Mono- and Dinitro-BN-Naphthalenes: Formation and Characterization
Mono- and dinitro-BN-naphthalenes, i.e., 1-nitro-, 3-nitro-, 1,6-dinitro-, 3,6-dinitro-, and 1,8-dinitro-BNN, were generated in the nitration of 9,10-BN-naphthalene (BNN), a boron–nitrogen (BN) bond-embedded naphthalene, with AcONO2 and NO2BF4 in acetonitrile. The nitrated products were isolated and characterized by NMR, GC-MS, IR, and X-ray single crystallography. The effects of the nitration on the electron density and aromaticity of BNN were evaluated by B-11 NMR analysis and HOMA calculations.
1989 ◽
Vol 47
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pp. 30-31
1992 ◽
Vol 25
(2)
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pp. 205-210
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2006 ◽
Vol 47
(3)
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pp. 558-562
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1991 ◽
Vol 251
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pp. 11-27
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2017 ◽
Vol 73
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pp. 1-9
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