scholarly journals Thermal Process of Rock Crystal: Cause of Infrared Absorption Band at 3585 cm−1

Crystals ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 1083
Author(s):  
Jianjun Li ◽  
Yuyu Zheng ◽  
Xuesong Liu ◽  
Guihua Li ◽  
Xiaoyan Yu ◽  
...  

Synthetic rock crystals often show a typical infrared (IR) absorption band at 3585 cm−1. However, the authors recently found this band in a natural rock crystal with blue coating. The origin of this IR band is controversial as yet. In this paper, the infrared spectra of several natural and synthetic rock crystal samples which were heated to 673 K and 1073 K were measured after these samples returned to room temperature. Comparing the infrared spectra of samples before and after heating, we found the absorption band at 3585 cm−1 was induced by the thermal process, which indicates that this band cannot be used as diagnostic evidence for synthetic rock crystal alone. In addition, the LiOH bands decreased while AlOH bands increased upon thermal processing. And the negative correlation between the LiOH bands and the 3585 cm−1 band was also distinct. The above results reveal that the thermal process destroyed the LiOH defects, leading to the formation of a new AlLi defect. And the isolated OH− defect inside dislocations generated upon thermal processing is considered to be the exact cause of the 3585 cm−1 band.

1965 ◽  
Vol 5 (04) ◽  
pp. 329-332 ◽  
Author(s):  
Larman J. Heath

Abstract Synthetic rock with predictable porosity and permeability bas been prepared from mixtures of sand, cement and water. Three series of mixes were investigated primarily for the relation between porosity and permeability for certain grain sizes and proportions. Synthetic rock prepared of 65 per cent large grains, 27 per cent small grains and 8 per cent Portland cement, gave measurable results ranging in porosity from 22.5 to 40 per cent and in permeability from 0.1 darcies to 6 darcies. This variation in porosity and permeability was caused by varying the amount of blending water. Drainage- cycle relative permeability characteristics of the synthetic rock were similar to those of natural reservoir rock. Introduction The fundamental behavior characteristics of fluids flowing through porous media have been described in the literature. Practical application of these flow characteristics to field conditions is too complicated except where assumptions are overly simplified. The use of dimensionally scaled models to simulate oil reservoirs has been described in the literature. These and other papers have presented the theoretical and experimental justification for model design. Others have presented elements of model construction and their operation. In most investigations the porous media have consisted of either unconsolidated sand, glass beads, broken glass or plastic-impregnated granular substances-materials in which the flow behavior is not identical to that in natural reservoir rock. The relative permeability curves for unconsolidated sands differ from those for consolidated sandstone. The effect of saturation history on relative permeability measurements A discussed by Geffen, et al. Wygal has shown quite conclusively that a process of artificial cementation can be used to render unconsolidated packs into synthetic sandstones having properties similar to those of natural rock. Many theoretical and experimental studies have been made in attempts to determine the structure and properties of unconsolidated sand, the most notable being by Naar and Wygal. Others have theorized and experimented with the fundamental characteristics of reservoir rocks. This study was conducted to determine if some general relationship could be established between the size of sand grains and the porosity and permeability in consolidated binary packs. This paper presents the results obtained by changing some of the factors which affect the porosity and permeability of synthetically prepared sandstone. In addition, drainage relative permeability curves are presented. EXPERIMENTAL PROCEDURE Mixtures of Portland cement with water and aggregate generally are designed to have certain characteristics, but essentially all are planned to be impervious to water or other liquids. Synthetic sandstone simulating oil reservoir rock, however, must be designed to have a given permeability (sometimes several darcies), a porosity which is primarily the effective porosity but quantitatively similar to natural rock, and other characteristics comparable to reservoir rock, such as wettability, pore geometry, tortuosity, etc. Unconsolidated ternary mixtures of spheres gave both a theoretically computed and an experimentally observed minimum porosity of about 25 per cent. By using a particle-distribution system, one-size particle packs had reproducible porosities in the reproducible range of 35 to 37 per cent. For model reservoir studies of the prototype system, a synthetic rock having a porosity of 25 per cent or less and a permeability of 2 darcies was required. The rock bad to be uniform and competent enough to handle. Synthetic sandstone cores mere prepared utilizing the technique developed by Wygal. Some tight variations in the procedure were incorporated. The sand was sieved through U.S. Standard sieves. SPEJ P. 329ˆ


1994 ◽  
Vol 14 (1-3) ◽  
pp. 155-160 ◽  
Author(s):  
Tatsuhisa Kato

Absorption spectra are detected for C60− and C602− produced electrolytically in solution at room temperature. Theoretical analysis of the spectrum of C60− by CNDO/S calculations gives an interpretation of the characteristic near-IR bands, the weak visible bands, and the strong bands in the UV region. The emission spectrum of C60− is a mirror image of the near-IR absorption band, and the detection of the emission reconfirms our original assignment of the absorption spectrum. The nature of the spectrum of C602− is characterized by a similar orbital picture to that of C60−. Further laser experiments of significance are proposed.


Author(s):  
E. A. Tolkacheva ◽  
V. P. Markevich ◽  
L. I. Murin

The isotopic content of natural silicon (28Si (92.23 %), 29Si (4.68 %) и 30Si (3.09 %)) affects noticeably the shape of IR absorption bands related to the oxygen impurity atoms. In the present work an attempt is undertaken to determine the positions of local vibrational modes (LVMs), related to quasimolecules 28Si16OS29Si and 28Si16OS30Si (OS – substitutional oxygen atom), for the absorption spectra measured at room temperature. An estimation of the isotopic shifts of corresponding modes is done by fitting the shape of the experimentally measured absorption band related to the vacancy–oxygen center in irradiated Si crystals. The LVM isotope shifts are found to be equal 2,2 ± 0.25 cm–1 for 28Si-16OS29Si and 4,3 ± 0,9 см–1 for 28Si-16OS30Si in relation to the basic band due to 28Si-16OS28Si, and the full width at half maximum of the A-center absorption band (28Si-16OS28Si) is 5,3 ± 0.25 cm–1. By means of infrared absorption spectroscopy a clear correlation between the disappearance of the divacancy (V2) in the temperature range 200–275 ºС and appearance of two absorption bands with their maxima at 825.8 and 839.2 cm–1 in irradiated oxygen-rich Si crystals is found. The band positioned at 825.8 cm–1 is assigned to a divacancy-oxygen defect V2O formed via an interaction of mobile V2 with interstitial oxygen (Oi ) atoms. The 839.2 cm–1 band is much more pronounced in neutron irradiated samples as compared to samples irradiated with electrons. We argue that it is related to a trivacancy–oxygen defect (V3O) formed via an interaction of mobile V3 with Oi atoms.


2017 ◽  
Vol 82 (9) ◽  
pp. 1063-1073 ◽  
Author(s):  
Yerzhan Imanbayev ◽  
Yerdos Ongarbayev ◽  
Yerbol Tileuberdi ◽  
Evgeniy Krivtsov ◽  
Anatoly Golovko ◽  
...  

Transformations of high-molecular-weight compounds of oil sand natural bitumen under the heat treatment were studied in this work. For that purpose the natural bitumen isolated from oil sand taken from the Beke field (Kazakhstan) was used as a substrate. Thermal processing of natural bitumen leads to a general change in the chemical composition of components and to an increase in the output of certain fractions. The contents of oil, tar and asphaltenes were determined and the elemental composition of tar-asphaltene compounds was evaluated. Molecular structures of the tar and asphaltene components of natural bitumen before and after cracking have been defined from the data of elemental analysis, NMR spectroscopy and molecular weight. The high molecular compounds were presented as giant molecules containing small aromatic islands some of which were linked by aliphatic chains, that was proved by infrared spectroscopy.


Author(s):  
K. Hema ◽  
P. Velayutham ◽  
C.O. Mohan ◽  
D. Sukumar ◽  
B. Sundaramoorthy ◽  
...  

Background: Seafood analogue is a ready to make value added product prepared out of surimi. Thermal processing of restructured products in retort pouches such as fish ball in curry medium, surimi stew in white tripod, boneless rohu balls in curry. Also no work had done on thermal processing of shrimp analogue products in retort pouches. The main objective of this work was to develop the analogue shrimp product from lizardfish and to compare the heat penetration attributes of analogue shrimp curry and masala using retort pouches and different sterilization methods such as steam / air over pressure retort and water immersion retort.Methods: Analogue shrimp products were prepared and thermally processed in retortable pouches. About 125g of shrimp analogue product and 100g of curry (masala) were filled in retort pouches of size, 150x200mm. Air inside the pouch was exhausted by steam injection followed by heat sealing and processing at 121.1°C in a retort by steam/air over pressure retort and water immersion retort. The difference in the heat penetration characteristics of analogue shrimp products processed in retort by steam/air over pressure retort and water immersion retort were studied. Result: The results showed that minimum heating lag factor and minimum come up time led to faster heating rate which decreased total process time in imitated shrimp curry by steam/ air retort. At the same time the cook value was low in curry medium processed by steam air retort. So finally conclude that imitated shrimp curry processed by steam air retort was good.


Foods ◽  
2019 ◽  
Vol 8 (6) ◽  
pp. 215 ◽  
Author(s):  
Zhijun Pan ◽  
Yiming Sun ◽  
Fangyuan Zhang ◽  
Xinbo Guo ◽  
Zhihua Liao

Carotenoids and folate are two mandatory supplying micronutrients for children or pregnant women. Inadequate intake of these two nutrients was relevant to a higher mortality of both children and pregnancies. This study is intended to investigate the thermal impact on the changes of carotenoids and folate in sweet potato roots (SPRs). Carotenoids were identified by high performance liquid chromatography (HPLC) while the folate was estimated using a microbial assay. An obvious decline was observed in total carotenoids after heating. Nevertheless, the content of provitamin compound β-carotene exhibited incredible stability during steaming and α-carotene multiplied in certain varieties, evidencing that SPRs could be an efficient way for addressing Vitamin A deficiency (VAD). As for the total folate contents, two varieties were found no significant loss after thermal process while the others showed a significant decrease. The results indicated that steaming process led to generally loss of both carotenoids and folate while the α-carotene and β-carotene were well preserved. The information provided by this study might help with enhancing the food quality in processing industry and the understanding in the nutrition changes during steaming.


1970 ◽  
Vol 13 (4) ◽  
pp. 1332-1334
Author(s):  
M. A. Orel ◽  
I. V. Kagarlitskaya ◽  
I. V. Lapatukhin ◽  
R. A. Kabirova

Sign in / Sign up

Export Citation Format

Share Document