scholarly journals On the Feasibility of a pMDI-Reduced Production of Wood Fiber Insulation Boards by Means of Kraft Lignin and Ligneous Canola Hulls

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1088
Author(s):  
Kolja Ostendorf ◽  
Christian Ahrens ◽  
Arne Beulshausen ◽  
Jean Lawrence Tene Tayo ◽  
Markus Euring
Keyword(s):  
Thermal Conductivity ◽  
Wood Fiber ◽  
Kraft Lignin ◽  
Positive Contribution ◽  
Diphenylmethane Diisocyanate ◽  
Wood Fibers ◽  
Hot Air ◽  
Softwood Kraft Lignin ◽  
Polymeric Diphenylmethane Diisocyanate ◽  
Different Climates

The thermal insulation of buildings using wood fiber insulation boards (WFIBs) constitutes a positive contribution towards climate change. Thereby, the bonding of wood fibers using mainly petrochemical-based resins such as polymeric diphenylmethane diisocyanate (pMDI) is an important measure to meet required board properties. Still there is a need to reduce or partial substitute the amount of these kinds of resins in favor of a greener product. This study therefore focusses on the feasibility of reducing the amount of pMDI by 50% through the addition of 1% BioPiva 395 or Indulin as two types of softwood Kraft-Lignin and lignin rich canola hulls together with propylene carbonate as a diluent. A panel density of 160 kg/m3 and a thickness of 40 mm was aimed. The curing of these modified pMDI was investigated by using two types of techniques: hot-steam (HS) and innovative hot-air/hot-steam-process (HA/HS). The WFIBs were then tested on their physical-mechanical properties. The equilibrium moisture content (EMC) was determined at two different climates. An exemplary investigation of thermal conductivity was conducted as well. The WFIBs did undergo a further chemically based analysis towards extractives content and elemental (C, N) composition. The results show that it is feasible to produce WFIBs with lower quantities of pMDI resin and added lignin with enhanced physical-mechanical board properties, which were lacking no disadvantages towards thermal conductivity or behavior towards moisture, especially when cured via HA/HS-process.

scholarly journals Thermal insulation properties of green vacuum insulation panel using wood fiber as core material

BioResources ◽  
2019 ◽  
Vol 14 (2) ◽  
pp. 3339-3351 ◽  
Author(s):  
Baowen Wang ◽  
Zhihui Li ◽  
Xinglai Qi ◽  
Nairong Chen ◽  
Qinzhi Zeng ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Bulk Density ◽  
Thermal Insulation ◽  
Wood Fiber ◽  
Core Material ◽  
High Porosity ◽  
Total Thermal Conductivity ◽  
Wood Fibers ◽  
Vacuum Insulation ◽  
Vacuum Insulation Panel

Wood fibers were prepared as core materials for a vacuum insulation panel (VIP) via a dry molding process. The morphology of the wood fibers and the microstructure, pore structure, transmittance, and thermal conductivity of the wood fiber VIP were tested. The results showed that the wood fibers had excellent thermal insulation properties and formed a porous structure by interweaving with one another. The optimum bulk density that led to a low-cost and highly thermally efficient wood fiber VIP was 180 kg/m3 to 200 kg/m3. The bulk density of the wood fiber VIP was 200 kg/m3, with a high porosity of 78%, a fine pore size of 112.8 μm, and a total pore volume of 7.0 cm3·g-1. The initial total thermal conductivity of the wood fiber VIP was 9.4 mW/(m·K) at 25 °C. The thermal conductivity of the VIP increased with increasing ambient temperature. These results were relatively good compared to the thermal insulation performance of current biomass VIPs, so the use of wood fiber as a VIP core material has broad application prospects.

scholarly journals Thermo-Mechanical Properties of a Wood Fiber Insulation Board Using a Bio-Based Adhesive as a Binder

Buildings ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 152
Author(s):  
Franz Segovia ◽  
Pierre Blanchet ◽  
Nicolas Auclair ◽  
Gatien Geraud Essoua Essoua
Keyword(s):  
Mechanical Properties ◽  
Thermal Conductivity ◽  
Tensile Strength ◽  
Compressive Strength ◽  
Citric Acid ◽  
Crude Glycerol ◽  
Wood Fiber ◽  
Physical And Mechanical Properties ◽  
Acid Mixture ◽  
Wood Fibers

The goal of the present study was to develop a low-density thermal insulation board using wood fibers and a bio-based adhesive as a binder, which was prepared from a crude glycerol and citric acid mixture. The physical and mechanical properties of insulation boards manufactured using two ratios of crude glycerol and citric acid (1:0.66 and 1:1 mol/mol) and two adhesive contents (14% and 20%) were evaluated. The results show that the insulation boards with a range of density between 332 to 338 kg m−3 present thermal conductivity values between 0.064 W/m-K and 0.066 W/m-K. The effect of adhesive content was very significant for certain mechanical properties (tensile strength perpendicular to surface and compressive strength). The tensile strength (internal bond) increased between 20% and 36% with the increased adhesive content. In contrast, the compressive strength decreased between 7% and 15%. The thermo-mechanical properties obtained of insulation boards such as thermal conductivity, traverse strength, tensile strength parallel and perpendicular to surface, and compressive strength are in accordance with the requirements of the American Society for Testing and Materials C208-12 standard for different uses. The results confirm the potential of crude glycerol and citric acid mixture to be used as an adhesive in the wood fiber insulation boards’ manufacturing for sustainability purposes.

scholarly journals Reactivity of Aliphatic and Phenolic Hydroxyl Groups in Kraft Lignin towards 4,4′ MDI

Molecules ◽  
2021 ◽  
Vol 26 (8) ◽  
pp. 2131
Author(s):  
Leonardo Dalseno Antonino ◽  
Júlia Rocha Gouveia ◽  
Rogério Ramos de Sousa Júnior ◽  
Guilherme Elias Saltarelli Garcia ◽  
Luara Carneiro Gobbo ◽  
...  
Keyword(s):  
Experimental Work ◽  
Chemical Structure ◽  
31P Nmr ◽  
Kraft Lignin ◽  
Hydroxyl Group ◽  
Hydroxyl Groups ◽  
Diphenylmethane Diisocyanate ◽  
Complex Chemical ◽  
Heterogeneous Reactivity ◽  
Phenolic Hydroxyl Groups

Several efforts have been dedicated to the development of lignin-based polyurethanes (PU) in recent years. The low and heterogeneous reactivity of lignin hydroxyl groups towards diisocyanates, arising from their highly complex chemical structure, limits the application of this biopolymer in PU synthesis. Besides the well-known differences in the reactivity of aliphatic and aromatic hydroxyl groups, experimental work in which the reactivity of both types of hydroxyl, especially the aromatic ones present in syringyl (S-unit), guaiacyl (G-unit), and p-hydroxyphenyl (H-unit) building units are considered and compared, is still lacking in the literature. In this work, the hydroxyl reactivity of two kraft lignin grades towards 4,4′-diphenylmethane diisocyanate (MDI) was investigated. 31P NMR allowed the monitoring of the reactivity of each hydroxyl group in the lignin structure. FTIR spectra revealed the evolution of peaks related to hydroxyl consumption and urethane formation. These results might support new PU developments, including the use of unmodified lignin and the synthesis of MDI-functionalized biopolymers or prepolymers.

Effect of the delignification of wood fibers on the mechanical properties of wood fiber–polypropylene composites

2006 ◽  
Vol 102 (5) ◽  
pp. 4759-4763 ◽  
Author(s):  
Alinaghi Karimi ◽  
Saleh Nazari ◽  
Ismaeil Ghasemi ◽  
Mehdi Tajvidi ◽  
Ghanbar Ebrahimi
Keyword(s):  
Mechanical Properties ◽  
Wood Fiber ◽  
Wood Fibers ◽  
Polypropylene Composites

scholarly journals Improved Procedure for Electro-Spinning and Carbonisation of Neat Solvent-Fractionated Softwood Kraft Lignin

2021 ◽  
Author(s):  
Inam Khan ◽  
Bongkot Hararak ◽  
Gerard Franklyn Fernando
Keyword(s):  
Cross Section ◽  
Circular Cross Section ◽  
Kraft Lignin ◽  
Binary Solvent ◽  
Natural Polymers ◽  
Solvent Fractionation ◽  
Custom Made ◽  
Treatment Procedures ◽  
Softwood Kraft Lignin ◽  
Soluble Lignin

Abstract In general, the electro-spinning of lignin requires it to be functionalised and/or blended with synthetic or natural polymers. This paper reports on the use of solvent fractionated lignin-lignin blend to electro-spin BioChoice® softwood Kraft lignin. The blend consisted of acetone-soluble and ethanol-soluble lignin in a binary solvent of acetone and DMSO. Solvent fractionation was used to purify lignin where the ash content was reduced in the soluble lignin fractions from 1.24% to ~0.1%. The corresponding value for conventional acid-washing in sulphuric acid was 0.34%. A custom-made electro-spinning apparatus was used to produce the nano-fibres. Heat treatment procedures were developed for drying the electro-spun fibres prior to oxidation and carbonisation; this was done to prevent fibre fusion. The lignin fibres were oxidised at 250⁰C, carbonised at 1000⁰C and 1500⁰C. The cross-section of the fibres was circular and they were observed to be void-free. The longitudinal sections showed that the fibres were not fused. Thus, this procedure demonstrated that solvent fractionated lignin can be electro-spun without using plasticisers or polymer blends using common laboratory solvents and subsequently carbonised to produce carbon fibres with a circular cross-section.

Unused Plant Waste and Thermal Insulation Composition Boards on their Basis

2021 ◽  
Vol 887 ◽  
pp. 480-486
Author(s):  
T.N. Vachnina ◽  
I.V. Susoeva ◽  
A.A. Titunin ◽  
S.V. Tsybakin
Keyword(s):  
Thermal Conductivity ◽  
Thermal Insulation ◽  
Wood Fiber ◽  
Mineral Wool ◽  
Wood Waste ◽  
Insulation Material ◽  
Plant Fibers ◽  
Coefficient Of Thermal Conductivity ◽  
Plant Waste ◽  
Technology Of Production

Many plant wastes are not currently used in production, they are disposed of in landfills or incinerated. The aim of this study is to develop a composite thermal insulation material from unused spinning waste of flax and cotton fibers and soft wood waste. Samples of thermal insulation materials from plant waste were made by drying using the technology of production of soft wood fiber boards. For composite board defined physico-mechanical characteristics and thermal conductivity. The experiment was carried out according to a second-order plan, regression models of the dependences of the material indicators on the proportion of the binder additive, drying temperature and the proportion of wood waste additives were developed. The study showed that composites from unused spinning waste of plant fibers and soft wood waste have the necessary strength under static bending, the swelling in thickness after staying in water is much lower in comparison with the performance of boards from other plant fillers. The coefficient of thermal conductivity of the boards is comparable with the indicator for mineral wool boards.

scholarly journals Evaluation of Alternative Substrates and Fertilizer Regimes for the Nursery Cultivation of Phyllostachys pubescens (Carrière) J. Houz.

2017 ◽  
Vol 45 (2) ◽  
pp. 442-445
Author(s):  
Federica LARCHER ◽  
Luca BATTISTI ◽  
Walter GAINO ◽  
Marco DEVECCHI
Keyword(s):  
Rice Husk ◽  
Wood Fiber ◽  
Phyllostachys Pubescens ◽  
Wood Fibers ◽  
Alternative Materials ◽  
Before And After ◽  
Sustainable Cultivation ◽  
Recorded Data ◽  
Fertilizer Regimes ◽  
Coconut Fibers

The economic importance of the bamboo cultivation in Asia is well known, but the recent rise of interest in Europe required more deep studies on growing techniques. Among the bamboo species, the Phyllostachys pubescens (Carrière) J. Houz. is appreciated for its multiple uses: landscaping, timber and shoots production. In order to identify the best and sustainable combination of substrates and fertilization regimes, a nursery experimental trial was performed in 2016. Eight treatments (four substrates and two fertilization regimes) with 256 young plantlets divided into four randomized blocks were evaluated. The substrates used were: 40% peat, 40% coconut fibers, 20% pumice (standard substrate, S1); 30% peat, 40% coconut fibers, 10% rice husk, 20% pumice (S2); 30% peat, 40% coconut fibers, 20% rice husk, 10% pumice (S3); 30% peat, 40% coconut fibers, 20% wood fibers, 10% pumice (S4). The two fertilization regimes were: 1.6 g l-1 (A) and 0.8 g l-1 (B) NPK (16-11-10) Osmocote Exact®. All substrates were supplemented with a fungal inoculum (2.5 g l-1) and corrected with 2.5 × 10-3 g l-1 of CaCO3. The number of culms and leaves and the SPAD values of six plants of each blocks were monthly measured. Fresh and dry weights, before and after cultivation was recorded. Data were statistically analyzed. Results showed that rice husk should be used only in low percentage, but wood fiber can be more suitable for bamboo cultivation. The combination of alternative materials and low fertilization regimes (S1_B and S4_B) should be the key for a more sustainable cultivation for potted Phyllostachys pubescens in Europe.

scholarly journals Flame Retardancy of Wood Fiber Materials Using Phosphorus-Modified Wheat Starch

Molecules ◽  
2020 ◽  
Vol 25 (2) ◽  
pp. 335 ◽  
Author(s):  
Stefan Gebke ◽  
Katrin Thümmler ◽  
Rodolphe Sonnier ◽  
Sören Tech ◽  
André Wagenführ ◽  
...  
Keyword(s):  
Flame Retardant ◽  
Flame Retardancy ◽  
Flame Retardants ◽  
Wood Fiber ◽  
Reaction System ◽  
Wheat Starch ◽  
Wood Fibers ◽  
Industrial Processing ◽  
Starch Derivatives ◽  
Fiber Materials

Biopolymer-based flame retardants (FR) are a promising approach to ensure adequate protection against fire while minimizing health and environmental risks. Only a few, however, are suitable for industrial purposes because of their poor flame retardancy, complex synthesis pathway, expensive cleaning procedures, and inappropriate application properties. In the present work, wheat starch was modified using a common phosphate/urea reaction system and tested as flame retardant additive for wood fibers. The results indicate that starch derivatives from phosphate/urea systems can reach fire protection efficiencies similar to those of commercial flame retardants currently used in the wood fiber industry. The functionalization leads to the incorporation of fire protective phosphates (up to 38 wt.%) and nitrogen groups (up to 8.3 wt.%). The lowest levels of burning in fire tests were measured with soluble additives at a phosphate content of 3.5 wt.%. Smoldering effects could be significantly reduced compared to unmodified wood fibers. The industrial processing of a starch-based flame retardant on wood insulating materials exhibits the fundamental applicability of flame retardants. These results demonstrate that starch modified from phosphate/urea-systems is a serious alternative to traditional flame retardants.

Investigation of the Fracture of Resinated Single Wood Fibers in an Environmental Scanning Electron Microscope (Esem)

1998 ◽  
Vol 4 (S2) ◽  
pp. 838-839
Author(s):  
A. Egan ◽  
S. Shaler
Keyword(s):  
Mechanical Properties ◽  
Polymer Composite ◽  
Laser Scanning ◽  
Medium Density Fiberboard ◽  
Wood Fiber ◽  
Image Correlation ◽  
Environmental Scanning ◽  
Wood Fibers ◽  
Wood Polymer ◽  
Scanning Electron

Single fiber fracture is important in understanding the fundamental failure mechanisms in wood/polymer composite products such as medium density fiberboard (MDF). The mechanical properties and fracture behavior of individual wood fibers has only recently been observable using a combination of environmental scanning electron microscopy (ESEM), laser scanning confocal microscopy and digital image correlation (DIC). Previous work has shown that specific areas on the fiber such as microcompressions and pits acted as crack nucelators and induce a brash fracture across the surface of the fiber. Given the development of these procedures it is now possible to observe and measure the mechanical properties and fracture characteristics of the wood fiber/ polymer composite fibers.Individual black spruce wood fibers were coated with diphenylmethane 4-4'diisocyanate resin containing Hostasol Red GG. The addition of the Hostasol Red flurochrome provided the option of quantifying resin coverage by fluorescence microscopy.

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