scholarly journals Study of Hole-Transporter-Free Perovskite Solar Cells based on Fully Printable Components

Micromachines ◽  
2019 ◽  
Vol 10 (4) ◽  
pp. 266 ◽  
Author(s):  
Raminafshar ◽  
Raptis ◽  
Mohammadi ◽  
Lianos
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Ambient Conditions ◽  
Cell Scaffold ◽  
Standard Configuration ◽  
A Cell ◽  
The Cost ◽  
Contact Electrode ◽  
Made In

Hole-transporter-free perovskite solar cells carrying a carbon back contact electrode provide the possibility of making full printable low cost and stable devices, even though their efficiency is substantially lower than those made in the standard configuration. The present work searched for simple and easy routes for constructing such devices, demonstrating that organic components do enhance device efficiency but only to a level that is not worth the trouble nor the cost. Devices based on a triple mesoporous layer of titania/zirconia/carbon with perovskite infiltration gave an efficiency of 10.7%. After 180 days of storing under ambient conditions, a small loss of efficiency has been observed for a cell made in June, in spite of the fact that in going from June to December, a large increase of the ambient humidity took place, thus verifying the protective effect that the carbon electrode is providing. The addition of spiro-OMeTAD to the hole-transporter-free device resulted in increasing the efficiency by about 10%, a change which is appreciated to be of low importance given the cost of this material. This increase mainly derived from an increase in the current. Devices of different sizes have been constructed by screen printing, using home-made pastes for all the components making the cell scaffold, i.e., for titania, zirconia, and carbon layers.

scholarly journals Fabrication of low cost perovskite solar cell under ambient conditions using only spin coating deposition method

2018 ◽  
Vol 67 ◽  
pp. 01022 ◽  
Author(s):  
Michael Hariadi ◽  
Istighfari Dzikri ◽  
Retno Wigajatri Purnamaningsih ◽  
Nji Raden Poespawati
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Spin Coating ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Perovskite Solar Cell ◽  
Deposition Method ◽  
Ambient Conditions ◽  
Coating Deposition ◽  
Cost Constraints

Indonesia is an archipelagic nation that has many small islands where the average load is low and currently supplied by diesel power generators. The drawbacks from these generators are cost constraints from its operation. Solar cells are the solution of this problem with the support of daily average radiation in Indonesia of 4.8 kWh/m2/day. There has been a lot of technology for the construction of solar cells such as silicon based, copper indium gallium selenide (CIGS), which was already successfully commercialized. However, these technologies have been obsolete and started to reach its maximum potential. Perovskite solar cells have a very high future potential, due to the increase on the efficiency of this technology in a relatively short amount of time. The current challenge for the fabrication of perovskite solar cell is the material cost and fabrication cost. This paper discussed the low-cost fabrication of perovskite solar cell using only spin coating deposition method and relatively also low-cost materials for the structure of the perovskite solar cell itself. As a result, we achieve perovskite solar cell with VOC of 0.6 V, ISC of 13 mA, FF of 0.28, and 1.2% efficiency.

scholarly journals Molecularly engineered hole-transport material for low-cost perovskite solar cells

2020 ◽  
Vol 11 (9) ◽  
pp. 2429-2439
Author(s):  
Babak Pashaei ◽  
Sebastiano Bellani ◽  
Hashem Shahroosvand ◽  
Francesco Bonaccorso
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
Cheap Alternative ◽  
The Cost

Organic hole transport materials (HTMs) strongly affect the cost of efficient perovskite solar cells. In this work, a newly engineered HTM based on triphenylamine is proposed as a cheap alternative to efficient organic HTMs (e.g., spiro-OMeTAD).

scholarly journals Polyvinylpyrrolidone as additive for perovskite solar cells with water and isopropanol as solvents

2019 ◽  
Vol 10 ◽  
pp. 2374-2382
Author(s):  
Chen Du ◽  
Shuo Wang ◽  
Xu Miao ◽  
Wenhai Sun ◽  
Yu Zhu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Uv Spectroscopy ◽  
Low Cost ◽  
Lead Nitrate ◽  
Perovskite Solar Cells ◽  
Solar Irradiation ◽  
Ambient Conditions ◽  
Carrier Recombination ◽  
Photoelectric Performance ◽  
Low Toxicity

The recent years have witnessed a fast-paced development of perovskite solar cells (PSCs). Unfortunately, the vast majority of PSCs relies on the use of highly polar aprotic solvents during the preparation process, such as dimethylformamide (DMF), which is toxic and detrimental to both humans and the environment. Here, we describe the preparation of PSCs under ambient conditions from an aqueous solution of lead nitrate, to which polyvinylpyrrolidone (PVP) was added in order to enhance the photoelectric performance of the PSCs. By a combination of SEM, EIS, PL and UV spectroscopy and other characterization approaches, we show that the PVP additive is effective in inhibiting carrier recombination, enhancing composite resistance and reducing film defects. Ultimately, we achieved an outstanding photoelectric performance of the PVP-doped PSCs shown by a power conversion efficiency (PCE) of 15.19% and an average steady-state PCE of 14.55% under AM 1.5G simulated solar irradiation with a shadow mask of 0.1 cm2. The PCE continued to be over 80% of the initial PCE after 60 days of storage. FInally, the introduced PVP-doped PSCs present a low-cost and low-toxicity way to commercialize perovskite solar cells.

A sequential condensation route as a versatile platform for low cost and efficient hole transport materials in perovskite solar cells

2019 ◽  
Vol 7 (38) ◽  
pp. 21867-21873 ◽  
Author(s):  
Babak Pashaei ◽  
Hashem Shahroosvand ◽  
Mohsen Ameri ◽  
Ezeddin Mohajerani ◽  
Mohammad Khaja Nazeeruddin
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Hole Transport ◽  
The Cost

In an effort to diminish the cost of perovskite solar cells (PSCs) with regard to hole transport materials (HTMs), we employed an easily attainable condensation route to synthesize a cheap and efficient HTM.

scholarly journals Exploring the Effect of Ammonium Iodide Salts Employed in Multication Perovskite Solar Cells with a Carbon Electrode

Molecules ◽  
2021 ◽  
Vol 26 (19) ◽  
pp. 5737
Author(s):  
Maria Bidikoudi ◽  
Carmen Simal ◽  
Vasillios Dracopoulos ◽  
Elias Stathatos
Keyword(s):  
Solar Cells ◽  
High Efficiency ◽  
Positive Impact ◽  
Promising Result ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Precursor Solution ◽  
Ammonium Iodide ◽  
Ambient Conditions ◽  
Large Area

Perovskite solar cells that use carbon (C) as a replacement of the typical metal electrodes, which are most commonly employed, have received growing interest over the past years, owing to their low cost, ease of fabrication and high stability under ambient conditions. Even though Power Conversion Efficiencies (PCEs) have increased over the years, there is still room for improvement, in order to compete with metal-based devices, which exceed 25% efficiency. With the scope of increasing the PCE of Carbon based Perovskite Solar Cells (C-PSCs), in this work we have employed a series of ammonium iodides (ammonium iodide, ethylammonium iodide, tetrabutyl ammonium iodide, phenethylammonium iodide and 5-ammonium valeric acid iodide) as additives in the multiple cation-mixed halide perovskite precursor solution. This has led to a significant increase in the PCE of the corresponding devices, by having a positive impact on the photocurrent values obtained, which exhibited an increase exceeding 20%, from 19.8 mA/cm2, for the reference perovskite, to 24 mA/cm2, for the additive-based perovskite. At the same time, the ammonium iodide salts were used in a post-treatment method. By passivating the defects, which provide charge recombination centers, an improved performance of the C-PSCs has been achieved, with enhanced FF values reaching 59%, which is a promising result for C-PSCs, and Voc values up to 850 mV. By combining the results of these parallel investigations, C-PSCs of the triple mesoscopic structure with a PCE exceeding 10% have been achieved, while the in-depth investigation of the effects of ammonium iodides in this PSC structure provide a fruitful insight towards the optimum exploitation of interface and bulk engineering, for high efficiency and stable C-PSCs, with a structure that is favorable for large area applications.

An unconventional blade coating for low-cost fabrication of PCDTBT: PC70BM polymer and CH3NH3PbIxCl3-x perovskite solar cells

2021 ◽  
Vol 23 ◽  
pp. 100969
Author(s):  
Anusit Kaewprajak ◽  
Pisist Kumnorkaew ◽  
Khathawut Lohawet ◽  
Binh Duong ◽  
Teantong Chonsut ◽  
...  
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Blade Coating

Stable Perovskite Solar Cells Using Molecularly Engineered Functionalized Oligothiophenes as Low‐Cost Hole‐Transporting Materials

Small ◽  
2021 ◽  
pp. 2100783
Author(s):  
Vellaichamy Joseph ◽  
Albertus Adrian Sutanto ◽  
Cansu Igci ◽  
Olga A. Syzgantseva ◽  
Vygintas Jankauskas ◽  
...  
Keyword(s):  
Solar Cells ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Hole Transporting ◽  
Hole Transporting Materials

scholarly journals Room-Temperature Solution-Processed 0D/1D Bilayer Electrodes for Translucent CsPbBr3 Perovskite Photovoltaics

Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1489
Author(s):  
Bhaskar Parida ◽  
Saemon Yoon ◽  
Dong-Won Kang
Keyword(s):  
Solar Cells ◽  
Indium Tin Oxide ◽  
High Performance ◽  
Room Temperature ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Ambient Air ◽  
Plasma Damage ◽  
Temperature Solution ◽  
Ito Nanoparticles

Materials and processing of transparent electrodes (TEs) are key factors to creating high-performance translucent perovskite solar cells. To date, sputtered indium tin oxide (ITO) has been a general option for a rear TE of translucent solar cells. However, it requires a rather high cost due to vacuum process and also typically causes plasma damage to the underlying layer. Therefore, we introduced TE based on ITO nanoparticles (ITO-NPs) by solution processing in ambient air without any heat treatment. As it reveals insufficient conductivity, Ag nanowires (Ag-NWs) are additionally coated. The ITO-NPs/Ag-NW (0D/1D) bilayer TE exhibits a better figure of merit than sputtered ITO. After constructing CsPbBr3 perovskite solar cells, the device with 0D/1D TE offers similar average visible transmission with the cells with sputtered ITO. More interestingly, the power conversion efficiency of 0D/1D TE device was 5.64%, which outperforms the cell (4.14%) made with sputtered-ITO. These impressive findings could open up a new pathway for the development of low-cost, translucent solar cells with quick processing under ambient air at room temperature.

scholarly journals Low-temperature-processed metal oxide electron transport layers for efficient planar perovskite solar cells

Rare Metals ◽  
2021 ◽  
Author(s):  
Jia-Xing Song ◽  
Xin-Xing Yin ◽  
Zai-Fang Li ◽  
Yao-Wen Li
Keyword(s):  
Solar Cells ◽  
Electron Transport ◽  
Low Temperature ◽  
Metal Oxide ◽  
Low Cost ◽  
Perovskite Solar Cells ◽  
Transport Layer ◽  
Electron Transport Layer ◽  
Future Research ◽  
Low Temperature Preparation

Abstract As a promising photovoltaic technology, perovskite solar cells (pero-SCs) have developed rapidly over the past few years and the highest power conversion efficiency is beyond 25%. Nowadays, the planar structure is universally popular in pero-SCs due to the simple processing technology and low-temperature preparation. Electron transport layer (ETL) is verified to play a vital role in the device performance of planar pero-SCs. Particularly, the metal oxide (MO) ETL with low-cost, superb versatility, and excellent optoelectronic properties has been widely studied. This review mainly focuses on recent developments in the use of low-temperature-processed MO ETLs for planar pero-SCs. The optical and electronic properties of widely used MO materials of TiO2, ZnO, and SnO2, as well as the optimizations of these MO ETLs are briefly introduced. The commonly used methods for depositing MO ETLs are also discussed. Then, the applications of different MO ETLs on pero-SCs are reviewed. Finally, the challenge and future research of MO-based ETLs toward practical application of efficient planar pero-SCs are proposed. Graphical abstract

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