scholarly journals Iron Isotopes Reveal a Benthic Iron Shuttle in the Palaeoproterozoic Zaonega Formation: Basinal Restriction, Euxinia, and the Effect on Global Palaeoredox Proxies

Minerals ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 368
Author(s):  
Kaarel Mänd ◽  
Stefan V. Lalonde ◽  
Kärt Paiste ◽  
Marie Thoby ◽  
Kaarel Lumiste ◽  
...  
Keyword(s):  
Trace Metal ◽  
Trace Element ◽  
Deep Water ◽  
Water Exchange ◽  
Global Ocean ◽  
Geochemical Data ◽  
Iron Isotopes ◽  
Metal Enrichment ◽  
Great Oxidation Event ◽  
Redox Dynamics

The Zaonega Formation in northwest Russia (~2.0 billion years old) is amongst the most complete successions that record the middle of the Palaeoproterozoic era. As such, geochemical data from the formation have played a central role in framing the debate over redox dynamics in the aftermath of the Great Oxidation Event (GOE). However, uncertainty over local redox conditions and the degree of hydrographic restriction in the formation has led to contradictory interpretations regarding global oxygen (O2) fugacity. Here, we provide new iron (Fe) isotope data together with major and trace element concentrations to constrain the local physiochemical conditions. The Zaonega Formation sediments show authigenic Fe accumulation (Fe/Al ≫ 1 wt.%/wt.%) and δ56Fe ranging from −0.58‰ to +0.60‰. Many of the data fall on a negative Fe/Al versus δ56Fe trend, diagnostic of a benthic Fe shuttle, which implies that Zaonega Formation rocks formed in a redox-stratified and semi-restricted basin. However, basin restriction did not coincide with diminished trace metal enrichment, likely due to episodes of deep-water exchange with metal-rich oxygenated seawater, as evidenced by simultaneous authigenic Fe(III) precipitation. If so, the Onega Basin maintained a connection that allowed its sediments to record signals of global ocean chemistry despite significant basinal effects.

Lithospheric roots beneath western Laurentia: the geochemical signal in mantle garnets

2003 ◽  
Vol 40 (8) ◽  
pp. 1027-1051 ◽  
Author(s):  
D Canil ◽  
D J Schulze ◽  
D Hall ◽  
B C Hearn Jr. ◽  
S M Milliken
Keyword(s):  
Rare Earth ◽  
North America ◽  
Trace Element ◽  
Earth Element ◽  
Geochemical Data ◽  
Trace Element Data ◽  
Mantle Lithosphere ◽  
Western North America ◽  
Wyoming Province ◽  
Thick Mantle

This study presents major and trace element data for 243 mantle garnet xenocrysts from six kimberlites in parts of western North America. The geochemical data for the garnet xenocrysts are used to infer the composition, thickness, and tectonothermal affinity of the mantle lithosphere beneath western Laurentia at the time of kimberlite eruption. The garnets record temperatures between 800 and 1450°C using Ni-in-garnet thermometry and represent mainly lherzolitic mantle lithosphere sampled over an interval from about 110–260 km depth. Garnets with sinuous rare-earth element patterns, high Sr, and high Sc/V occur mainly at shallow depths and occur almost exclusively in kimberlites interpreted to have sampled Archean mantle lithosphere beneath the Wyoming Province in Laurentia, and are notably absent in garnets from kimberlites erupting through the Proterozoic Yavapai Mazatzal and Trans-Hudson provinces. The similarities in depths of equilibration, but differing geochemical patterns in garnets from the Cross kimberlite (southeastern British Columbia) compared to kimberlites in the Wyoming Province argue for post-Archean replacement and (or) modification of mantle beneath the Archean Hearne Province. Convective removal of mantle lithosphere beneath the Archean Hearne Province in a "tectonic vise" during the Proterozoic terminal collisions that formed Laurentia either did not occur, or was followed by replacement of thick mantle lithosphere that was sampled by kimberlite in the Triassic, and is still observed there seismically today.

scholarly journals Major-oxide and trace-element geochemical data from rocks collected in the Tok River area, Tanacross A-5 and A-6 quadrangles, Alaska in 2016

2016 ◽  
Author(s):  
Alicja Wypych ◽  
K. R. Sicard ◽  
R. J. Gillis ◽  
L. L. Lande ◽  
T. J. Naibert ◽  
...  
Keyword(s):  
Trace Element ◽  
Geochemical Data ◽  
Major Oxide

A new record of the Toarcian oceanic anoxic event from Scotland (UK) and environmental responses

2021 ◽  
Author(s):  
Wenhan Chen ◽  
David Bryan Kemp ◽  
Tianchen He ◽  
Chunju Huang
Keyword(s):  
Chemical Weathering ◽  
Coarse Grained ◽  
Global Ocean ◽  
Geochemical Data ◽  
Oceanic Anoxic Event ◽  
Organic Carbon Isotope ◽  
Anoxic Event ◽  
Geographic Differences ◽  
Environmental Responses ◽  
Global Carbon

<p>The early Toarcian oceanic anoxic event (T-OAE, ~183 Ma) was characterized by a prominent environmental perturbation, likely associated with a large amount of <sup>12</sup>C-enriched carbon released into the global ocean-atmosphere system. This effusion caused a marked disruption to the global carbon cycle and propagated a series of remarkable changes in ocean chemistry and climate. Although the T-OAE has been recognized worldwide, clear geographic differences in the character of the event and its environmental effects have been recognized. Here, we present new geochemical data from a lower Toarcian succession on the Isle of Raasay, NE Scotland (Hebrides Basin, Northwest European Shelf). Organic carbon isotope data through the Raasay section reveal a pronounced negative excursion, similar to that recognised globally. The excursion interval is enriched in organic matter, and redox sensitive element data suggest that suboxic bottom water conditions contemporaneously occurred, likely interspersed with anoxic episodes. Our findings contrast with evidence of more pervasive anoxia/euxinia in nearby basins, and emphasize how deoxygenation was spatially variable within the T-OAE. Inorganic geochemical data and sedimentological observations suggest a significant enhancement in chemical weathering and coarse-grained detrital flux during the T-OAE on Raasay. These findings support evidence from other localities for a strengthening of hydrological cycling in response to global warming during the T-OAE.</p>

scholarly journals The global ocean circulation on a retrograde rotating earth

2011 ◽  
Vol 7 (2) ◽  
pp. 487-499 ◽  
Author(s):  
V. Kamphuis ◽  
S. E. Huisman ◽  
H. A. Dijkstra
Keyword(s):  
Ocean Circulation ◽  
Deep Water ◽  
North Pacific ◽  
Global Ocean ◽  
Freshwater Flux ◽  
Deep Water Formation ◽  
The North ◽  
Water Formation ◽  
Global Ocean Circulation ◽  
The North Pacific

Abstract. To understand the three-dimensional ocean circulation patterns that have occurred in past continental geometries, it is crucial to study the role of the present-day continental geometry and surface (wind stress and buoyancy) forcing on the present-day global ocean circulation. This circulation, often referred to as the Conveyor state, is characterised by an Atlantic Meridional Overturning Circulation (MOC) with a deep water formation at northern latitudes and the absence of such a deep water formation in the North Pacific. This MOC asymmetry is often attributed to the difference in surface freshwater flux: the Atlantic as a whole is a basin with net evaporation, while the Pacific receives net precipitation. This issue is revisited in this paper by considering the global ocean circulation on a retrograde rotating earth, computing an equilibrium state of the coupled atmosphere-ocean-land surface-sea ice model CCSM3. The Atlantic-Pacific asymmetry in surface freshwater flux is indeed reversed, but the ocean circulation pattern is not an Inverse Conveyor state (with deep water formation in the North Pacific) as there is relatively weak but intermittently strong deep water formation in the North Atlantic. Using a fully-implicit, global ocean-only model the stability properties of the Atlantic MOC on a retrograde rotating earth are also investigated, showing a similar regime of multiple equilibria as in the present-day case. These results indicate that the present-day asymmetry in surface freshwater flux is not the most important factor setting the Atlantic-Pacific salinity difference and, thereby, the asymmetry in the global MOC.

scholarly journals Middle Holocene expansion of Pacific Deep Water into the Southern Ocean

2019 ◽  
Vol 117 (2) ◽  
pp. 889-894
Author(s):  
Torben Struve ◽  
David J. Wilson ◽  
Tina van de Flierdt ◽  
Naomi Pratt ◽  
Kirsty C. Crocket
Keyword(s):  
Southern Ocean ◽  
Ocean Circulation ◽  
Deep Water ◽  
Water Masses ◽  
Ocean Dynamics ◽  
Global Ocean ◽  
Circulation System ◽  
The Holocene ◽  
Middle Holocene ◽  
Deep Mixing

The Southern Ocean is a key region for the overturning and mixing of water masses within the global ocean circulation system. Because Southern Ocean dynamics are influenced by the Southern Hemisphere westerly winds (SWW), changes in the westerly wind forcing could significantly affect the circulation and mixing of water masses in this important location. While changes in SWW forcing during the Holocene (i.e., the last ∼11,700 y) have been documented, evidence of the oceanic response to these changes is equivocal. Here we use the neodymium (Nd) isotopic composition of absolute-dated cold-water coral skeletons to show that there have been distinct changes in the chemistry of the Southern Ocean water column during the Holocene. Our results reveal a pronounced Middle Holocene excursion (peaking ∼7,000–6,000 y before present), at the depth level presently occupied by Upper Circumpolar Deep Water (UCDW), toward Nd isotope values more typical of Pacific waters. We suggest that poleward-reduced SWW forcing during the Middle Holocene led to both reduced Southern Ocean deep mixing and enhanced influx of Pacific Deep Water into UCDW, inducing a water mass structure that was significantly different from today. Poleward SWW intensification during the Late Holocene could then have reinforced deep mixing along and across density surfaces, thus enhancing the release of accumulated CO2 to the atmosphere.

Geochemical contrasts between late Caledonian granitoid plutons of northern, central and southern Scotland

1984 ◽  
Vol 75 (2) ◽  
pp. 259-273 ◽  
Author(s):  
W. E. Stephens ◽  
A. N. Halliday
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Incompatible Element ◽  
Geochemical Data ◽  
Wide Sense ◽  
Trace Element Data ◽  
Isotopic Data ◽  
Element Data ◽  
High K ◽  
Mantle Component

ABSTRACTNew major- and trace-element data for granitoid plutons from the Grampian Highlands, the Midland Valley and the Southern Uplands of Scotland are presented and discussed. The study is restricted to ‘late granitoids’ (all younger than 430 Ma); the term ‘granitoid’ is used in a wide sense to encompass all plutonic components of a zoned intrusion of this age, sometimes including diorites and ultrabasic cumulate rocks. The data indicate that as a whole the province is chemically high-K calc-alkalic. Other notable enrichments are in Sr and Ba, and a marked geographical difference in these trace-elements is found between plutons of the SW Grampian Highlands and those of the Southern Highlands, the Midland Valley, and the Southern Uplands. Plutons of the NE Highlands tend to be more geochemically evolved than those further SW and those of the Midland Valley and Southern Uplands.When petrographical and geochemical data are considered, three plutonic suites are recognised: (1) the Cairngorm suite comprising plutons of the NE Highlands, (2) the Argyll suite comprising plutons from the SW Highlands, and (3) the S of Scotland suite comprising plutons from the Southern Highlands, Midland Valley and the Southern Uplands excluding Criffell and the Cairnsmore of Fleet. It is proposed that the more acidic granitoids are dominantly the products of I-type crustal sources, but certain diorites and the more basic members of zoned plutons have a substantial mantle component. The elevated Sr and Ba levels in granitoids of the Argyll suite may reflect the influence of incompatible-element-rich fluids from the mantle in the petrogenesis of this suite. The relatively anhydrous pyroxene-mica diorites of the S of Scotland suite are richer in Ni and Cr and appear to represent mantle-derived melts. The relationships between these data and already published isotopic data are discussed.

scholarly journals Reconstruction of east–west deep water exchange in the low latitude Atlantic Ocean over the past 25,000 years

2017 ◽  
Vol 458 ◽  
pp. 327-336 ◽  
Author(s):  
Jacob N.W. Howe ◽  
Alexander M. Piotrowski ◽  
Rong Hu ◽  
Aloys Bory
Keyword(s):  
Atlantic Ocean ◽  
Deep Water ◽  
Water Exchange ◽  
Low Latitude ◽  
The Past ◽  
East West

An Assessment of Global Ocean Barotropic Tide Models Using Geodetic Mission Altimetry and Surface Drifters

2021 ◽  
Vol 51 (1) ◽  
pp. 63-82
Author(s):  
Edward D. Zaron ◽  
Shane Elipot
Keyword(s):  
Shallow Water ◽  
Deep Water ◽  
Variance Reduction ◽  
Model Performance ◽  
Data Sources ◽  
Global Ocean ◽  
Ocean Tide ◽  
Analysis Model ◽  
Surface Drifters ◽  
Ocean Tide Models

AbstractThe accuracy of three data-constrained barotropic ocean tide models is assessed by comparison with data from geodetic mission altimetry and ocean surface drifters, data sources chosen for their independence from the observational data used to develop the tide models. Because these data sources do not provide conventional time series at single locations suitable for harmonic analysis, model performance is evaluated using variance reduction statistics. The results distinguish between shallow and deep-water evaluations of the GOT410, TPXO9A, and FES2014 models; however, a hallmark of the comparisons is strong geographic variability that is not well summarized by global performance statistics. The models exhibit significant regionally coherent differences in performance that should be considered when choosing a model for a particular application. Quantitatively, the differences in explained SSH variance between the models in shallow water are only 1%–2% of the root-mean-square (RMS) tidal signal of about 50 cm, but the differences are larger at high latitudes, more than 10% of 30-cm RMS. Differences with respect to tidal currents variance are strongly influenced by small scales in shallow water and are not well represented by global averages; therefore, maps of model differences are provided. In deep water, the performance of the models is practically indistinguishable from one another using the present data. The foregoing statements apply to the eight dominant astronomical tides M2, S2, N2, K2, K1, O1, P1, and Q1. Variance reduction statistics for smaller tides are generally not accurate enough to differentiate the models’ performance.

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