scholarly journals Chemical Shrinkage of Low Water to Cement (w/c) Ratio CEM I and CEM III Cement Pastes Incorporating Silica Fume and Filler

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1164
Author(s):  
Judy Kheir ◽  
Benoît Hilloulin ◽  
Ahmed Loukili ◽  
Nele De Belie

Chemical shrinkage (CS) is the reason behind early age cracking, a common problem for concrete with low water to cement ratios (w/c < 0.35) known as Ultra-High- and High-Performance Concrete (U-HPC). However, to avoid the crack development initiated by autogenous shrinkage, a precise measurement of CS is required, as the values obtained can determine the correct amount of internal curing agent to be added in the mixture to avoid crack formation. ASTM C1608 is the standardized method for performing CS tests. In this study, recommendations are provided to improve the reliability of results obtained with this standard method, such as good compaction of samples and the use of superplasticizer (SP) for low w/c ratios (≤0.2). Cement pastes with CEM I and CEM III have been tested at different w/c ratios equal to 0.2, 0.3 and 0.4 with and without the addition of superplasticizer. CS results following ASTM-C1608 dilatometry showed that the presence of mineral additions such as silica fume and filler reduced the chemical shrinkage, while CS increased with increasing w/c. Low w/c ratio pastes of CEM III had slightly higher CS rates than CEM I, while the opposite was noticed at higher w/c. SEM images illustrated the importance of a careful compaction and SP use.

2011 ◽  
Vol 466 ◽  
pp. 105-113 ◽  
Author(s):  
António Bettencourt Ribeiro ◽  
Vasco Medina ◽  
Augusto Gomes ◽  
Arlindo Gonçalves

Shrinkage Reducing Admixtures (SRA) are being used more often in concrete structures in order to better control shrinkage cracks. High-performance concrete, nowadays with large application, has more proneness to crack at very early age due to the lower W/C. In this type of concrete, autogenous shrinkage is usually more important than drying shrinkage. Autogenous shrinkage is due to the volume decrease inherent to binder hydration reactions. The rate of these reactions is influenced not only by the type of binder but also by the presence of chemical admixtures. It is recognized that SRA delay the hydration, being a secondary effect of this type of admixtures. In this work changes on the degree of hydration of cement pastes with SRA and different binders are presented, using the chemical shrinkage test.


2017 ◽  
Vol 726 ◽  
pp. 521-526
Author(s):  
Di Zou ◽  
Lian Zhen Xiao ◽  
Wen Chong Shi

The cement-silica fume blended pastes were prepared with different silica fume (SF) dosages of 0%, 5%, 10%, and 15% at different water-binder ratios (W/B) of 0.4 and 0.5. The autogenous shrinkage (AS) and the drying shrinkage (DS) of the paste samples in the hydration period of 7d (168 hours) were measured by a new measurement technique to explore the influence of W/B and silica fume incorporation on the shrinkage in early age. The study results can provide reference for high performance concrete mix design.It is found that ether the AS or the DS of the paste samples shows a similar pattern, and the AS development with hydration time appeared a temporary expansion period after a rapid growth, especially in the samples at a higher W/B or with a lower SF content. However, the DS development did not occur obvious expansion period.Three development trends were obtained for the factors of W/B and SF content. 1) the AS and DS of the pastes mainly occurred in early ages. The lower W/B, the shorter the rapid growth periods, and the higher the shrinkage ratio of 1d to 7d. For the pastes with W/B of 0.4, the AS grew rapidly in 1d and the DS grew rapidly in the first 10h, and the AS value in 1d reached to 63.6% of 7d, and the DS value reached to 62.1% of 7d in the paste with SF of 10%. For the pastes with W/B of 0.5, the rapid growth periods of the AS and DS respectively extended to 30~33h and 12h, and the AS value in 1d reached to 60.0% of 7d, and the DS value reached to 57.2% of 7d in the paste with SF of 10%. 2) The lower W/B, the higher the shrinkage ratio of the AS to the DS. When the SF dosage is 10%, the ratio of the AS value to the DS value of 7d is 21.66%~21.15% for W/B of 0.4, and only 6.06%~5.78% for the W/B of 0.5. 3) the higher SF content results in the higher AS in cement-SF blended pastes. For the pastes with W/B of 0.4, the ratio of the AS to the DS increased from 6.98% to 30.16% with the increase of content of SF from 5% to 15% in 1d, from 15.1% to 28.19% in 3d, from 16.78% to 26.16% in 7d.


2021 ◽  
Author(s):  
Jedadiah Burroughs ◽  
Jason Weiss ◽  
John Haddock

Specialized classes of concrete, such as ultra-high-performance concrete, use volumes of silica fume in concrete that are higher than those in conventional concrete, resulting in increased water demand and mixing difficulty. This study considered the effects of eight different silica fumes in three dosages (10%, 20%, 30%) with three w/b (0.20, 0.30, 0.45) on rheological behavior as characterized by the Herschel-Bulkley model. Results indicated that the specific source of silica fume used, in addition to dosage and w/b, had a significant effect on the rheological behavior. As such, all silica fumes cannot be treated as equivalent or be directly substituted one for another without modification of the mixture proportion. The rheology of cement pastes is significantly affected by the physical properties of silica fume more so than any chemical effects.


2016 ◽  
Vol 711 ◽  
pp. 143-149
Author(s):  
Jennifer Anette Canul-Polanco ◽  
Alejandro Durán-Herrera ◽  
Pedro Valdez-Tamez

Durability in High Performance Concrete have resulted in the development of admixtures to mitigate several concrete deterioration mechanisms. Due to the low water/binder, HPC enables autogenous shrinkage that could lead to cracks at early ages. Superabsorbent polymers, shrinkage reducing admixtures and corrosion inhibitor based on calcium nitrite were used in HPC with silica fume to evaluate autogenous shrinkage. SAP was added with an amount of intenal curing water determined by the modification proposed by Jensen to the Power’s Model. Results showed that admixtures could improve or aggravate autogenous shrinkage.


2013 ◽  
Vol 457-458 ◽  
pp. 318-322 ◽  
Author(s):  
Li Xie

The influence rules of the mineral admixtures containing fly ash, ground slag and silica fume on the early-age autogenous shrinkage of high-performance concrete have been discussed in this paper. According to the research results, fly ash mixture can substantially decrease the early-age autogenous shrinkage of high-performance concrete, while the silica fume will increase the autogenous shrinkage. Meanwhile the influence of ground slag on autogenous shrinkage is related to its fineness and admixture amount. Generally, it is believed that when the fineness of the fly ash is higher than 4000cm2/g, the autogenous shrinkage will increase with the increasing admixture amount. The double admixture or multi-admixture of fly ash or ground slag is better for reducing the early-age autogenous shrinkage of concrete than the single-admixture. The early-age autogenous shrinkage of concrete occurs in distinctive linear dependence with the three types of mineral admixtures.


Author(s):  
Rizwan Ahmad Khan ◽  

This paper investigates the fresh and durability properties of the high-performance concrete by replacing cement with 15% Silica fume and simultaneously replacing fine aggregates with 25%, 50%, 75% and 100% copper slag at w/b ratio of 0.23. Five mixes were analysed and compared with the standard concrete mix. Fresh properties show an increase in the slump with the increase in the quantity of copper slag to the mix. Sorptivity, chloride penetration, UPV and carbonation results were very encouraging at 50% copper slag replacement levels. Microstructure analysis of these mixes shows the emergence of C-S-H gel for nearly all mixes indicating densification of the interfacial transition zone of the concrete.


2009 ◽  
Vol 419-420 ◽  
pp. 1-4 ◽  
Author(s):  
Ying Wei Yun ◽  
Ii Young Jang ◽  
Seong Kyum Kim ◽  
Seung Min Park

High-performance concrete (HPC) as a promising construction material has been widely used in infrastructures and high-rise buildings etc. However, its pretty high autogenous shrinkage (AS) especially in its early age becomes one of the key problems endangering long-time durability of HPC structures. This paper carried out the early age AS research of large scaled HPC column specimens by embedded Fiber Bragg-Grating (FBG) strain sensor. Temperature compensation for FBG strain sensor by thermocouple was also attempted in this paper, and the results were reasonable and acceptable comparing with the result compensated by FBG temperature sensor. Reinforcement influence, size effect and temperature effect on HPC AS were also analyzed respectively in this paper.


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