scholarly journals Thermodilatometric Study of the Decay of Zeolite-Bearing Building Materials

Materials ◽  
2021 ◽  
Vol 14 (13) ◽  
pp. 3551
Author(s):  
Michele Pansini ◽  
Angelo Cappi ◽  
Vincenzo Monetti ◽  
Enrico Di Clemente ◽  
Maurizio de Gennaro ◽  
...  

Six zeolite-bearing rocks, often used as building materials, were analyzed by thermodilatometry, together with a rock not bearing zeolites and a plaster covering a containing wall made of zeolite-bearing dimension stones, up to 250 °C. The main results obtained were the following: (i) the zeolite-bearing rocks exhibited very small, if any, positive variation of ΔL/Lo (%) up to about 100 °C, whereas they more or less shrank in the temperature range 100–250 °C (final values ranging from −0.21 to −0.92%); (ii) the rock not bearing zeolites regularly expanded through the whole temperature range, attaining a final value of 0.19%; (iii) the plaster showed a thermodilatometric behavior strongly affected by its water content. Obtained results were interpreted based on plain thermal expansion, shrinkage by dehydration, cation migration and thermal collapse of the zeolitic structure. The decay of the zeolite-bearing building materials was essentially related to: (i) the large differences recorded in the thermodilatometric behavior of the various rocks and the plaster; (ii) the different minerogenetic processes that resulted in the deposition of the various zeolite-bearing rocks.

2020 ◽  
Vol 263 ◽  
pp. 120107
Author(s):  
Romain Damez ◽  
Philippe Artillan ◽  
Arthur Hellouin de Menibus ◽  
Cédric Bermond ◽  
Pascal Xavier

2007 ◽  
Vol 539-543 ◽  
pp. 3261-3266 ◽  
Author(s):  
Iulian Radu ◽  
Dong Yang Li

The near-equiatomic TiNi alloy has been demonstrated to possess high wear resistance, which largely benefits from its pseudoelasticity (PE). However, the PE occurs only in a small temperature range, which makes the wear resistance of this alloy unstable as temperature changes, caused by environmental instability or frictional heating. Therefore, enlarging the working temperature of PE could considerably improve this alloy as a novel wear-resistant material. One possible approach is to develop a self-built temperature-dependent internal stress field by taking the advance of the difference in thermal expansion between the pseudoelastic matrix and a reinforcing phase. Such a T-dependent internal stress could adjust the martensitic transformation temperature to respond changes in environmental temperature so that the temperature range of PE could be enlarged, thus leading to a wide temperature range in which the minimum wear loss is retained. Research was conducted to investigate effects of an added second phase having a negative thermal expansion (NTE) coefficient on the wear resistance of a near-equiatomic TiNi alloy. It was demonstrated that the temperature range of this modified material in which the wear loss dropped was enlarged. In addition, the wear resistance of such a TiNi-matrix composite was on one order of magnitude higher than that of unmodified TiNi alloy.


2012 ◽  
Vol 68 (1) ◽  
pp. 91-91 ◽  
Author(s):  
K. Röttger ◽  
A. Endriss ◽  
Jörg Ihringer ◽  
S. Doyle ◽  
W. F. Kuhs

In a previous paper we reported the lattice constants and thermal expansion of normal and deuterated ice Ih [Röttger et al. (1994). Acta Cryst. B50, 644–648]. Synchrotron X-ray powder diffraction data were used to obtain the lattice constants and unit-cell volumes of H2O and D2O ice Ih in the temperature range 15–265 K. A polynomial expression was given for the unit-cell volumes. It turns out that the coefficients quoted have an insufficient number of digits to faithfully reproduce the volume cell data. Here we provide a table with more significant digits. Moreover, we also provide the coefficients of a polynomial fit to the previously published a and c lattice constants of normal and deuterated ice Ih for the same temperature range.


1993 ◽  
Vol 101 (1171) ◽  
pp. 305-308
Author(s):  
Kazuyuki KAWAI ◽  
Hideki ISHIDA ◽  
Nozomu OTSUKA

Crystals ◽  
2018 ◽  
Vol 9 (1) ◽  
pp. 11 ◽  
Author(s):  
Chao Jiang ◽  
Feifei Chen ◽  
Fapeng Yu ◽  
Shiwei Tian ◽  
Xiufeng Cheng ◽  
...  

A high-quality Ba2TiSi2O8 (BTS) single crystal was grown using the Czochralski (Cz) pulling method. The thermal expansion and electro-elastic properties of BTS crystal were studied for high temperature sensor applications. The relative dielectric permittivities ε 11 T / ε 0 and ε 33 T / ε 0 were determined to be 16.3 and 11.8, while the piezoelectric coefficients d15, d31, d33 were found to be 17.8, 2.9, and 4.0 pC/N, respectively. Temperature dependence of electro-elastic properties were investigated, where the variation of elastic compliance s 55 E (= s 44 E ) was found to be <6% over temperature range of 20–700 °C. Taking advantage of the anisotropic thermal expansion, linear thermal expansion comparable to insulating alumina ceramic was achieved over temperature range up to 650 °C. The optimum crystal cut with large effective piezoelectric coefficient (>8.5 pC/N) and linear thermal expansion coefficient (8.03 ppm/°C) achieved for BTS crystal along the (47°, φ) direction (φ is arbitrary in 0–360°), together with its good temperature stability up to 650 °C, make BTS crystal a promising candidate for high temperature piezoelectric sensors.


2018 ◽  
Vol 57 (22) ◽  
pp. 14396-14400 ◽  
Author(s):  
Cheng Yang ◽  
Yugang Zhang ◽  
Jianming Bai ◽  
Peng Tong ◽  
Jianchao Lin ◽  
...  

2018 ◽  
Vol 113 (18) ◽  
pp. 181902 ◽  
Author(s):  
N. Katayama ◽  
K. Otsuka ◽  
M. Mitamura ◽  
Y. Yokoyama ◽  
Y. Okamoto ◽  
...  

1993 ◽  
Vol 07 (01n03) ◽  
pp. 810-813
Author(s):  
N.H. KIM-NGAN ◽  
P.E. BROMMER ◽  
J.J.M. FRANSE

Specific heat and thermal expansion measurements have been performed on Nd1−xLUxMn2 in the temperature range between 1.5K and 300K. Below 10K, anomalies are observed which are ascribed to a spin reorientation of the Nd sublattice. These anomalies are only slightly affected by the substitution of Nd by Lu. Large effects, however, are observed on the magnetic properties of the Mn sublattice. The antiferromagnetic order disappears for x exceeding 0.30. The data are analysed in terms of Grüneisen parameters. In the paramagnetic compound LuMn2, a spin-fluctuation contribution to the thermodynamic properties is observed. In the Nd-containing compounds, distinct contributions from the crystal field acting on the Nd ions can be distinguished. The variation of the magnetic properties of the Mn sublattice with the concentration of Lu is discussed.


2018 ◽  
Vol 6 ◽  
Author(s):  
Wenjun Zhao ◽  
Ying Sun ◽  
Yufei Liu ◽  
Kewen Shi ◽  
Huiqing Lu ◽  
...  

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