scholarly journals Physicochemical and Rheological Properties of a Transparent Asphalt Binder Modified with Nano-TiO2

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2152
Author(s):  
Iran Rocha Segundo ◽  
Salmon Landi ◽  
Alexandros Margaritis ◽  
Georgios Pipintakos ◽  
Elisabete Freitas ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Softening Point ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Solar Irradiation ◽  
Creep Recovery ◽  
Polymer Modification ◽  
Nano Tio2 ◽  
Rutting Resistance ◽  
Multiple Stress Creep Recovery

Transparent binder is used to substitute conventional black asphalt binder and to provide light-colored pavements, whereas nano-TiO2 has the potential to promote photocatalytic and self-cleaning properties. Together, these materials provide multifunction effects and benefits when the pavement is submitted to high solar irradiation. This paper analyzes the physicochemical and rheological properties of a transparent binder modified with 0.5%, 3.0%, 6.0%, and 10.0% nano-TiO2 and compares it to the transparent base binder and conventional and polymer modified binders (PMB) without nano-TiO2. Their penetration, softening point, dynamic viscosity, master curve, black diagram, Linear Amplitude Sweep (LAS), Multiple Stress Creep Recovery (MSCR), and Fourier Transform Infrared Spectroscopy (FTIR) were obtained. The transparent binders (base and modified) seem to be workable considering their viscosity, and exhibited values between the conventional binder and PMB with respect to rutting resistance, penetration, and softening point. They showed similar behavior to the PMB, demonstrating signs of polymer modification. The addition of TiO2 seemed to reduce fatigue life, except for the 0.5% content. Nevertheless, its addition in high contents increased the rutting resistance. The TiO2 modification seems to have little effect on the chemical functional indices. The best percentage of TiO2 was 0.5%, with respect to fatigue, and 10.0% with respect to permanent deformation.

scholarly journals Physicochemical and Rheological Properties of A Transparent Asphalt Binder Modified with Nano-TiO2

2020 ◽  
Author(s):  
Iran Rocha Segundo ◽  
Salmon Landi Jr. ◽  
Alexandros Margaritis ◽  
Georgios Pipintakos ◽  
Elisabete Freitas ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Softening Point ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Solar Irradiation ◽  
Creep Recovery ◽  
Polymer Modification ◽  
Nano Tio2 ◽  
Rutting Resistance ◽  
Multiple Stress Creep Recovery

Transparent binder is used to substitute conventional black asphalt binder and to provide light-colored pavements, whereas nano-TiO2 has the potential to promote photocatalytic and self-cleaning properties. Together, these materials provide multifunction effects and benefits when the pavement is submitted to high solar irradiation. This paper analyses the physicochemical and rheological properties of a transparent binder modified with 0.5%, 3.0%, 6.0%, and 10.0% of nano-TiO2 and compares it to the transparent base binder, and conventional and polymer modified binders (PMB) without nano-TiO2. Their penetration, softening point, dynamic viscosity, master curve, black diagram, Linear Amplitude Sweep (LAS), Multiple Stress Creep Recovery (MSCR), and Fourier-Transform Infrared Spectroscopy (FTIR) were obtained. The transparent binders (base and modified) seem to be workable considering their viscosity and exhibited values between the conventional binder and PMB regarding rutting resistance, penetration, and softening point. They showed similar behavior as the PMB, demonstrating signs of polymer-modification. The addition of TiO2 seems to reduce fatigue life, except for the 0.5% content. Nevertheless, its addition in high contents increases the rutting resistance. The TiO2 modification seems to have little effect on the chemical functional indices. The best percentage of TiO2 was 0.5%, considering fatigue and 10.0% concerning permanent deformation.

scholarly journals Physical and rheological properties of nano zinc oxide modified asphalt binder

2018 ◽  
Vol 250 ◽  
pp. 02004
Author(s):  
Khairul Nizam Mohd Yunus ◽  
Mohd Ezree Abdullah ◽  
Mohd Khairul Ahmad ◽  
Nurul Hidayah Mohd Kamaruddin ◽  
Haniffah Tami
Keyword(s):  
Zinc Oxide ◽  
Rheological Properties ◽  
Softening Point ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Zinc Nitrate ◽  
Rutting Resistance ◽  
Nano Zinc Oxide ◽  
Modified Binder ◽  
Nano Zinc

The main objectives of this work were to investigate the physical and rheological properties of nano zinc oxide (NaZO) flake structure as a modifier in asphalt binder. NaZO was produced with hydrothermal method by using two precursors, which are zinc nitrate and sodium hydroxide. NaZO was mixed with virgin binder 60/70 penetration grade at 3%, 5% and 7% of asphalt binder weight, respectively. The physical properties were evaluated by conventional testing, such as penetration, softening point and viscosity. Meanwhile, the rheological property, such as rutting resistance, was measured by using a dynamic shear rheometer (DSR) for unaged and rolling thin film oven (RTFO) aged. It was observed that the penetration value was decreased and the softening point increased with increasing NaZO concentrations. In addition, the rutting resistance factor was increased for the modified binder. A comparison between the modified binder, 7% NaZO, showed a greater resistance to rutting before and after aging. Results of this study showed that the NaZO addition had increased the asphalt binder stiffness ; thus, could contribute to better resistance to permanent deformation.

scholarly journals Evaluation of permanent deformation of asphalt rubber using multiple stress creep recovery tests and flow number tests

TRANSPORTES ◽  
2020 ◽  
Vol 28 (2) ◽  
pp. 76-86
Author(s):  
Luis Miguel Gutierrez Klinsky ◽  
Vivian Silveira dos Santos Bardini ◽  
Valeria Cristina De Faria
Keyword(s):  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Mixtures ◽  
Creep Recovery ◽  
Excellent Correlation ◽  
Flow Number ◽  
Multiple Stress ◽  
Asphalt Rubber ◽  
Modified Binders ◽  
Multiple Stress Creep Recovery

This study used the Multiple Stress Creep Recovery Test (MSCR) and the Flow number test to analyze the characteristics of asphalt rubber and its use in hot mix asphalt (HMA) regarding to their ability to withstand permanent deformation. MSCR tests were done in three commercial asphalt rubber and in the traditional asphalt binder 50/70. Flow number tests were performed in twenty four specimens of asphalt rubber mixtures and eight specimens of conventional asphalt mixtures. The results of these tests showed that all the asphalt rubber samples had lower compliance values (Jnr) in the MSCR test, which denotes that these modified binders improved the rutting resistance of HMA. This behavior was confirmed with flow number results, since the HMA produced with asphalt rubber had always higher flow number values, when compared to the conventional asphalt mixtures. The analysis of the data showed excellent correlation between Jnr values and FN values.

EMPIRICAL AND RHEOLOGICAL PROPERTIES EVALUATION OF MODIFIED ASPHALT BINDER CONTAINING NANOPOLYACRYLATE POLYMER MODIFIER

2015 ◽  
Vol 76 (9) ◽  
Author(s):  
E. Shaffie ◽  
J. Ahmad ◽  
A. K. Arshad ◽  
D. Kamarun
Keyword(s):  
Rheological Properties ◽  
Softening Point ◽  
Asphalt Binder ◽  
Pavement Performance ◽  
Polymer Modification ◽  
Modified Asphalt ◽  
Complex Shear ◽  
Modified Asphalt Binder ◽  
Modified Binder ◽  
Temperature Susceptibility

In this paper, the effects of nanopolyacrylate (NP) in binder modification on the empirical and rheological characteristics of the conventional binder were explored. The empirical and rheological binder properties were characterized using penetration, softening point, viscosity and dynamic shear rheometer (DSR) respectively.  These testings have become useful methods in characterizing of the binder performance on the pavement. The results indicated that NP polymer modification improved the physical properties of the conventional binder such as; penetration, softening point and temperature susceptibility. The results of viscosity test show that the NP polymer modified binder is more viscous than unmodified binder where viscosity increases with the increment of polymer content. The DSR results indicate that the NP polymer improves rheological properties of conventional binder, i.e. increasing the complex shear modulus (G∗) values and rutting parameters (G∗/sin δ), as well as decreasing the phase angle (δ) values. Therefore, it can be concluded that NP polymers considerably improves elastic properties and rutting resistance of binder and thus could be used for enhancing the asphalt pavement performance.

scholarly journals Characterization of asphalt binders extracted from field mixtures containing RAP and/or RAS

2022 ◽  
Vol 13 (1) ◽  
pp. 140-152
Author(s):  
Eslam Deef-Allah ◽  
Magdy Abdelrahman
Keyword(s):  
High Temperature ◽  
Rheological Properties ◽  
Asphalt Binder ◽  
Asphalt Mixtures ◽  
Asphalt Binders ◽  
Creep Recovery ◽  
Recycled Asphalt ◽  
Reclaimed Asphalt ◽  
Multiple Stress Creep Recovery ◽  
Pavement Construction

The use of reclaimed asphalt pavement (RAP) and/or recycled asphalt shingles (RAS) in the asphalt mixtures is a common practice in the U.S.A. However, there is a controversy to date on how RAP/RAS interact with virgin asphalt binders (VABs) in asphalt mixtures. For mixtures containing RAP/RAS, the aged asphalt binders in RAP and air-blown asphalt binders in RAS alter the performances of the extracted asphalt binders (EABs). Thus, the rheological properties of EABs from these mixtures require more investigation. The focus of this paper was relating the high-temperature properties of EABs from field cores to the corresponding rolling thin film oven aged virgin asphalt binders (RTFO AVABs). Furthermore, a comparison of the effect of RAP and RAS on the high-temperature rheological properties of EABs was another objective. Different asphalt cores were collected from the field within two weeks after the pavement construction process in 2016. These cores represented eight asphalt mixtures with different asphalt binder replacement percentages by RAP, RAS, or both. The asphalt binders were extracted from these mixtures and considered as RTFO AVABs. The high-temperature rheological properties included the temperature sweep and frequency sweep testing and the multiple stress creep recovery testing. The EABs had higher stiffnesses and elasticates than the corresponding RTFO AVABs because of the aged binders in RAP/RAS. The binders in RAP interacted more readily with VABs than RAS binders.

Laboratory Comparison of Permanent Deformation and Fatigue Behavior of Neat, Polymer, and Rubber-Asphalt Binders

2019 ◽  
Vol 2673 (4) ◽  
pp. 524-532
Author(s):  
Felipe F. Camargo ◽  
Kamilla Vasconcelos ◽  
Liedi L. Bernucci
Keyword(s):  
Fatigue Life ◽  
Life Prediction ◽  
Fatigue Behavior ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Fatigue Cracking ◽  
Fatigue Life Prediction ◽  
Polymer Modification ◽  
Neat Polymer ◽  
Percentage Recovery

Fatigue cracking and rutting are among the major types of distresses to be considered in flexible pavement design. In this context, the choice of the asphalt binder plays a major role in both the fatigue behavior and permanent deformation resistance of the asphalt mixture. This study was conducted to assess the permanent deformation and fatigue behavior of a field-blended rubber-asphalt (CRMA) and compare the results with typical binders used in Brazil. The neat binder used for modification was also employed as a control and as a base for polymer modification (SBSA). The binders were evaluated using the multiple stress creep and recovery (MSCR) for permanent deformation behavior, and the time sweep (TST) and linear amplitude sweep (LAS) tests for fatigue behavior. Modification of the neat binder resulted in an increase in percentage recovery in the MSCR, whereas the percentage recovery for CRMA was the highest among the three binders at any given temperature. The non-recoverable creep compliance for the CRMA was lower than that exhibited by the neat and SBSA binders for both stress levels for the range of temperatures tested. Binder modification resulted in an improved fatigue behavior compared with the neat binder according to the TST and LAS, whereas rubber modification resulted in the best fatigue behavior. Fatigue life prediction by TST was consistently higher than fatigue life prediction in the LAS test, probably because different criteria were used for determining failure in each test (ranking of the binders remained constant regardless of the criteria used).

RHEOLOGICAL BEHAVIOUR OF COCONUT SHELL POWDER MODIFIED ASPHALT BINDER

2016 ◽  
Vol 78 (7-3) ◽  
Author(s):  
Rosnawati Buhari ◽  
Nur Fareesya Zabidi ◽  
Mohd Ezree Abdullah ◽  
Siti Khatijah Abu Bakar ◽  
Nurul Hidayah Mohd Kamarudin
Keyword(s):  
Rheological Properties ◽  
Softening Point ◽  
Asphalt Binder ◽  
Rheological Behaviour ◽  
Coconut Shell ◽  
Modified Asphalt ◽  
Modified Asphalt Binder ◽  
Modified Binder ◽  
Coconut Shell Powder ◽  
Shell Powder

The objectives of this study were to determine the blending parameters of coconut shell powder (CSP) modified asphalt binder and to evaluate the rheological properties of CSP modified asphalt binder. CSP of 2%, 4%, 6%, 8% and 10% by weight of asphalt have been incorporated into an unaged 80/100 asphalt mix in order to improve its performance. The influence of the additives on the physical and rheological properties was evaluated with penetration test, softening point, storage stability, dynamic shear rheometer test (DSR), and Field Emission Scanning Electron Microscope (FESEM). The aging of asphalt binders was simulated in a laboratory by using Rotational Thin Film Oven (RTFO). The results showed that the addition of CSP into virgin binder was decreasing the penetration value and increasing the softening point temperature compared to the original binder. On the rheological effect, for unaged modified binder, higher CSP resulted higher G*/sin δ especially at lower temperature compared to the unaged control binder. Besides, for the aged modified binder, stiffness was lower than the control aged binder for all temperature.

Study of Rheological Properties of Cariphalte Modified Asphalt

2014 ◽  
Vol 638-640 ◽  
pp. 1185-1189
Author(s):  
Tan Hua
Keyword(s):  
Comparative Analysis ◽  
Rheological Properties ◽  
Fatigue Damage ◽  
Systematic Study ◽  
Low Temperatures ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Fatigue Properties ◽  
Dynamic Shear ◽  
Modified Asphalt

To explore the effects of different factors on the rheological properties of cariphalte modified asphalt, based superpave asphalt binder relevant norms, through the use of dynamic shear rheometer Shell 70# asphalt under different temperature, frequency and strain conditions and rheological properties of cariphalte modified asphalt carrying on a systematic study, and comparative analysis of the two anti-fatigue properties of asphalt in the middle and low temperature.The results show that: compared with 70# asphalt, cariphalte modified asphalt has better rutting resistance over a wide temperature range; at lower frequencies and high intensity pavement, cariphalte modified asphalt to better resistance to permanent deformation; better fatigue resistance at low temperatures, and more fatigue damage is not easy to achieve.

Rheological Properties of High Grade Asphalt and its Mixture

2014 ◽  
Vol 599 ◽  
pp. 244-247 ◽  
Author(s):  
Qun Shan Ye ◽  
Chang Jian Ye ◽  
Zhi Lin Sun
Keyword(s):  
Rheological Properties ◽  
Dynamic Modulus ◽  
Permanent Deformation ◽  
Asphalt Binder ◽  
Asphalt Mixture ◽  
Asphalt Binders ◽  
Test Results ◽  
Complex Shear Modulus ◽  
Complex Shear ◽  
Dynamic Modulus Test

Viscosity test, dynamic shear test, dynamic modulus test and creep test were conducted to investigate the rheological properties of high modulus asphalt and its mixture. Test results indicated that the viscosity of hard grade asphalt could be increased when compared with the ordinary asphalt, especially at high temperatures. The complex shear modulus and dynamic modulus of hard-grade asphalt binder and its mixture were increased, which implied that the stiffness of them was enhanced. Furthermore, the elastically portions for viscoelastic property of asphalt binders were increased, which resulted in the reduction of phase angle for hard grade asphalt binders and mixtures. The rutting parameter for hard-grade asphalt mixture was increased remarkably, which revealed that the resistance to permanent deformation could be significantly improved for hard grade asphalt mixture.

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