scholarly journals Novel Conjugated s-Tetrazine Derivatives Bearing a 4H-1,2,4-Triazole Scaffold: Synthesis and Luminescent Properties

Molecules ◽  
2022 ◽  
Vol 27 (2) ◽  
pp. 459
Author(s):  
Anna Maj ◽  
Agnieszka Kudelko ◽  
Marcin Świątkowski
Keyword(s):  
Quantum Yield ◽  
Fluorescence Emission ◽  
Triazole Ring ◽  
Coupled System ◽  
Luminescent Properties ◽  
Membered Ring ◽  
Spectroscopic Methods ◽  
Strong Fluorescence ◽  
Potential Applications ◽  
The Individual

A series of new symmetrical s-tetrazine derivatives, coupled via a 1,4-phenylene linkage with a 4H-1,2,4-triazole ring, were obtained. The combination of these two rings in an extensively coupled system has significant potential applications, mainly in optoelectronics. The methodology used turned out to be useful regardless of the type of five-membered ring or the nature of the individual substituents. All the products were identified by spectroscopic methods, and the target compounds were tested for luminescent properties. This study showed that all the synthesized highly-conjugated triazoles exhibited luminescence; in particular, one derivative, 3,6-bis(4-(5-(4-methoxyphenyl)-4-phenyl-4H-1,2,4-triazol-3-yl)phenyl)-1,2,4,5-tetrazine (13b), showed strong fluorescence emission and ahigh quantum yield close to 1.

scholarly journals Chiroptical property enhancement of chiral Eu(III) complex upon association with DNA-CTMA

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Haruki Minami ◽  
Natsumi Itamoto ◽  
Wataru Watanabe ◽  
Ziying Li ◽  
Kazuki Nakamura ◽  
...  
Keyword(s):  
Structural Change ◽  
Quantum Yield ◽  
Functional Properties ◽  
Photophysical Properties ◽  
Luminescent Properties ◽  
Dna Molecule ◽  
Emission Enhancement ◽  
Chiroptical Property ◽  
Potential Applications ◽  
Sensitization Efficiency

Abstract DNA-based materials have attracted much attention due to their unique photo-functional properties and potential applications in various fields such as luminescent and biological systems, nanodevices, etc. In this study, the photophysical properties of a chiral Eu(III) complex, namely (Eu(D-facam)3), within DNA films were extensively investigated. The enhancement of photoluminescence (more than 25-folds increase of luminescence quantum yield) and degree of circularly polarization in luminescence (glum = − 0.6) was observed upon interaction with DNA. Various photophysical analyses suggested that the emission enhancement was mainly due to an increase of the sensitization efficiency (high ηsens) from the ligands to Eu(III) and suppression of the vibrational deactivation upon immobilization onto the DNA molecule. From CD and VCD measurements, it was suggested that the coordination structure of Eu(D-facam)3 was affected by the interaction with DNA, suggesting that the structural change of Eu(D-facam)3 contributed to the improvement of its luminescent properties.

Spermine-directed supramolecular self-assembly of water-soluble AIE-active tetraphenylethylene: nanobelt, nanosheet, globular and nanotubular structures

2018 ◽  
Vol 42 (18) ◽  
pp. 15379-15386 ◽  
Author(s):  
Duong Duc La ◽  
Jotiram N. Malegaonkar ◽  
Mohammad Al Kobaisi ◽  
Rajesh S. Bhosale ◽  
Sidhanath V. Bhosale ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Self Assembly ◽  
Fluorescence Emission ◽  
Water Soluble ◽  
Strong Fluorescence

Tetrasulfonate-tetraphenylethylene (Su-TPE) is non-emissive in water and upon addition of a good solvent such as THF (fTHF = 95%) it displays strong fluorescence emission with a quantum yield of 6.33%.

Towards a New Approach to Cross-Cultural Distinctiveness and Typicality of Human Faces: The Cross-Group Typicality/Distinctiveness Metric

2018 ◽  
Author(s):  
Karel Kleisner ◽  
Šimon Pokorný ◽  
Selahattin Adil Saribay
Keyword(s):  
Cross Cultural ◽  
Facial Appearance ◽  
Alternative Measure ◽  
Home Culture ◽  
Facial Stimuli ◽  
The Two Cultures ◽  
Potential Applications ◽  
The Individual ◽  
Human Faces ◽  
Ingroup Outgroup

In present research, we took advantage of geometric morphometrics to propose a data-driven method for estimating the individual degree of facial typicality/distinctiveness for cross-cultural (and other cross-group) comparisons. Looking like a stranger in one’s home culture may be somewhat stressful. The same facial appearance, however, might become advantageous within an outgroup population. To address this fit between facial appearance and cultural setting, we propose a simple measure of distinctiveness/typicality based on position of an individual along the axis connecting the facial averages of two populations under comparison. The more distant a face is from its ingroup population mean towards the outgroup mean the more distinct it is (vis-à-vis the ingroup) and the more it resembles the outgroup standards. We compared this new measure with an alternative measure based on distance from outgroup mean. The new measure showed stronger association with rated facial distinctiveness than distance from outgroup mean. Subsequently, we manipulated facial stimuli to reflect different levels of ingroup-outgroup distinctiveness and tested them in one of the target cultures. Perceivers were able to successfully distinguish outgroup from ingroup faces in a two-alternative forced-choice task. There was also some evidence that this task was harder when the two faces were closer along the axis connecting the facial averages from the two cultures. Future directions and potential applications of our proposed approach are discussed.

GENERALIZED SYNCHRONIZATION, FREQUENCY-LOCKING AND PHASE-LOCKING OF COUPLED SINE CIRCLE MAPS

2001 ◽  
Vol 11 (08) ◽  
pp. 2245-2253
Author(s):  
WEN-XIN QIN
Keyword(s):  
Dynamical Systems ◽  
Invariant Manifold ◽  
Coupling Strength ◽  
Phase Locking ◽  
Coupled System ◽  
Generalized Synchronization ◽  
Frequency Locking ◽  
Local Systems ◽  
Circle Maps ◽  
The Individual

Applying invariant manifold theorem, we study the existence of generalized synchronization of a coupled system, with local systems being different sine circle maps. We specify a range of parameters for which the coupled system achieves generalized synchronization. We also investigate the relation between generalized synchronization, predictability and equivalence of dynamical systems. If the parameters are restricted in the specified range, then all the subsystems are topologically equivalent, and each subsystem is predictable from any other subsystem. Moreover, these subsystems are frequency locked even if the frequencies are greatly different in the absence of coupling. If the local systems are identical without coupling, then the widths of the phase-locked intervals of the coupled system are the same as those of the individual map and are independent of the coupling strength.

Calculation of Component Mode Synthesis Matrices From Measured Frequency Response Functions, Part 2: Application

1998 ◽  
Vol 120 (2) ◽  
pp. 509-516 ◽  
Author(s):  
J. A. Morgan ◽  
C. Pierre ◽  
G. M. Hulbert
Keyword(s):  
Frequency Response ◽  
Coupled System ◽  
Companion Paper ◽  
Component Mode Synthesis ◽  
Response Functions ◽  
Frequency Response Functions ◽  
Measured Frequency ◽  
Measured Frequency Response ◽  
Coupled Beams ◽  
The Individual

This paper demonstrates how to calculate Craig-Bampton component mode synthesis matrices from measured frequency response functions. The procedure is based on a modified residual flexibility method, from which the Craig-Bampton CMS matrices are recovered, as presented in the companion paper, Part I (Morgan et al., 1998). A system of two coupled beams is analyzed using the experimentally-based method. The individual beams’ CMS matrices are calculated from measured frequency response functions. Then, the two beams are analytically coupled together using the test-derived matrices. Good agreement is obtained between the coupled system and the measured results.

Circularly polarized luminescence from oriented polymer films doped with a tetraphenylethylene-based conjugated oligomer

2021 ◽  
Author(s):  
Wan Zhang ◽  
Baining Ni ◽  
Hongkun Li ◽  
Yonggang Yang ◽  
Yongfang Li ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Polymer Films ◽  
High Quantum Yield ◽  
Oriented Polymer ◽  
Active Materials ◽  
Circularly Polarized ◽  
Circularly Polarized Luminescence ◽  
Polarized Luminescence ◽  
Potential Applications ◽  
Wide Potential

Circularly polarized luminescence (CPL) materials have attracted increasing interest due to their wide potential applications. However, achieving CPL-active materials with both large dissymmetry factor (glum) and high quantum yield (F)...

A new twofold interpenetrated two-dimensional cadmium(II) coordination polymer constructed from 2,2′-(benzene-1,4-dicarboxamido)dipropionate

2018 ◽  
Vol 74 (11) ◽  
pp. 1434-1439
Author(s):  
Hong-Tao Zhang ◽  
Xiao-Long Wang
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Fluorescence Emission ◽  
Functional Materials ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Carboxylate Groups ◽  
Potential Applications

In recent years, much initial interest and enthusiasm has focused on the self-assembly of coordination polymers due to the aesthetics of their crystalline architectures and their potential applications as new functional materials. As part of an exploration of chiral coordination polymers, a new twofold interpenetrated two-dimensional (2D) coordination polymer, namely, poly[[tetraaquabis[μ3-(2R,2′R)-2,2′-(benzene-1,4-dicarboxamido)dipropionato-κ5 O,O′:O′′,O′′′:O′′]dicadmium(II)] trihydrate], {[Cd2(C14H14N2O6)2(H2O)4]·3H2O} n , has been synthesized by the reaction of Cd(CH3COO)2·2H2O with the designed ligand (2R,2′R)-2,2′-(benzene-1,4-dicarboxamido)dipropionic acid (H2 L). The compound has been structurally characterized by elemental analysis, IR spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction analysis. In the crystal structure, each CdII cation binds to three carboxylate groups from two crystallographically independent L 2− dianions. Four carboxylate groups link two crystallographically independent cadmium cations into a 4,4-connected secondary building unit (SBU). The resulting SBUs are extended into a two-dimensional folding sheet via the terephthalamide moiety of the ligand as a spacer, which can be simplified as a (4,4)-connected 4,4L15 net with the point symbol (3.53.62)(32.52.62). In the lattice, two independent folding sheets interpenetrate each other to yield a double-sheet layer. The resulting 2D layers pack in parallel arrays through intermolecular hydrogen bonds and interlayer π–π interactions. The thermal stability and photoluminescence properties of the title compound have been investigated and it exhibits an enhanced fluorescence emission and a longer lifetime compared with free H2 L.

scholarly journals Rapid Production of a Novel Al(III) Dependent Bioflocculant Isolated From Raoultella ornithinolytica 160-1 and Its Application Combined With Inorganic Salts

2021 ◽  
Vol 11 ◽  
Author(s):  
Rui Ding ◽  
Laipeng Luo ◽  
Ruixiang Han ◽  
Meiling Zhang ◽  
Tingting Li ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Zeta Potentials ◽  
Ph Tolerance ◽  
Flocculation Activity ◽  
Great Performance ◽  
Wide Range ◽  
Rapid Production ◽  
Potential Applications ◽  
Individual Use ◽  
The Individual

An efficient bioflocculant-producing strain, Raoultella ornithinolytica 160-1, was identified by 16S rRNA and mass spectrometry analyses. Rapid production of bioflocculant EPS-160 was obtained with 10.01 g/(L⋅d) after optimized by response surface methodology. With the aid of Al(III), more than 90% flocculation activity of EPS-160 at 8 mg/L dosage was achieved in 5 min. Thus, this novel Al(III) dependent bioflocculant was used in combined with chemical coagulants AlCl3 to remove kaolin suspensions and wastewater treatment. The results indicated that the addition of EPS-160 in aggregation system not only largely improved the flocculation ability than the individual use of chemical flocculant (over 30 percent), but also overcome the decrease of flocculation activity due to the overdose of AlCl3 and maintained the optimum dosage of AlCl3 in a wide range (11–23 mg/L). The zeta potentials and EPS-160 structure indicated that both charge neutralization and bridging were the flocculation mechanism with kaolin. During the wastewater treatment, this composite flocculants consisted of EPS-160 and AlCl3 also had great performance for turbidity elimination. Moreover, with the properties of high flocculation activity, hyperthermal stability, pH tolerance and non-toxicity, EPS-160 shows great potential applications.

scholarly journals Evaluation of anthocyanin encapsulation efficiency into yeast cell by plasmolysis, ethanol, and ultrasound treatments using alone or in combination

Food Research ◽  
2019 ◽  
Vol 4 (2) ◽  
pp. 557-562
Author(s):  
M.D. Lieu ◽  
T.T.H. Hoang ◽  
H.N.T. Nguyen ◽  
T.K.T. Dang
Keyword(s):  
Yeast Cell ◽  
Encapsulation Efficiency ◽  
Color Stability ◽  
Water Soluble ◽  
Impact Factors ◽  
Time Treatment ◽  
Treated Sample ◽  
Potential Applications ◽  
The Individual ◽  
First Time

Anthocyanin is a water-soluble color compound of the flavonoid which was successfully encapsulation in Saccharomyces cerevisiae by plasmolysis, ethanol, and ultrasound treatments using alone or in combination in the first time. Treatment agents significantly enhanced the encapsulation efficiency of anthocyanin fluid. The encapsulation yield (EY) of the combined factors was higher than the individual impact factors. Ethanol 10% (v/v) and ultrasound 180 seconds for the highest EY 40.22±0.67%, then ethanol 10% (v/v) and NaCl 10% (w/v) for EY 36.45±0.35%, NaCl 10% and ultrasound for EY 32.14±0.98% lowest. The color stability evaluation of the capsules was carried out at 80°C for 30 minutes. The color lost rate was determined by the spectrometer. The color loss of samples with the un-treatment yeast was 20.45±1.21%, higher than the treated sample. This suggests that anthocyanin encapsulation by yeast cell is efficient in overcoming the effects of high temperatures and having potential applications in food processing.

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