scholarly journals A Review of the System-Intrinsic Nonequilibrium Thermodynamics in Extended Space (MNEQT) with Applications

Entropy ◽  
2021 ◽  
Vol 23 (12) ◽  
pp. 1584
Author(s):  
Purushottam D. Gujrati

The review deals with a novel approach (MNEQT) to nonequilibrium thermodynamics (NEQT) that is based on the concept of internal equilibrium (IEQ) in an enlarged state space SZ involving internal variables as additional state variables. The IEQ macrostates are unique in SZ and have no memory just as EQ macrostates are in the EQ state space SX⊂SZ. The approach provides a clear strategy to identify the internal variables for any model through several examples. The MNEQT deals directly with system-intrinsic quantities, which are very useful as they fully describe irreversibility. Because of this, MNEQT solves a long-standing problem in NEQT of identifying a unique global temperature T of a system, thus fulfilling Planck’s dream of a global temperature for any system, even if it is not uniform such as when it is driven between two heat baths; T has the conventional interpretation of satisfying the Clausius statement that the exchange macroheatdeQflows from hot to cold, and other sensible criteria expected of a temperature. The concept of the generalized macroheat dQ=deQ+diQ converts the Clausius inequality dS≥deQ/T0 for a system in a medium at temperature T0 into the Clausius equalitydS≡dQ/T, which also covers macrostates with memory, and follows from the extensivity property. The equality also holds for a NEQ isolated system. The novel approach is extremely useful as it also works when no internal state variables are used to study nonunique macrostates in the EQ state space SX at the expense of explicit time dependence in the entropy that gives rise to memory effects. To show the usefulness of the novel approach, we give several examples such as irreversible Carnot cycle, friction and Brownian motion, the free expansion, etc.

Open Physics ◽  
2020 ◽  
Vol 18 (1) ◽  
pp. 1161-1167
Author(s):  
Marin Marin ◽  
Praveen Ailawalia ◽  
Ioan Tuns

Abstract In this paper, we obtain a generalization of the Gronwall’s inequality to cover the study of porous elastic media considering their internal state variables. Based on some estimations obtained in three auxiliary results, we use this form of the Gronwall’s inequality to prove the uniqueness of solution for the mixed initial-boundary value problem considered in this context. Thus, we can conclude that even if we take into account the internal variables, this fact does not affect the uniqueness result regarding the solution of the mixed initial-boundary value problem in this context.


Author(s):  
Kumar V. Singh ◽  
Xiaoxuan Ling

Viscoelastic materials both stores and dissipate energies and have frequency and temperature dependent properties and hence by tuning and optimizing their damping (viscous) and stiffness (elastic) properties they can be used as passive controlling devices in wide range of vibration applications. If the control of viscoelastic systems (viscoelastic structures or structures composed of viscoelastic elements) to be realized by active means, then an accurate mathematical modeling of the viscoelastic system is needed. In practice, various material models and approximation techniques such as Biot model, Golla-Hughes-McTavish (GHM) model and Anelastic Displacement Field (ADF) methods are used to model the dynamic behavior of viscoelastic systems. These models are then transformed into approximating state space models which introduces several challenges: (i) they increase the size of the related eigenvalue problems, (ii) state space realization introduces non-physical internal state variables, and, (iii) the feedback control implementation poses practical challenges such as observer and state estimator design. In this research it is shown that the active control for viscoelastic structures can be designed accurately by only utilizing the available transfer functions. These transfer functions can be obtained from dynamic experiments and the active feedback control is designed without having the knowledge of approximated state-space system matrices. The problem associated with the active control for viscoelastic system is formulated as feedback control problems in frequency domain by using the receptance method. Active control for poles and zeros assignment of the viscoelastic systems is demonstrated using numerical examples associated with the multi-degree-degree of freedom systems. It is also shown that a nested active controller can also be designed for continuous structures (beams/rods) supported by viscoelastic elements. It is highlighted that such a controller design requires modest size of transfer functions and solution of the set of linear system of equations.


2002 ◽  
Vol 8 (7) ◽  
pp. 1033-1050 ◽  
Author(s):  
J. De Cuyper ◽  
M. Verhaegen

This paper introduces a novel approach for trajectory tracking on seat test rigs. Seat test rigs are used in the automotive industry to test prototypes of new seats with respect to their comfort and vibration characteristics. Classically, a digital Fourier transform (DFT) approach, based on a Frequency Response Function (FRF) model, is used in this domain and different software packages exist that are based on this approach. The novel approach proposes state space models to identify the test rig and uses the recently developed Stable Dynamic Inversion (SDI) to invert the obtained state space models. The approach is validated on an industrial seat test rig and it is shown that the new approach is a competitive alternative to the existing DFT based methods. A closed loop experiment is also performed; this shows that the feedback controller allows one to reduce the state space model order without loss of accuracy.


2017 ◽  
Vol 140 (2) ◽  
Author(s):  
Kumar V. Singh ◽  
Xiaoxuan Ling

Viscoelastic materials have frequency and temperature-dependent properties and they can be used as passive controlling devices in wide range of vibration applications. In order to design active control for viscoelastic systems, an accurate mathematical modeling is needed. In practice, various material models and approximation techniques are used to model the dynamic behavior of viscoelastic systems. These models are then transformed into approximating state-space models, which introduces several challenges such as introduction of nonphysical internal state variables and requirement of observer/state estimator design. In this paper, it is shown that the active control for viscoelastic structures can be designed accurately by only utilizing the available receptance transfer functions (RTF) and hence eliminating the need for state-space modeling for control design. By using the recently developed receptance method, it is shown that active control for poles and zeros assignment of the viscoelastic systems can be achieved. It is also shown that a nested active controller can also be designed for continuous structures (beams/rods) supported by viscoelastic elements. It is highlighted that such a controller design requires modest size of RTF and solution of the set of linear system of equations.


2020 ◽  
Author(s):  
Elaine Gallagher ◽  
Bas Verplanken ◽  
Ian Walker

Social norms have been shown to be an effective behaviour change mechanism across diverse behaviours, demonstrated from classical studies to more recent behaviour change research. Much of this research has focused on environmentally impactful actions. Social norms are typically utilised for behaviour change in social contexts, which facilitates the important element of the behaviour being visible to the referent group. This ensures that behaviours can be learned through observation and that deviations from the acceptable behaviour can be easily sanctioned or approved by the referent group. There has been little focus on how effective social norms are in private or non-social contexts, despite a multitude of environmentally impactful behaviours occurring in the home, for example. The current study took the novel approach to explore if private behaviours are important in the context of normative influence, and if the lack of a referent groups results in inaccurate normative perceptions and misguided behaviours. Findings demonstrated variance in normative perceptions of private behaviours, and that these misperceptions may influence behaviour. These behaviours are deemed to be more environmentally harmful, and respondents are less comfortable with these behaviours being visible to others, than non-private behaviours. The research reveals the importance of focusing on private behaviours, which have been largely overlooked in the normative influence literature.


2021 ◽  
Vol 11 (2) ◽  
pp. 674
Author(s):  
Marianna Koctúrová ◽  
Jozef Juhár

With the ever-progressing development in the field of computational and analytical science the last decade has seen a big improvement in the accuracy of electroencephalography (EEG) technology. Studies try to examine possibilities to use high dimensional EEG data as a source for Brain to Computer Interface. Applications of EEG Brain to computer interface vary from emotion recognition, simple computer/device control, speech recognition up to Intelligent Prosthesis. Our research presented in this paper was focused on the study of the problematic speech activity detection using EEG data. The novel approach used in this research involved the use visual stimuli, such as reading and colour naming, and signals of speech activity detectable by EEG technology. Our proposed solution is based on a shallow Feed-Forward Artificial Neural Network with only 100 hidden neurons. Standard features such as signal energy, standard deviation, RMS, skewness, kurtosis were calculated from the original signal from 16 EEG electrodes. The novel approach in the field of Brain to computer interface applications was utilised to calculated additional set of features from the minimum phase signal. Our experimental results demonstrated F1 score of 86.80% and 83.69% speech detection accuracy based on the analysis of EEG signal from single subject and cross-subject models respectively. The importance of these results lies in the novel utilisation of the mobile device to record the nerve signals which can serve as the stepping stone for the transfer of Brain to computer interface technology from technology from a controlled environment to the real-life conditions.


2020 ◽  
Vol 45 (3) ◽  
pp. 311-318
Author(s):  
Qiang Yang ◽  
Zhuofu Tao ◽  
Yaoru Liu

AbstractIn the kinetic rate laws of internal variables, it is usually assumed that the rates of internal variables depend on the conjugate forces of the internal variables and the state variables. The dependence on the conjugate force has been fully addressed around flow potential functions. The kinetic rate laws can be formulated with two potential functions, the free energy function and the flow potential function. The dependence on the state variables has not been well addressed. Motivated by the previous study on the asymptotic stability of the internal variable theory by J. R. Rice, the thermodynamic significance of the dependence on the state variables is addressed in this paper. It is shown in this paper that the kinetic rate laws can be formulated by one extended potential function defined in an extended state space if the rates of internal variables do not depend explicitly on the internal variables. The extended state space is spanned by the state variables and the rate of internal variables. Furthermore, if the rates of internal variables do not depend explicitly on state variables, an extended Gibbs equation can be established based on the extended potential function, from which all constitutive equations can be recovered. This work may be considered as a certain Lagrangian formulation of the internal variable theory.


ChemInform ◽  
2015 ◽  
Vol 46 (17) ◽  
pp. no-no
Author(s):  
Hajime Yokoyama ◽  
Takayoshi Kubo ◽  
Yosuke Matsumura ◽  
Junichi Hosokawa ◽  
Masahiro Miyazawa ◽  
...  

Nutrients ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 815
Author(s):  
Przemysław Domaszewski ◽  
Paweł Pakosz ◽  
Mariusz Konieczny ◽  
Dawid Bączkowicz ◽  
Ewa Sadowska-Krępa

Studies on muscle activation time in sport after caffeine supplementation confirmed the effectiveness of caffeine. The novel approach was to determine whether a dose of 9 mg/kg/ body mass (b.m.) of caffeine affects the changes of contraction time and the displacement of electrically stimulated muscle (gastrocnemius medialis) in professional athletes who regularly consume products rich in caffeine and do not comply with the caffeine discontinuation period requirements. The study included 40 professional male handball players (age = 23.13 ± 3.51, b.m. = 93.51 ± 15.70 kg, height 191 ± 7.72, BMI = 25.89 ± 3.10). The analysis showed that in the experimental group the values of examined parameters were significantly reduced (p ≤ 0.001) (contraction time: before = 20.60 ± 2.58 ms/ after = 18.43 ± 3.05 ms; maximal displacement: before = 2.32 ± 0.80 mm/after = 1.69 ± 0.51 mm). No significant changes were found in the placebo group. The main achievement of this research was to demonstrate that caffeine at a dose of 9 mg/kg in professional athletes who regularly consume products rich in caffeine has a direct positive effect on the mechanical activity of skeletal muscle stimulated by an electric pulse.


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