scholarly journals Modulation of Conductivity of Alginate Hydrogels Containing Reduced Graphene Oxide through the Addition of Proteins

Pharmaceutics ◽  
2021 ◽  
Vol 13 (9) ◽  
pp. 1473
Author(s):  
Ahmed Raslan ◽  
Jesús Ciriza ◽  
Ana María Ochoa de Retana ◽  
María Luisa Sanjuán ◽  
Muhammet S. Toprak ◽  
...  

Modifying hydrogels in order to enhance their conductivity is an exciting field with applications in cardio and neuro-regenerative medicine. Therefore, we have designed hybrid alginate hydrogels containing uncoated and protein-coated reduced graphene oxide (rGO). We specifically studied the adsorption of three different proteins, BSA, elastin, and collagen, and the outcomes when these protein-coated rGO nanocomposites are embedded within the hydrogels. Our results demonstrate that BSA, elastin, and collagen are adsorbed onto the rGO surface, through a non-spontaneous phenomenon that fits Langmuir and pseudo-second-order adsorption models. Protein-coated rGOs are able to preclude further adsorption of erythropoietin, but not insulin. Collagen showed better adsorption capacity than BSA and elastin due to its hydrophobic nature, although requiring more energy. Moreover, collagen-coated rGO hybrid alginate hydrogels showed an enhancement in conductivity, showing that it could be a promising conductive scaffold for regenerative medicine.

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 681 ◽  
Author(s):  
Fabian Arias Arias ◽  
Marco Guevara ◽  
Talia Tene ◽  
Paola Angamarca ◽  
Raul Molina ◽  
...  

Recently, green-prepared oxidized graphenes have attracted huge interest in water purification and wastewater treatment. Herein, reduced graphene oxide (rGO) was prepared by a scalable and eco-friendly method, and its potential use for the removal of methylene blue (MB) from water systems, was explored. The present work includes the green protocol to produce rGO and respective spectroscopical and morphological characterizations, as well as several kinetics, isotherms, and thermodynamic analyses to successfully demonstrate the adsorption of MB. The pseudo-second-order model was appropriated to describe the adsorption kinetics of MB onto rGO, suggesting an equilibrium time of 30 min. Otherwise, the Langmuir model was more suitable to describe the adsorption isotherms, indicating a maximum adsorption capacity of 121.95 mg g−1 at 298 K. In addition, kinetics and thermodynamic analyses demonstrated that the adsorption of MB onto rGO can be treated as a mixed physisorption–chemisorption process described by H-bonding, electrostatic, and π − π interactions. These results show the potential of green-prepared rGO to remove cationic dyes from wastewater systems.


RSC Advances ◽  
2016 ◽  
Vol 6 (61) ◽  
pp. 56278-56286 ◽  
Author(s):  
Lei Chen ◽  
Zhang-Run Xu

A 3D nickel-doped reduced graphene oxide aerogel was prepared by one-step reduction and self-assembly, which exhibited favorable selectivity and high adsorption capacity for isolating hemoglobin.


RSC Advances ◽  
2016 ◽  
Vol 6 (49) ◽  
pp. 43401-43407 ◽  
Author(s):  
Ritesh Sevanthi ◽  
Fahmida Irin ◽  
Dorsa Parviz ◽  
W. Andrew Jackson ◽  
Micah J. Green

The objective of this study was to investigate Joule heating/electric swing adsorption (ESA) as a mode of regeneration and to compare the carbon dioxide (CO2) adsorption capacity of pristine graphene films and reduced graphene oxide (rGO) aerogels.


2020 ◽  
Vol 114 ◽  
pp. 111075
Author(s):  
Iriana Zambrano-Andazol ◽  
Natalia Vázquez ◽  
Manuel Chacón ◽  
Ronald M. Sánchez-Avila ◽  
Mairobi Persinal ◽  
...  

2016 ◽  
Vol 18 (3) ◽  
pp. 1478-1486 ◽  
Author(s):  
K. Bramhaiah ◽  
Vidya N. Singh ◽  
Neena S. John

Binary and ternary systems of rGO, Au and ZnO with nanoparticle and nanorod morphologies are explored as photocatalysts and their photodegradation performance in relation to adsorption capacity and photoluminescence is presented.


2016 ◽  
Vol 4 (28) ◽  
pp. 10885-10892 ◽  
Author(s):  
Yuan Zhuang ◽  
Fei Yu ◽  
Hong Chen ◽  
Jie Zheng ◽  
Jie Ma ◽  
...  

We designed and prepared a novel alginate/reduced graphene oxide double-network hydrogel and investigated its mechanical properties, stability and adsorption capacity in comparison with a single network.


2014 ◽  
Vol 70 (10) ◽  
pp. 1663-1669 ◽  
Author(s):  
Jian-Zhong Sun ◽  
Zhi-Hong Liao ◽  
Rong-Wei Si ◽  
Gakai Peter Kingori ◽  
Fu-Xiang Chang ◽  
...  

Triphenylmethane (TPM) dye is one of the most prevalent and recalcitrant water contaminants. Magnetic reduced graphene oxide (rGO) is an efficient adsorbent for organic pollutants removal. However, the performance and adsorption kinetics of magnetic rGO towards TPM have not yet been studied. In this study, a magnetic Fe3O4@rGO nano-composite, which could be easily removed from water with a simple magnetic separation step was synthesized and characterized. The magnetic rGO showed fast adsorption rate and high adsorption capacity towards different TPM dyes (the Langmuir monolayer adsorption capacity is 64.93 mg/g for adsorption of crystal violet). The adsorption processes are well-fitted to the pseudo-second-order kinetic model (R2 > 0.99) and the Langmuir isotherm model (R2 = 0.9996). Moreover, the magnetic rGO also showed excellent recycling and regeneration capabilities. The results indicated that adsorption with magnetic rGO would be a promising strategy to clean up the TPM contamination.


2013 ◽  
Vol 864-867 ◽  
pp. 1717-1720
Author(s):  
Chu Bei Wang

Phosphoric acid /graphene composites were synthesized by a facile one-pot method in the oil-phase. The composites produced in this study have more active groups than reduced graphene oxide. Adsorption data indicated that active groups of the material had far greater influence on the adsorption capacity than inert functional groups of reduced graphene oxide.


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