scholarly journals Viscosity Model for Nanoparticulate Suspensions Based on Surface Interactions

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2752
Author(s):  
Benedikt Finke ◽  
Clara Sangrós Sangrós Giménez ◽  
Arno Kwade ◽  
Carsten Schilde

In this paper, a widely mechanistic model was developed to depict the rheological behaviour of nanoparticulate suspensions with solids contents up to 20 wt.%, based on the increase in shear stress caused by surface interaction forces among particles. The rheological behaviour is connected to drag forces arising from an altered particle movement with respect to the surrounding fluid. In order to represent this relationship and to model the viscosity, a hybrid modelling approach was followed, in which mechanistic relationships were paired with heuristic expressions. A genetic algorithm was utilized during model development, by enabling the algorithm to choose among several hard-to-assess model options. By the combination of the newly developed model with existing models for the various physical phenomena affecting viscosity, it can be applied to model the viscosity over a broad range of solids contents, shear rates, temperatures and particle sizes. Due to its mechanistic nature, the model even allows an extrapolation beyond the limits of the data points used for calibration, allowing a prediction of the viscosity in this area. Only two parameters are required for this purpose. Experimental data of an epoxy resin filled with boehmite nanoparticles were used for calibration and comparison with modelled values.

2019 ◽  
Vol 12 (2) ◽  
Author(s):  
Tawqeer Zada

In this paper, a two-parameter mechanistic model for the fatigue crack growth has been developed. Fatigue failure is the major causes of mechanical structural failure. The fatigue failure progress in three stages crack initiation, crack growth and final failure. The fatigue crack growth has been modelled by different approaches, however these approaches are generally empirical. In this paper, a mechanistic fatigue crack growth model is proposed. The striation and its relation to the cyclic load is used for the model development. Scanning electronic microscope results are used to establish relation between striation and crack growth. The developed model is two-parameters. The model has been implemented and validated using experimental data from the literature. The model prediction is satisfactory in region II of the crack growth curve. However, in region I and region III the model deviates from experimental data. It is suggested to incorporate interaction of monotonic and cyclic loading in the mechanistic modelling for the fatigue growth.


2021 ◽  
Vol 99 (Supplement_1) ◽  
pp. 55-56
Author(s):  
Christian D Ramirez-Camba ◽  
Crystal L Levesque

Abstract A mechanistic model was developed with the objective to characterize weight gain and essential amino acid (EAA) deposition in the different tissue pools that make up the pregnant sow: placenta, allantoic fluid, amniotic fluid, fetus, uterus, mammary gland, and maternal body were considered. The data used in this modelling approach were obtained from published scientific articles reporting weights, crude protein (CP), and EAA composition in the previously mentioned tissues; studies reporting not less than 5 datapoints across gestation were considered. A total of 12 scientific articles published between 1977 and 2020 were selected for the development of the model and the model was validated using 11 separate scientific papers. The model consists of three connected sub-models: protein deposition (Pd) model, weight gain model, and EAA deposition model. Weight gain, Pd, and EAA deposition curves were developed with nonparametric statistics using splines regression. The validation of the model showed a strong agreement between observed and predicted growth (r2 = 0.92, root mean square error = 3%). The proposed model also offered descriptive insights into the weight gain and Pd during gestation. The model suggests that the definition of time-dependent Pd is more accurately described as an increase in fluid deposition during mid-gestation coinciding with a reduction in Pd. In addition, due to differences in CP composition between pregnancy-related tissues and maternal body, Pd by itself may not be the best measurement criteria for the estimation of EAA requirement in pregnant sows. The proposed model also captures the negative maternal Pd that occurs in late gestation and indicates that litter size influences maternal tissue mobilization more than parity. The model predicts that the EAA requirements in early and mid-gestation are 75, 55 and 50% lower for primiparous sows than parity 2, 3 and 4+ sows, respectively, which suggest the potential benefits of parity segregated feeding.


Author(s):  
Moncef Nehdi ◽  
Sidney Mindess

The emergence of new special concretes on construction sites has shown that concretes of the same slump may behave quite differently on the job. For these concretes, one cannot rely on the traditional workability tests for quality control and rheological characterization. It has been claimed that the flow behavior of fresh concrete closely approximates the Bingham model and that at least two parameters are therefore needed to describe its rheology. Thus, rheological measurements must be carried out at not fewer than two shear rates. This study examines the applicability of the Bingham model to fluid and self-leveling highstrength concrete (HSC). Results obtained from a rheometer are compared with results of the standard slump test. Fluid concrete mixtures were investigated that had a water/binder ratio ( w/ b) of 0.33 and slump values of 200 ± 20 mm and incorporated proportions of limestone filler, silica fume, and ground silica as partial replacement (by volume) of cement. In addition, self-leveling concrete mixtures (torque viscosity ≤ 1 Nm at 15 min) having a w/ b ratio of 0.25 and 15 percent replacement of cement by various fillers were examined. The possibility of characterizing the rheology of fluid and self-leveling HSC on the basis of only two tests carried out at two different shear rates was addressed. An effort was made to define which is more relevant in a rheometer flow curve: the ascending part, the descending part, the maximum stress requirement, the flow resistance, the torque viscosity, or combinations of these factors. The possibility of measuring the rapid stiffening behavior of fresh HSC with time and the effect of ultrafine particles on the rheology using rheometric tests were also investigated.


Author(s):  
Yasushi Uehara ◽  
Noriyuki Shirakawa ◽  
Masanori Naitoh ◽  
Hidetoshi Okada ◽  
Hidemasa Yamano ◽  
...  

Governing key phenomena in core disruptive accidents (CDAs) in sodium-cooled fast reactors (SFRs) are supposed to be (1) fuel pin failure and disruption, (2) molten pool boiling, (3) melt freezing and blockage formation, (4) duct wall failure, (5) low-energy disruptive core motion, (6) debris-bed coolability, and (7) metal-fuel pin failure with eutectics between fuel and steel [1]. Although the systematic assessment program for SIMMER-III [4–7] has provided a technological basis that SIMMER-III is practically applicable to integral reactor safety analyses, further model development and validation efforts should be made to make future reactor calculations more reliable and rational. For mechanistic model development, a mesoscopic approach with the COMPASS code [1, 2, 3] is expected to advance the understanding of these key phenomena during event progression in CDAs. The COMPASS code has been developed since FY2005 (Japanese Fiscal Year, hereafter) to play a complementary role to SIMMER-III. In this paper, the overall analysis of SCARABEE-BE+3 test with the SIMMER-III and those with COMPASS, focusing the duct wall failure in a small temporal and spatial window cut from the SIMMER-III analysis results of the test, are described.


2012 ◽  
Vol 538-541 ◽  
pp. 2794-2797
Author(s):  
Jun Wu ◽  
Li Bo Cao ◽  
Rui Feng Zhang ◽  
Jing Wen Hu

In this study, an occupant restraint system model of a production SUV developed in MADYMO software was used for crash simulations. Component tests were conducted to obtain the parameters of seatbelt and seat. Parameters of airbag were obtained by tank tests and the airbag model was validated by headform drop tests. The occupant restraint system model was validated against results from real vehicle crash tests. Robust design method was adopted for sensitivity analysis and system optimization. Two parameters, spool effect of the seatbelt and mass flow of the airbag, were studied to improve the occupant protection. Better protection performance has been obtained using optimized parameters, and the robustness of the optimized result was proved by robustness assessment.


1948 ◽  
Vol 159 (1) ◽  
pp. 313-334 ◽  
Author(s):  
J. Kestin ◽  
A. K. Oppenheim

Calculations of the flow of gases in pipes or ducts of varying cross-sections are important in the design of turbines and compressors, nozzles for various applications, exhaust or radiator ducts, thrust augmenting devices, etc. Provided certain simplifying assumptions are made, there is no difficulty in writing down the basic equations, but when the velocities are comparable to that of sound and compressibility effects cannot therefore be neglected, the solution of the transcendental equations present difficulties which hinder a clear discussion of the physical phenomena. Here the problem is solved by the use of a generalized entropy chart, off which results may be directly read. For example, if the conditions in the reservoir from which the gas is assumed to be discharged are known, the complete conditions at any given cross-section may be read off when two parameters at the section considered are specified. The parameters may include the velocity, pressure, density, temperature, local Mach number, local velocity of sound, area of cross-section, mass flow per unit area, momentum per second, etc. The method is not confined to isentropic flows and may be applied to such problems as the flow in straight pipes or convergent and divergent nozzles including losses by either friction or condensation shocks. The co-ordinates of the chart are: dimensionless entropy σ = ( s— s0) J/R and dimensionless enthalpy ι = h/h0 = T/T0 where the meaning of the symbols is given later. All other variables are expressed in terms of these two co-ordinates and tables for several values of the ratio of specific heats are included to facilitate the drawing of such charts. The method does not aim at presenting new facts, but its usefulness lies in the provision of a comprehensive graphical means of calculating one-dimensional flow of compressible fluids. The charts lend themselves to the construction of a mechanical device for simplifying their use, such as a portable scale with sliding curves.


2009 ◽  
Vol 131 (12) ◽  
Author(s):  
Wen Wu ◽  
Barclay G. Jones ◽  
Ty A. Newell

A mechanistic model for the boiling heat flux prediction proposed in Part I of this two-part paper (2009, “A Statistical Model of Bubble Coalescence and Its Application to Boiling Heat Flux Prediction—Part I: Model Development,” ASME J. Heat Transfer, 131, p. 121013) is verified in this part. In the first step, the model is examined by experiments conducted using R134a covering a range of pressures, inlet subcoolings, and flow velocities. The density of the active nucleation sites is measured and correlated with critical diameter Dc and static contact angle θ. Underlying submodels on bubble growth and bubble departure/lift-off radii are validated. Predictions of heat flux are compared with the experimental data with an overall good agreement observed. This model achieves an average error of ±25% for the prediction of R134a boiling curves, with the predicted maximum surface heat flux staying within ±20% of the experimentally measured critical heat flux. In the second step, the model is applied to water data measured by McAdams et al. (1949, “Heat Transfer at High Rates to Water With Surface Boiling,” Ind. Eng. Chem., 41(9), pp. 1945–1953) in vertical circular tubes. The consistency suggests that the application of this mechanistic model can be extended to other flow conditions if the underlying submodels are appropriately chosen and the assumptions made during model development remain valid.


2012 ◽  
Vol 504-506 ◽  
pp. 1269-1274 ◽  
Author(s):  
François Ducobu ◽  
Edouard Rivière-Lorphèvre ◽  
Enrico Filippi

Micro-milling with a cutting tool is a manufacturing technique that allows production of parts ranging from several millimeters to several micrometers. The technique is based on a downscaling of macroscopic milling process. Micro-milling is one of the most effective process to produce complex three-dimensional micro-parts, including sharp edges and with a good surface quality. Reducing the dimensions of the cutter and the cutting conditions requires taking into account physical phenomena that can be neglected in macro-milling. These phenomena include a size effect (nonlinear rising of specific cutting force when chip thickness decreases), the minimum chip thickness (under a given dimension, no chip can be machined) and the heterogeneity of the material (the size of the grains composing the material is significant as compared to the dimension of the chip). The aim of this paper is to introduce some phenomena, appearing in micromilling, in the mechanistic dynamic simulation software ‘dystamill’ developed for macro-milling. The software is able to simulate the cutting forces, the dynamic behavior of the tool and the workpiece and the kinematic surface finish in 2D1/2 milling operation (slotting, face milling, shoulder milling,…). It can be used to predict chatter-free cutting condition for example. The mechanistic model of the cutting forces is deduced from the local FEM simulation of orthogonal cutting. This FEM model uses the commercial software ABAQUS and is able to simulate chip formation and cutting forces in an orthogonal cutting test. This model is able to reproduce physical phenomena in macro cutting conditions (including segmented chip) as well as specific phenomena in micro cutting conditions (minimum chip thickness and size effect). The minimum chip thickness is also taken into account by the global model. The results of simulation for the machining of titanium alloy Ti6Al4V under macro and micro milling condition with the mechanistic model are presented discussed. This approach connects together local machining simulation and global models.


2011 ◽  
Vol 38 (2) ◽  
pp. 210-220 ◽  
Author(s):  
Luis Esteban Amador-Jiménez ◽  
Donath Mrawira

This paper proposes the use of multi-level Bayesian modeling for calibrating mechanistic model parameters from historical data while capturing reliability by estimating a desired confidence interval of the predictions. The model is capable of estimating the parameters from the observed data and expert criteria even in cases of missing data points. This approach allows rapid generation of several deterioration models without the need to partition the data into pavement families. It estimates posterior distributions for model coefficients and predicts values of the response for unobserved levels of the causal factors. A case study from the New Brunswick Department of Transportation is used to calibrate a simplified mechanistic pavement roughness progression model based on 6-year international roughness index (IRI) observations. The model incorporates the effects of pavement structural capacity in terms of deflection basin parameter (AREA) in place of the modified structural number, traffic loading (ESAL) and environmental factors. The results of the model showed that, as expected, chipseal roads have higher as built roughness and deteriorate faster than asphalt roads. Sensitivity analysis of the deterministic (the mean predictions) part of the model showed that in New Brunswick where traffic is relatively low the environment is the most important factor.


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