scholarly journals Impact of Sodium Hexametaphosphate on the Flotation of Ultrafine Magnesite from Dolomite-Rich Desliming Tailings

Minerals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 499
Author(s):  
Duong Huu Hoang ◽  
Doreen Ebert ◽  
Robert Möckel ◽  
Martin Rudolph

The depletion of ore deposits, the increasing demand for raw materials, the need to process low-grade, complex and finely disseminated ores, and the reprocessing of tailings are challenges especially for froth flotation separation technologies. Even though they are capable of handling relatively fine grain sizes, the flotation separation of very fine and ultrafine particles faces many problems still. Further, the flotation of low-contrast semi-soluble salt-type minerals with very similar surface properties, many complex interactions between minerals, reagents and dissolved species often result in poor selectivity. This study investigates the flotation beneficiation of ultrafine magnesite rich in dolomite from desliming, currently reported to the tailings. The paper especially focuses on the impact of the depressant sodium hexametaphosphate (SHMP) on the following: (i) the froth properties using dynamic froth analysis (DFA), (ii) the separation between magnesite and dolomite/calcite, and (iii) its effect on the entrainment. As a depressant/dispersant, SHMP has a beneficial impact on the flotation separation between magnesite and dolomite. However, there is a trade-off between grade and recovery, and as well as the dewatering process which needs to be considered. When the SHMP increases from 200 g/t to 700 g/t, the magnesite grade increases from 67% to 77%, while recovery decreases massively, from 80% to 40%. The open circuit with four cleaning stages obtained a concentrate assaying 77.5% magnesite at a recovery of 45.5%. The dolomite content in the concentrate is about 20%, where 80% of dolomite was removed and importantly 98% of the quartz was removed, with only 0.3% of the quartz in the final concentrate. Furthermore, the application of 1-hydroxyethylene-1,1-diphosphonic acid (HEDP) as a more environmentally friendly and low-cost alternative to SHMP is presented and discussed. Using only 350 g/t of HEDP can achieve a similar grade (76.3%), like 700 g/t of SHMP (76.9%), while obtaining a 17% higher magnesite recovery as compared to 700 g/t of SHMP. Interestingly, the proportion of hydrophilic quartz minerals ending up in the concentrate is lower for HEDP, with only 1.9% quartz at a recovery of 21.5% compared to the 2.7% of quartz at a recovery of 24.9% when using SHMP. The paper contributes in general to understanding the complexity of the depressant responses in froth flotation.

Author(s):  
Duong Huu Hoang ◽  
Doreen Ebert ◽  
Robert Möckel ◽  
Martin Rudolph

Depletion of ore deposits, increasing demand for raw materials, the need to process low-grade, complex and finely disseminated ores and the reprocessing of tailings are challenges, especially for froth flotation separation technologies. Even though capable of handling relatively fine grain sizes the flotation separation of very fine and ultrafine particles faces many problems still. Further, the flotation of low-contrast semi-soluble salt-type minerals with very similar surface properties, many complex interactions between minerals, reagents and dissolved species often result in poor selectivity. This study investigates the flotation beneficiation of ultrafine magnesite rich in dolomite from de-sliming, currently reported to the tailings. The paper especially focuses on the impact of the depressant sodium hexametaphosphate (SHMP) on: (i) the froth properties using dynamic froth analysis (DFA), (ii) the separation between magnesite and dolomite/calcite and (iii) its effect on the entrainment. Furthermore, the application of 1-hydroxyethylene-1,1-diphosphonic acid (HEDP) is a more environmentally friendly and low-cost alternative to SHMP is presented and discussed. The paper contributes to understanding on the complexity of depressant responses in froth flotation.


2019 ◽  
Vol 959 ◽  
pp. 125-133 ◽  
Author(s):  
Kerstin Eckert ◽  
Edgar Schach ◽  
Gunter Gerbeth ◽  
Martin Rudolph

Critical raw materials (CRMs) are of primary importance for energy storage systems as needed for electromobility. Many mineral deposits which contain CRMs are low-grade ores. To liberate the CRMs, a grinding of the mineral ores to very fine sizes below 20 µm particle size is necessary. However, the present class of industrial flotation plants fail to extract such fine and ultrafine particles. To improve the recovery in fine particle flotation, techniques have been developed which attempt to agglomerate the fine valuable particles into larger aggregates which subsequently can be separated by established technologies such as froth flotation. Carrier flotation is one of these techniques. The present work reviews the state of the art of this technique for the recovery of fines and ultrafines.


2020 ◽  
Vol 2020 (3) ◽  
pp. 24-31
Author(s):  
Z Galimova ◽  
◽  
H Babakhanova ◽  
M Abdunazarov ◽  
I Ismoilov ◽  
...  

Both raw and recycled fiber materials are used for paper production. The increase in percentage use of the latter is due to their paper-forming properties, availability and low cost. The article explores the possibility of using pulp from the inner layer of mulberry twig bark. Mulberry twigs, after removing leaves, which are the main raw material in silk production, have no practical industrial application. Recycling waste - mulberry branches - for the production of pulp is therefore relevant as it is aimed at solving raw material and environmental problems. The purpose of this work is to use local raw materials for paper production, study the impact of processing method of the grinding process on paper forming properties. During grinding the mechanical processes of changes of fibers determine mainly structure of a paper sheet, and colloidal-physical processes - bind and ability of fibers to form strong, homogenous and smooth structure of paper. The structure of the sheet of paper facilitates excessive or "selective" ink absorption into the pores of the paper and thus predetermines the quality of reproduction during the printing process. Methods for determining the physical and mechanical properties of papers were used in this work, and changes in the surface structure of samples cast at various technological modes of the milling process were studied. The results of the study revealed that the addition of cellulose mass from the inner layer of mulberry twig bark helps to obtain a strong paper. The optical properties of the paper, which contains cotton and cellulose from the inner layer of mulberry branch bark, are explained by the whiteness of the added fibers themselves. The strength properties of the paper at a weight grinding degree of 300 CWR are explained by the bond between the split and strongly interwoven fibers of the cellulose fibers. It has been established that the addition of more than 30% cellulose from the inner layer of the mulberry branch bark to the paper pulp mass is undesirable, as this adversely affects the whiteness of the paper


Minerals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 207 ◽  
Author(s):  
Petros Petrounias ◽  
Aikaterini Rogkala ◽  
Panagiota Giannakopoulou ◽  
Basilios Tsikouras ◽  
Paraskevi Lampropoulou ◽  
...  

This paper investigates an alternative use of sterile aggregate materials which may arise from various construction applications in conjunction with other low-cost mineral raw materials to remediate the acid mine drainage phenomenon. This study is based on the combination of unprocessed mineral raw materials, as well as on the basic concept of the cyclic economy where the conversion of a waste into a raw material for another application can be achieved. In this study, in order to examine the remediation, in lab scale, of the drainage waste water of Agios Philippos mine, an experimental electrically continuous flow-driven forced device was constructed, enriching the research gap relative to this type of remediation approach. Through this experimental device, the use of certain mixes of mineral raw materials (serpentinite, andesite, magnesite, peat, and biochar) was studied. Our results focus on the impact of the studied mineral raw materials and especially on their synergy on the water purification potential under continuous water flow operation. Using the new 7-day experimental electrically continuous flow-driven forced device with certain mixes of mineral raw materials, the increase of pH values from 3.00 to 6.82 was achieved. Moreover, with use of the experimental device, the removal of toxic load was achieved, and more specifically the concentration of Fe was decreased from 6149 to 1300 ppb, Cu from 8847 to 35 ppb, and Zn from 285,458 to 50,000 ppb.


2010 ◽  
Vol 177 ◽  
pp. 342-345 ◽  
Author(s):  
Zhan Peng Zhang ◽  
Cheng Zhang ◽  
De Xing Huang ◽  
Dan Yu Jiang ◽  
Rong Juan Zhang ◽  
...  

Magnesium oxide is one of the most important raw materials in the refractory industry due to its high melting point (2800oC), corrosion resistance in the basic environment, and low cost. Nevertheless, magnesium oxide reacts easily with water to produce magnesium hydrate, which is followed by a large volumetric expansion, limiting its application in refractory industry. As the hydration of MgO is very important either in theory or in industrial production of magnesium, in this paper, the influence of temperature, residence time, as well as the impact of the solid content on MgO hydration and the kinetics of hydration reaction was evaluated to optimize the determination method of magnesium oxide hydration in refractory industry.


Author(s):  
Petros Petrounias ◽  
Aikaterini Rogkala ◽  
Panagiota P. Giannakopoulou ◽  
Basilios Tsikouras ◽  
Paraskevi Lampropoulou ◽  
...  

This paper investigates an alternative use of sterile aggregate materials which may arise from various construction applications in conjunction with other low-cost mineral raw materials to remediate the acid mine drainage phenomenon. This study is based on the combination of unprocessed mineral raw materials as well as on the basic concept of the cyclic economy where the conversion of a waste into a raw material for another application can be achieved. In this way, the value of mineral raw materials can be prolonged for as long as possible, waste generation and exploitation of natural resources are minimized and resources are kept as far as possible within the existing economy. In this study, an electrically continuous flow driven forced device proposed and demonstrated for the remediation of waste water in lab-scale by using certain mixes of mineral raw materials (serpentinite, andesite, magnesite, peat and biochar). Our results focus on the impact of the studied mineral raw materials and especially on their synergy on the water purification potential under continuous water flow operation. Using the proposed 7-day experimental electrically continuous flow driven forced device with the certain mixes of mineral raw materials, the increase of pH values from 3.00 to 6.82 as well as significant removal of Fe, Cu and Zn was achieved.


Author(s):  
O. Ya. Faflei ◽  
R. O. Deynega ◽  
V. V. Mykhailiuk ◽  
A. V. Semenchuk ◽  
B. I. Zvir

The process of the oil field operation at the late stage is characterized by a significant content of mechanical impurities in the extracted raw materials and a high rate of water encroachment. Water encroachment plays a sig-nificant role in the processes of formation sand carry-over and the destruction of incompetent rocks of productive horizons in deposits. Today, to intensify the drainage of formation fluid from production wells, it is necessary to increase the depth of descent and to use more productive pumps. However, this leads to the growth of the draw down pressure and, as a rule, to more intensive sloughing of mechanical impurities out of the reservoir. First of all, the sand taken out of the formation is a highly abrasive agent, which causes the wear not only of the pump elements, but also of the tubings, valves, throttles, etc. Predicting the impact of mechanical impurities on the ele-ments of the pumping equipment for oil production is a complex task that requires consideration of many different factors. The sand which is carried out of wells is accumulated in the pipelines. Besides, it is accumulated in meas-uring units, separators, valves and other parts of group metering and pumping units. Process tanks and reservoirs at oil or condensate treatment plants are clogged with sand. To combat sloughing of sand, in most cases the meth-od of filtration is used. This method is not the most effective, but it is reliable, low cost, and environmentally friendly. Several constructions of downhole filters are analyzed. To evaluate the efficiency of the downhole filter, its research is carried out using simulation modeling. The dependence of the number of sloughed particles on their diameter is established in accordance with the hydrodynamic processes and characteristics of the working envi-ronment.


2017 ◽  
Vol 262 ◽  
pp. 307-310
Author(s):  
Susan Reichel ◽  
Mirko Martin ◽  
Christopher G. Bryan ◽  
Cristina Vila ◽  
António Fiúza ◽  
...  

The FAME (Flexible and Mobile Economic Processing Technologies) project targets the development of flexible and economic processing technologies for small and low-grade European ore deposits with complex mineralogy, targeting greisen, skarn and pegmatite ores. Amongst the valuable elements to be recovered are W, Sn, Li and minor constituents like In, Ge, Ga, Nb or Ta. To improve the processing of by-product sulfides to recover critical elements like In or Ga and to develop innovative processing strategies for raw materials, biohydrometallurgical technologies are investigated. There are different approaches in FAME for the biohydrometallurgical recovery of valuable metals from low grade ores: 1) the extraction of Li from zinnwaldite and lepidolite, 2) the heap leaching of low grade sulfide ore unsuitable for conventional processing to recover Zn and In, and 3) the bioleaching of sulfide concentrates in a two-stage tank process for recovery of Zn and Cu. So far the most promising results were achieved for heap-leaching of low-grade Zn-In ores achieving 7.4 ppm In in the leaching solution and for Li extraction (28%) from zinnwaldite.


2019 ◽  
Vol 123 ◽  
pp. 01031
Author(s):  
Stanislav Stovpnyk ◽  
Kostiantyn Tkachuk ◽  
Oleksandr Temchenko

The article deals with the problematic issues and features of further development of iron ore deposits at great depths (over 400 m). The necessity of wide application of innovative competitive technologies for ore mining by open method and an increase in the efficiency of mineral processing in the conditions of modern trends of sustainable development is substantiated. To solve this problem, a systematic approach is applied based on the consideration of all technological processes, taking into account the impact of mining operations on the environment as a single organizational and technological complex. It is proposed to use the Neumann-Gale model as an economic and mathematical model for assessing the investment activity of mining enterprises, which takes into account the influence of the environmental factor on the efficiency of their functioning. Approbation of the model was performed at the PJSC “Southern Mining Factory” as an example of production and economic activity. The priority measures are presented for the implementation of ecologically balanced strategies in terms of environmental protection for sustainable development at modern mining enterprises in difficult economic conditions and uncertainty of price characteristics in the markets of iron ore raw materials.


2019 ◽  
Vol 276 ◽  
pp. 01017 ◽  
Author(s):  
Usman Wijaya ◽  
Roesdiman Soegiarso ◽  
Tavio

Most parts of Indonesia are located at high-risk seismic regions. Therefore, it is necessary to seriously consider earthquake in designing the seismic-resistant buildings. One of the most effective methods to reduce the impact of the earthquake force is to introduce the use of the elastomeric rubber base isolation as an effective earthquake damper. Indonesia as a tropical country has many sources of raw materials particularly rubber. This can be potential as a main basic need for producing an optimum elastomeric rubber base isolation system. This paper determined an approach method of constitutive low-grade rubber to get the best fitting with experimental data. Five deformation models such as Mooney-Rivlin, Ogden, Arruda-Boyce, Neo-Hookean, Yeoh models compare to uniaxial test were adopted to simulate the characteristics of rubber materials used in base isolation. From the analysis, it can be concluded that Yeoh model give the best fitting and the most accurate to the test data even in limited test data.


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