scholarly journals Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater

Materials ◽  
2021 ◽  
Vol 14 (22) ◽  
pp. 6764
Author(s):  
Yingxiao Zhang ◽  
Tingting Yan ◽  
Lin Fan ◽  
Zhiyong Liu ◽  
Longfei Song ◽  
...  

The effect of pH on the corrosion and repassivation behavior of TA2 in simulated seawater was studied using electrochemical tests, immersion experiments, and surface morphology topology analysis. The results show that Ecorr and Rf increased while ipass and weight loss rate decreased as the pH of simulated seawater increased. The TA2 passive film was determined to be mainly composed of a large amount of TiO2 and a small amount of TiO. The repassivation function of TA2 can be expressed as E = −0.1375 + 0.0532ln(t − 1.241) for a simulated seawater pH of 8.2. The parameter b, which represents the slope of the potential–time curve during the friction electrode test, was used to evaluate the repassivation behavior of TA2. The increase in pH value was observed to promote the repassivation speed of the passive film, which is beneficial to the corrosion resistance of TA2.

2013 ◽  
Vol 864-867 ◽  
pp. 40-43
Author(s):  
Song Liu

This study obtained 12 microbial degradation of cellulose from perennial accumulation of cellulose waste soil, through Congo red staining, isolated high efficient bacteria N4 degradation of cellulose. The N4 strain degradation single factor experiment showed that: carbon concentration, incubation temperature and initial pH value influence on the degradation of filter paper. Through the orthogonal experimental study obtained: when the concentration of filter paper is 0.5%, culture temperature is 30 °C, initial pH is 8, N4 strain filter paper degradation rate reached optimal, filter paper weight loss rate of 68.92%.


2013 ◽  
Vol 690-693 ◽  
pp. 999-1002 ◽  
Author(s):  
Xiao Li Zhang ◽  
Yin Di He

Laccase was selected totreat linen fabric. Such properties of linenfabric were analyzed as weight loss rate, whiteness, breakagestrength, capillary effect, flexural stiffness. The orthogonal test was designedabout pH value, temperature, time and concentration. The factorswere discussed on hemp fabric performance. The optimal process of laccase treatment on hemp fabricis: 50°C, pH4, 25ml/300ml, 50min. Underthe best conditions, hemp fabric weight lossrate 1.87%, breakingstrength 674.7N, whiteness 60.7,flexural stiffness 703.7, capillary effect 8.08cm,wrinkle recovery angle174 º. And the hempfiber’s microstructure changed.


2021 ◽  
pp. 095400832199674
Author(s):  
Tao Guo ◽  
Yang Fan ◽  
Chang Bo ◽  
Zhang Qi ◽  
Han Tao ◽  
...  

Benzoxazine resin exhibits excellent properties and is widely used in many fields. Herein, the synthesis of a novel compound, the bis(2,4-dihydro-2 H-3-(4- N-maleimido)phenyl-1,3-benzoxazinyl)biphenyl (BMIPBB), has been reported, which was synthesized by reacting N-(4-aminophenyl)maleimide (APMI), formaldehyde, and 4,4’-dihydroxybiphenyl. 1,3,5-three(4-(maleimido)phenyl)-1,3,5-triazine (TMIPT) was formed as an intermediate during the reaction. The proton nuclear magnetic resonance (1H-NMR) and Fourier transform-infrared (FTIR) spectroscopy experiments were conducted to determine the structure of BMIPBB. BMIPBB was obtained as a reddish-brown solid in 40.1% yield. The thermal properties of BMIPBB were investigated using differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) techniques. Analysis of the DSC curves revealed that the broad peak representing the release of curing reaction heat appeared in the temperature range of 140–330°C. The peak temperature was 242.59°C and the heat of the reaction was 393.82 J/g, indicating that the rate of the curing reaction was low and the heat of the reaction was high. Analysis of the TGA results revealed that the weight loss rate was 5% at 110°C. The monomer exhibited a significant weight loss in the range of 320–500°C. The compound lost 50% of its weight at a temperature of 427°C.


2011 ◽  
Vol 13 (8) ◽  
pp. 3301-3311 ◽  
Author(s):  
Zhongshi Liang ◽  
Yun Liu ◽  
Sameul S. Ng ◽  
Xiangyang Li ◽  
Lihui Lai ◽  
...  

2011 ◽  
Vol 399-401 ◽  
pp. 1967-1971
Author(s):  
Hong Yin Xu ◽  
Li Li

The paper through the synergy before mixed Phytic acid and Sodium molybdate, Sulfosalicylic acid, Organic silane, and add the active substances PEG, Optimize the Passivation liquid formula of Brass surface, Phytic acid is the main ingredient, study the affection of Phytic acid Passive film Corrosion resistance on the three main Passivation conditions: Passivation temperature, time and Passivation solution PH value. The results show that,Phytic acid passivation film process recipes as follows:Phytic acid (quality score 50%) 2~5ml/L, sodium molybdate 4~8g/L, organic material 10~30ml/L, sulfosalicylic acid 3~7g/L, polyethylene glycol 2~6g/L, deactivated temperature 30~35°C, pH value 5, deactivated time 60s. The test showed that,the phytic acid passive film can obviously enhance the anti-corrosive performance on the brass surface, its corrosion resistance proportion chromates passive film is fairly good.


1992 ◽  
Vol 55 (6) ◽  
pp. 449-452 ◽  
Author(s):  
DEOG-HWAN OH ◽  
DOUGLAS L. MARSHALL

The effect of pH on the minimum inhibitory concentration (MIC) of glycerol monolaurate (monolaurin) against four strains of Listeria monocytogenes at 35°C in tryptic soy broth supplemented with 0.6% yeast extract was investigated. Our results demonstrate that the MIC of monolaurin was lower than MIC values reported for other common food antimicrobials such as potassium sorbate, tertiary butylhydroquinone, propyl paraben, and butylated hydroxyanisole. The MIC of monolaurin was reduced by decreasing the pH value of the medium. A 3-fold MIC reduction occurred when the pH decreased from pH 7.0 (10 μg/ml) to pH 5.0 (3 μg/ml).


2016 ◽  
Vol 78 (8-3) ◽  
Author(s):  
Nur Farhana Jaafar ◽  
Aishah Abdul Jalil ◽  
Sugeng Triwahyono ◽  
Adnan Ripin ◽  
Mohamad Wijayanuddin Ali

Photocatalytic is one of the inexpensive and non-toxic techniques for degradation of organic pollutants into harmless substances such as water and carbon dioxide. In this study, simple electrolysis method was used in preparation of Ag/TiO2 and α-Fe2O3/HY catalysts. The physicochemical properties of the catalysts were studied using XRD, FTIR, FESEM-EDX and surface area analysis. The pH of solution plays an important role in the photocatalytic degradation of organic pollutants which influences the surface-charge properties of the catalysts. Ag/TiO2 and α-Fe2O3/HY were used as catalyst on degradation of 2-chlorophenol (2-CP) and methyl orange (MO), respectively. The effect of pH on degradation of 2-CP and MO were investigated over a pH range from 2 to 9. Higher degradation of 2-CP and MO were obtained at pH 5 (74%) and pH 2 (80%), respectively. This finding might be explained by the amphoteric performance of the catalyst using point zero charge (pHZPC). The pHZPC for Ag/TiO2 and α-Fe2O3/HY was found to be at pH 6.3 and pH 7.2, respectively. Hence, the activities of the catalysts may have been affected by the existence of a strong electrostatic field between the positively charged catalysts surface and negatively charged 2-CP and MO caused a pH value lower than their pHZPC give greater degradation.


2018 ◽  
Vol 225 ◽  
pp. 02002 ◽  
Author(s):  
Girma T. Chala ◽  
Ying P. Lim ◽  
Shaharin A. Sulaiman ◽  
Chin L. Liew

This paper presents the characteristics of empty fruit bunch (EFB) using thermogravimetric analysis (TGA) and shows its potential as a renewable energy sources. A set of data were collected from the thermal reaction and plotted in mass or percentage of the initial mass against either temperature or time, respectively. In the thermogravimetric analysis, mass, temperature and time were considered as base measurements and important data for derivative thermogravimetric (DTG) curve were analysed while many additional measures could be derived from these three base measurements. It was observed that heating rate of 8.5°C/min and air flow rate of 85mL/min provided a maximum weight loss rate of 0.209%/°C at the temperature of 313.5°C and the derivative weight peak of -0.1895mg/°C at 292°C. The time taken to reach the maximum temperature of 899.9°C was 46.74 minutes, and ΔT endo-up reflected minimum point of -0.2°C at 15.82 minutes and maximum ΔT endo-up of 888°C at 42 minutes. Heat flow endo-up also showed that the minimum heat flow was 15.39mW at 15.85 minutes and reaching the peak heat flow endo-up of 47.73mW at 43.27 minutes.


2018 ◽  
Vol 33 (4) ◽  
pp. 605-609
Author(s):  
Hiroki YABE ◽  
Mizuki TSUKAMOTO ◽  
Shihomi TAKEUCHI ◽  
Sayaka ITO ◽  
Kan OMI ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document