Sugai ◽  
Kyuro Sasaki
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Xanthan Gum ◽  
Polymer Concentration ◽  
Sodium Dodecyl ◽  
Screening Design ◽  
Stirring Rate ◽  
Definitive Screening ◽  
The Stability ◽  
Definitive Screening Design

CO2 microbubbles have recently been used in enhanced oil recovery for blocking the high permeability zone in heterogeneous reservoirs. Microbubbles are colloidal gas aphrons stabilized by thick shells of polymer and surfactant. The stability of CO2 microbubbles plays an important role in improving the performance of enhanced oil recovery. In this study, a new class of design of experiment (DOE)—definitive screening design (DSD) was employed to investigate the effect of five quantitative parameters: xanthan gum polymer concentration, sodium dodecyl sulfate surfactant concentration, salinity, stirring time, and stirring rate. This is a three-level design that required only 11 experimental runs. The results suggest that DSD successfully evaluated how various parameters contribute to CO2 microbubble stability. The definitive screening design revealed a polynomial regression model has ability to estimate the main effect factor, two-factor interactions and pure-quadratic effect of factors with high determination coefficients for its smaller number of experiments compared to traditional design of experiment approach. The experimental results showed that the stability depend primarily on xanthan gum polymer concentration. It was also found that the stability of CO2 microbubbles increases at a higher sodium dodecyl sulfate surfactant concentration and stirring rate, but decreases with increasing salinity. In addition, several interactions are presented to be significant including the polymer–salinity interaction, surfactant–salinity interaction and stirring rate–salinity interaction.

scholarly journals Properties of Biodegradable Polymer from Terrestrial Mushroom for Potential Enhanced Oil Recovery

2020 ◽  
Vol 20 (6) ◽  
pp. 1382
Author(s):  
Tengku Amran Tengku Mohd ◽  
Shareena Fairuz Abdul Manaf ◽  
Munawirah Abd Naim ◽  
Muhammad Shafiq Mat Shayuti ◽  
Mohd Zaidi Jaafar
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Biodegradable Polymer ◽  
Polymer Concentration ◽  
Polymer Flooding ◽  
Mobility Control ◽  
Sweep Efficiency ◽  
Reservoir Conditions ◽  
Infrared Spectrometer ◽  
Original Oil In Place

Polymer flooding could enhance the oil recovery by increasing the viscosity of water, thus, improving the mobility control and sweep efficiency. It is essential to explore natural sources of polymer, which is biologically degradable and negligible to environmental risks. This research aims to produce a biodegradable polymer from terrestrial mushroom, analyze the properties of the polymer and investigate the oil recovery from polymer flooding. Polysaccharide biopolymer was extracted from mushroom and characterized using Fourier Transform Infrared Spectrometer (FTIR), while the polymer viscosity was investigated using an automated microviscometer. The oil recovery tests were conducted at room temperature using a sand pack model. It was found that polymer viscosity increases with increasing polymer concentration and decreases when increase in temperature, salinity, and concentration of divalent ions. The oil recovery tests showed that a higher polymer concentration of 3000 ppm had recovered more oil with an incremental recovery of 25.8% after waterflooding, while a polymer concentration of 1500 pm obtained incremental 22.2% recovery of original oil in place (OOIP). The oil recovery from waterflooding was approximately 25.4 and 24.2% of the OOIP, respectively. Therefore, an environmentally friendly biopolymer was successfully extracted, which is potential for enhanced oil recovery (EOR) application, but it will lose its viscosity performance at certain reservoir conditions.

scholarly journals Mechanistic study of nanoparticles-assisted xanthan gum polymer flooding for enhanced oil recovery: a comparative study

2021 ◽  
Author(s):  
Afeez Gbadamosi ◽  
Adeyinka Yusuff ◽  
Augustine Agi ◽  
Prem Muruga ◽  
Radzuan Junin ◽  
...  
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Shear Viscosity ◽  
Xanthan Gum ◽  
Silicon Oxide ◽  
Polymer Concentration ◽  
Rheological Behaviour ◽  
Water Flooding ◽  
Mechanistic Study ◽  
Oil Displacement

AbstractRecently, nanoparticle additives have been used to improve stability and hence efficiency of chemicals during enhanced oil recovery. Herein, a comparative analysis of the application of nanoparticle-stabilized xanthan gum for oil recovery applications was investigated. The nanoparticles used as additives are silicon oxide (SiO2), metallic aluminium oxide (Al2O3), and titanium oxide (TiO2). Rheological measurements were carried out to examine the shear viscosity of the polymeric nanofluids under a range of salinity typical of reservoir conditions. Interfacial tension (IFT) experiment was conducted using Kruss tensiometer. Oil displacement studies were carried out to examine the incremental recovery factor of the polymeric nanofluids. The polymeric nanofluids exhibited better rheological behaviour compared to bare xanthan gum (XG) polymer. At 0.5 wt.% nanoparticle concentration, 0.5 wt.% polymer concentration, shearing rate of 10 s−1, and 3 wt.% NaCl concentration, rheology result shows that the shear viscosity of SiO2-XG, Al2O3-XG, and TiO2-XG is 423 mPa.s, 299 mPa.s, and 293 mPa.s, respectively. Moreover, the polymeric nanofluids lowered the IFT of the oil/brine interface due to adsorption at the nanoparticles at the interface. Finally, oil displacement result confirms that the incremental oil recovery after water flooding by Al2O3-XG, TiO2-XG, and SiO2-XG is 28.4%, 27.6%, and 25.2%, respectively.

scholarly journals Parametric Study of Polymer-Nanoparticles-Assisted Injectivity Performance for Axisymmetric Two-Phase Flow in EOR Processes

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1818 ◽  
Author(s):  
Afshin Davarpanah
Keyword(s):  
Oil Recovery ◽  
Polymer Concentration ◽  
Extensive Study ◽  
Recovery Factor ◽  
Sweep Efficiency ◽  
Forward Movement ◽  
Two Phase ◽  
Type Curves ◽  
Wide Range ◽  
Damage Coefficient

Among a wide range of enhanced oil-recovery techniques, polymer flooding has been selected by petroleum industries due to the simplicity and lower cost of operational performances. The reason for this selection is due to the mobility-reduction of the water phase, facilitating the forward-movement of oil. The objective of this comprehensive study is to develop a mathematical model for simultaneous injection of polymer-assisted nanoparticles migration to calculate an oil-recovery factor. Then, a sensitivity analysis is provided to consider the significant influence of formation rheological characteristics as type curves. To achieve this, we concentrated on the driving mathematical equations for the recovery factor and compare each parameter significantly to nurture the differences explicitly. Consequently, due to the results of this extensive study, it is evident that a higher value of mobility ratio, higher polymer concentration and higher formation-damage coefficient leads to a higher recovery factor. The reason for this is that the external filter cake is being made in this period and the subsequent injection of polymer solution administered a higher sweep efficiency and higher recovery factor.

scholarly journals Study of Enhanced Oil Recovery and Adsorption Using Glycerol in Surfactant Solution

Energies ◽  
2020 ◽  
Vol 13 (12) ◽  
pp. 3135
Author(s):  
Fabiola D. S. Curbelo ◽  
Alfredo Ismael C. Garnica ◽  
Danilo F. Q. Leite ◽  
Amanda B. Carvalho ◽  
Raphael R. Silva ◽  
...  
Keyword(s):  
Interfacial Tension ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Coconut Oil ◽  
Surfactant Solution ◽  
Recovery Factor ◽  
Sweep Efficiency ◽  
Brine Solution ◽  
Flow Through ◽  
Over Time

Over time, oil production in a reservoir tends to decrease, which makes it difficult to flow through the reservoir to the well, making its production increasingly difficult and costly. Due to their physical properties, such as reducing the water/oil interfacial tension, surfactants have been used in enhanced oil recovery (EOR) processes, however, their adsorption presents as an undesirable and inevitable factor and can decrease the efficiency of the method. This work’s main objective is to evaluate the effect of glycerol in the adsorption of surfactants in sandstones, as well as in the recovery factor during EOR. Brine solutions containing the nonionic surfactant saponified coconut oil (SCO), with and without glycerol, were used in the adsorption and oil recovery tests in sandstone. Adsorption, recovery, rheological, and thermogravimetric analysis were carried out. Regarding the surfactant/glycerol/brine solution, there was an improvement in the oil mobility, as the glycerol contributed to an increase in the viscosity of the solution, thereby increasing the sweep efficiency. The recovery factor obtained for the surfactant solution with glycerol was satisfactory, being 53% higher than without glycerol, because it simultaneously provided an increase in viscosity and a decrease in interfacial tension, both of which are beneficial for the efficiency of the process.

scholarly journals Research progress of viscoelastic surfactants for enhanced oil recovery

2021 ◽  
pp. 014459872098020
Author(s):  
Ruizhi Hu ◽  
Shanfa Tang ◽  
Musa Mpelwa ◽  
Zhaowen Jiang ◽  
Shuyun Feng
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
High Efficiency ◽  
Research Progress ◽  
Surfactant Flooding ◽  
Sweep Efficiency ◽  
The World ◽  
Washing Efficiency ◽  
Viscoelastic Surfactants ◽  
Viscoelastic Surfactant

Although new energy has been widely used in our lives, oil is still one of the main energy sources in the world. After the application of traditional oil recovery methods, there are still a large number of oil layers that have not been exploited, and there is still a need to further increase oil recovery to meet the urgent need for oil in the world economic development. Chemically enhanced oil recovery (CEOR) is considered to be a kind of effective enhanced oil recovery technology, which has achieved good results in the field, but these technologies cannot simultaneously effectively improve oil sweep efficiency, oil washing efficiency, good injectability, and reservoir environment adaptability. Viscoelastic surfactants (VES) have unique micelle structure and aggregation behavior, high efficiency in reducing the interfacial tension of oil and water, and the most important and unique viscoelasticity, etc., which has attracted the attention of academics and field experts and introduced into the technical research of enhanced oil recovery. In this paper, the mechanism and research status of viscoelastic surfactant flooding are discussed in detail and focused, and the results of viscoelastic surfactant flooding experiments under different conditions are summarized. Finally, the problems to be solved by viscoelastic surfactant flooding are introduced, and the countermeasures to solve the problems are put forward. This overview presents extensive information about viscoelastic surfactant flooding used for EOR, and is intended to help researchers and professionals in this field understand the current situation.

scholarly journals Enhanced Oil Recovery: Chemical Flooding

2021 ◽  
Author(s):  
Ahmed Ragab ◽  
Eman M. Mansour
Keyword(s):  
Interfacial Tension ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Recovery Phase ◽  
Mobility Ratio ◽  
Chemical Flooding ◽  
Sweep Efficiency ◽  
Oil Displacement ◽  
Remaining Oil ◽  
Oil Displacement Efficiency

The enhanced oil recovery phase of oil reservoirs production usually comes after the water/gas injection (secondary recovery) phase. The main objective of EOR application is to mobilize the remaining oil through enhancing the oil displacement and volumetric sweep efficiency. The oil displacement efficiency enhances by reducing the oil viscosity and/or by reducing the interfacial tension, while the volumetric sweep efficiency improves by developing a favorable mobility ratio between the displacing fluid and the remaining oil. It is important to identify remaining oil and the production mechanisms that are necessary to improve oil recovery prior to implementing an EOR phase. Chemical enhanced oil recovery is one of the major EOR methods that reduces the residual oil saturation by lowering water-oil interfacial tension (surfactant/alkaline) and increases the volumetric sweep efficiency by reducing the water-oil mobility ratio (polymer). In this chapter, the basic mechanisms of different chemical methods have been discussed including the interactions of different chemicals with the reservoir rocks and fluids. In addition, an up-to-date status of chemical flooding at the laboratory scale, pilot projects and field applications have been reported.

Effect of pressure variation on polymer flooding

2021 ◽  
Author(s):  
Ahmad Ali Manzoor
Keyword(s):  
Polymer Solution ◽  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Heavy Oil ◽  
Constant Pressure ◽  
Maximum Pressure ◽  
Core Flooding ◽  
Sweep Efficiency ◽  
Black Oil Model ◽  
Original Oil In Place

Chemical-based enhanced oil recovery (EOR) techniques utilize the injection of chemicals, such as solutions of polymers, alkali, and surfactants, into oil reservoirs for incremental recovery. The injection of a polymer increases the viscosity of the injected fluid and alters the water-to-oil mobility ratio which in turn improves the volumetric sweep efficiency. This research study aims to investigate strategies that would help intensify oil recovery with the polymer solution injection. For that purpose, we utilize a lab-scale, cylindrical heavy oil reservoir model. Furthermore, a dynamic mathematical black oil model is developed based on cylindrical physical model of homogeneous porous medium. The experiments are carried out by injecting classic and novel partially hydrolyzed polyacrylamide solutions (concentration: 0.1-0.5 wt %) with 1 wt % brine into the reservoir at pressures in the range, 1.03-3.44 MPa for enhanced oil recovery. The concentration of the polymer solution remains constant throughout the core flooding experiment and is varied for other subsequent experimental setup. Periodic pressure variations between 2.41 and 3.44 MPa during injection are found to increase the heavy oil recovery by 80% original-oil-in-place (OOIP). This improvement is approximately 100% more than that with constant pressure injection at the maximum pressure of 3.44 MPa. The experimental oil recoveries are in fair agreement with the model calculated oil production with a RMS% error in the range of 5-10% at a maximum constant pressure of 3.44 MPa.

Improved Fluids Characterization Model During Gas Huff-n-Puff EOR Processes in Unconventional Reservoirs

2021 ◽  
Author(s):  
Gang Yang ◽  
Xiaoli Li
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Fluid Model ◽  
Geometric Constraints ◽  
Confinement Effect ◽  
Recovery Factor ◽  
Unconventional Reservoirs ◽  
Compositional Simulation ◽  
Compositional Model ◽  
Characterization Model

Abstract Despite the great potential of unconventional hydrocarbons, the primary recovery factor from such reservoirs remain low. The gas-injection enhanced oil recovery (EOR) has been proved to be a promising approach by both laboratory and simulation studies. However, the fluid model for characterizing gas and oil in nanoscale pores has not been well understood and developed. Erroneous results can be generated if the bulk fluids model is applied, resulting in a large uncertainty for the numerical simulations. The objective of this work is to propose an improved fluids characterization model tailored for the compositional simulation of gas huff-n-puff in unconventional reservoirs. The Peng-Robinson equation of state (PR EOS) is used as the basic thermodynamic model in this work. Both the attraction parameter and the co-volume parameter in the PR EOS are simultaneously modified for the first time to reflect the effect of molecule-wall interaction and geometric constraints. The collected experimental data are used for validating the model. The newly generated PVT data are imported into the compositional model to numerically simulate the gas huff-n-puff process in the Middle Bakken formation to investigate the influence of modified fluid property on the production and ultimate recovery. The improved fluids characterization model is validated applicable to calculate the confined properties of reservoir fluids. It is demonstrated that the phase envelope of the confined reservoir fluids tends to shrink. At reservoir temperature, the bubble-point pressure of the Middle Bakken oil is reduced by 17.32% with consideration of the confinement effect. Such a significant suppression represents a late occurrence of the gas evaporation, which implies a potentially higher production of the shale oil reservoir. Compositional simulation predicts that the enhanced oil recovery efficiency of CO2 huff-n-puff is unsatisfactory for the specific well in this work, which is also demonstrated in the field pilot test. However, the confinement effect results in a 1.14% elevation of the oil recovery factor in 10 years production. This work not only deepens our understanding of the confinement effect on phase behavior characterization and also shed light on the computation of the thermodynamic properties of hydrocarbons in nanopores. The results also provide practical instructions for the EOR development of unconventional reservoirs.

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