scholarly journals An Insight into a Sustainable Removal of Bisphenol A from Aqueous Solution by Novel Palm Kernel Shell Magnetically Induced Biochar: Synthesis, Characterization, Kinetic, and Thermodynamic Studies

Polymers ◽  
2021 ◽  
Vol 13 (21) ◽  
pp. 3781
Author(s):  
Kamil Kayode Katibi ◽  
Khairul Faezah Yunos ◽  
Hasfalina Che Man ◽  
Ahmad Zaharin Aris ◽  
Mohd Zuhair Mohd Mohd Nor ◽  
...  
Keyword(s):  
Bisphenol A ◽  
Palm Kernel ◽  
Textural Properties ◽  
Batch Adsorption ◽  
Aqueous Environment ◽  
Ferrous Chloride ◽  
Magnetic Biochar ◽  
Palm Kernel Shell ◽  
Estrogenic Contaminants ◽  
Co Precipitation

Recently Bisphenol A (BPA) is one of the persistent trace hazardous estrogenic contaminants in the environment, that can trigger a severe threat to humans and environment even at minuscule concentrations. Thus, this work focused on the synthesis of neat and magnetic biochar (BC) as a sustainable and inexpensive adsorbent to remove BPA from aqueous environment. Novel magnetic biochar was efficiently synthesized by utilizing palm kernel shell, using ferric chloride and ferrous chloride as magnetic medium via chemical co-precipitation technique. In this experimental study, the influence of operating factors comprising contact time (20–240 min), pH (3.0–12.0), adsorbent dose (0.2–0.8 g), and starting concentrations of BPA (8.0–150 ppm) were studied in removing BPA during batch adsorption system using neat biochar and magnetic biochar. It was observed that the magnetically loaded BC demonstrates superior maximum removal efficiency of BPA with 94.2%, over the neat biochar. The functional groups (FTIR), Zeta potential, vibrating sample magnetometer (VSM), surface and textural properties (BET), surface morphology, and mineral constituents (FESEM/EDX), and chemical composition (XRD) of the adsorbents were examined. The experimental results demonstrated that the sorption isotherm and kinetics were suitably described by pseudo-second-order model and Freundlich model, respectively. By studying the adsorption mechanism, it was concluded that π-π electron acceptor–donor interaction (EAD), hydrophobic interaction, and hydrogen bond were the principal drives for the adsorption of BPA onto the neat BC and magnetic BC.

scholarly journals SYNTHESIS AND CHARACTERIZATION: COMPOSITE OF GRAPHENE OXIDE BASED PALM KERNEL SHELL WASTE WITH FE3O4

2021 ◽  
Vol 22 (2) ◽  
pp. 101
Author(s):  
Bernadeta Ayu Widyaningrum ◽  
Dita Apriani ◽  
Putri Amanda ◽  
Ismadi Ismadi ◽  
Sutanto Sutanto
Keyword(s):  
Raman Spectroscopy ◽  
Graphene Oxide ◽  
Palm Kernel ◽  
Energy Dispersive Spectrum ◽  
Energy Dispersive ◽  
Synthesis And Characterization ◽  
Palm Kernel Shell ◽  
Shell Waste ◽  
Ft Ir ◽  
Co Precipitation

SYNTHESIS AND CHARACTERIZATION: COMPOSITE OF GRAPHENE OXIDE BASED PALM KERNEL SHELL WASTE WITH Fe3O4. In this study, GO-Fe3O4 were fabricated by co-precipitation technique and the graphene oxide (GO) were synthesized from an agricultural biomass, palm kernel shell, via Hummer’s method. Field Emission Scanning Electron Microscopy and Energy Dispersive Spectrum (FESEM-EDS), Fourier Transform Infra-Red (FT-IR) spectroscopy, X-Ray Diffractometer (XRD), and Raman spectroscopy were used to analysis the successful attachment of Fe3O4 onto the surface of GO. Morphology observation showed that Fe3O4 were heterogeneously deposited on the surface of GO. FT-IR spectra shows peak that incorporated to oxygenated functional groups and sharp peak at 586 cm-1 confirmed to lattice absorption of Fe3O4. The percentage of composition of GO-Fe3O4 was characterized by energy dispersive spectroscopy and the results also confirmed in XRD exhibits similar properties with JCPDS 19-0629 for magnetite more dominant than GO. From Raman spectroscopy analysis shows that 1343.82 cm-1 (D-band) and 1584.62 cm-1 (G-band) and 2698 cm-1 (2D-band) indicates GO and GO-Fe3O4 were successfully synthesized.

Synthesis of magnetic biochar derived from cotton stalks for the removal of Cr(VI) from aqueous solution

2019 ◽  
Vol 79 (11) ◽  
pp. 2106-2115 ◽  
Author(s):  
Fengfeng Ma ◽  
Baowei Zhao ◽  
Jingru Diao
Keyword(s):  
Adsorption Capacity ◽  
Photoelectron Spectroscopy ◽  
Batch Adsorption ◽  
Maximum Adsorption Capacity ◽  
Cotton Stalk ◽  
Magnetic Biochar ◽  
X Ray ◽  
Cotton Stalks ◽  
Pseudo Second Order ◽  
Co Precipitation

Abstract A magnetic cotton stalk biochar (MCSBC) was synthesized through chemical co-precipitation, based on cotton stalk biochar (CSBC). The MCSBC and CSBC were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy and vibrating sample magnetometry. The characterization analyses showed that the magnetization process endowed the CSBC with excellent magnetic properties with a superparamagnetic magnetization of 27.59 emu/g. Batch adsorption experiment results indicated that the Cr(VI) maximum adsorption capacity of MCSBC was 20.05 mg/g, which was higher than that of CSBC (18.77 mg/g). The adsorption kinetic data were well fitted by the pseudo-second-order model and the adsorption isotherms were well represented by the Sips isotherm model. The thermodynamic studies indicated that the adsorption process was spontaneous and endothermic, and the entropy increased. The potential adsorption mechanism was the electrostatic adsorption of anionic Cr(VI) to the positively charged MCSBC surface, the reduction of Cr(VI) into Cr(III) and the complexation of Cr(III) by oxygen-containing functional groups of MCSBC. The regeneration studies showed that MCSBC kept 80% of its initial Cr(VI) adsorption capacity in the cycle. All the findings suggest that this novel magnetic biochar could be used in the field of Cr(VI)-containing wastewater treatment.

Magnetic biochar derived from waste palm kernel shell for biodiesel production via sulfonation

2020 ◽  
Vol 118 ◽  
pp. 626-636
Author(s):  
Ray Vern Quah ◽  
Yie Hua Tan ◽  
N.M. Mubarak ◽  
Jibrail Kansedo ◽  
Mohammad Khalid ◽  
...  
Keyword(s):  
Palm Kernel ◽  
Biodiesel Production ◽  
Magnetic Biochar ◽  
Palm Kernel Shell

Bimetallic Fe-Ni/Zeolite β Catalysts for Hydrogen Generation from Steam Gasification of Palm Kernel Shell

2014 ◽  
Vol 925 ◽  
pp. 313-317
Author(s):  
Anita Ramli ◽  
Siti Eda Eliana Misi ◽  
Mas Fatiha Mohamad ◽  
Suzana Yusup
Keyword(s):  
Hydrogen Generation ◽  
Fixed Bed ◽  
Palm Kernel ◽  
Textural Properties ◽  
Lower Surface ◽  
Steam Gasification ◽  
Impregnation Method ◽  
Palm Kernel Shell ◽  
Calcination Temperatures ◽  
Zeolite Β

In this study, the potential usage of PKS as a direct source for hydrogen production is being explored in the presence of bimetallic Fe-Ni/Zeolite β (BEA) catalyst. The catalyst was prepared by co-impregnation method and calcined at temperatures between 500-700 oC to study the effect of calcination temperatures on the gas compositions from steam gasification of PKS. The textural properties and crystalline phase present were characterized using BET and X-Ray Diffraction. The catalysts were tested in steam gasification of PKS in a fixed-bed microreactor at 700 oC using 0.3 g catalyst and 0.9 g PKS. The steam to PKS ratio was 4:1 (vol) while steam to Ar ratio was 1:6 (vol.). The Fe-Ni/BEA catalysts possess lower surface area, higher pore volume and larger pore diameter as compared to the bare BEACalcination temperature is found to contribute to the crystallization of the prepared catalysts where high crystallization of Fe and Ni was observed in Fe-Ni/BEA (700) catalyst with the formation of NiO and NiFe2O4 phase. Fe-Ni/BEA (700) shows the highest composition of H2 gas produced with 76.32 vol% H2, 18.72 vol% CO2, 4.96 vol% CO and the absence of CH4. This shows that the steam gasification of PKS in the presence of Fe-Ni/BEA (700) has a potential to replace the commercial H2 production via methane reforming process.

scholarly journals Isotherm Studies of Adsorption of Methylene Blue by Palm Kernel Shell

2018 ◽  
pp. 1-9
Author(s):  
Oladokun Benjamen Niran ◽  
Salaudeen Abdulwasiu Olawale ◽  
Utam John Ushie
Keyword(s):  
Methylene Blue ◽  
Adsorption Process ◽  
Palm Kernel ◽  
Isotherm Models ◽  
Batch Adsorption ◽  
Suitable Model ◽  
Palm Kernel Shell ◽  
Freundlich Adsorption Isotherm ◽  
Langmuir And Freundlich Models ◽  
Mb Adsorption

The main aim of this work is determine the feasibility of palm kernel shell (PKS) with phosphoric acid impregnation to biosorb methylene blue (MB) from aqueous solution by carrying out isotherm studies of the process. The influence of various factors such as contact time, initial dye concentration, adsorbent dosage, pH of dye solution and temperature were investigated in a batch adsorption technique. Result showed that adsorption of methylene blue (MB) dye was favourable at acidic pH. The percentage adsorption was found to increase with time of agitation, temperature, and mass of adsorbent but decreased with increase in initial MB concentration. In order to obtain a suitable model for the MB adsorption process, obtained data were fitted into different isotherm models like Langmuir and Freundlich models. Results showed that Freundlich adsorption isotherm model best describe MB adsorption onto palm kernel shell (PKS).

A COMPARISON STUDY OF WATER FILTERING MATERIALSMADE FROM EXTRACTED PALM FRUIT FIBREAND PALM KERNEL SHELL

2017 ◽  
Vol 16 (12) ◽  
pp. 2657-2663
Author(s):  
Jamaliah Idris ◽  
Siti Fadira Osman ◽  
Eyu Gaius ◽  
Chukwuekezie Christian
Keyword(s):  
Palm Kernel ◽  
Comparison Study ◽  
Palm Fruit ◽  
Palm Kernel Shell

scholarly journals Synthesis, characterization and heavy metal removal efficiency of nickel ferrite nanoparticles (NFN’s)

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Waheed Ali Khoso ◽  
Noor Haleem ◽  
Muhammad Anwar Baig ◽  
Yousuf Jamal
Keyword(s):  
Heavy Metals ◽  
Nickel Ferrite ◽  
Contact Time ◽  
Metal Removal ◽  
Heavy Metal Removal ◽  
Ferrite Nanoparticles ◽  
Batch Adsorption ◽  
Aqueous Environment ◽  
Human Beings ◽  
Nickel Ferrite Nanoparticles

AbstractThe heavy metals, such as Cr(VI), Pb(II) and Cd(II), in aqueous solutions are toxic even at trace levels and have caused adverse health impacts on human beings. Hence the removal of these heavy metals from the aqueous environment is important to protect biodiversity, hydrosphere ecosystems, and human beings. In this study, magnetic Nickel-Ferrite Nanoparticles (NFNs) were synthesized by co-precipitation method and characterized using X-Ray Diffraction (XRD), Energy Dispersive Spectroscopy (EDS) and Field Emission Scanning Electronic Microscopy (FE-SEM) techniques in order to confirm the crystalline structure, composition and morphology of the NFN’s, these were then used as adsorbent for the removal of Cr(VI), Pb(II) and Cd(II) from wastewater. The adsorption parameters under study were pH, dose and contact time. The values for optimum removal through batch-adsorption were investigated at different parameters (pH 3–7, dose: 10, 20, 30, 40 and 50 mg and contact time: 30, 60, 90, and 120 min). Removal efficiencies of Cr(VI), Pb(II) and Cd(II) were obtained 89%, 79% and 87% respectively under optimal conditions. It was found that the kinetics followed the pseudo second order model for the removal of heavy metals using Nickel ferrite nanoparticles.

scholarly journals Release of toxic methylene blue from water by mesoporous silicalite-1: characterization, kinetics and isotherm studies

2021 ◽  
Vol 11 (7) ◽  
Author(s):  
Sabarish Radoor ◽  
Jasila Karayil ◽  
Aswathy Jayakumar ◽  
Jyotishkumar Parameswaranpillai ◽  
Suchart Siengchin
Keyword(s):  
Electron Microscopy ◽  
Contact Time ◽  
Dye Removal ◽  
Batch Adsorption ◽  
Aqueous Environment ◽  
Order Kinetic ◽  
Adsorption Method ◽  
X Ray ◽  
Ft Ir ◽  
Adsorption Desorption

AbstractIn the present work, we have developed a mesoporous silicalite-1 using CMC as a template for the removal of MB from aqueous solution. The synthesized silicalite-1 were characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), thermogravimetric analysis (TGA), Energy-dispersive X-ray spectroscopy (EDAX) and N2 adsorption–desorption isotherm (BET). XRD and FT-IR analysis confirmed the formation of crystallinity and development of MFI structure in the mesoporous silicalite-1. The adsorption of MB dye on mesoporous silicalite-1 was conducted by batch adsorption method. The effect of various parameters such as adsorbent dosage, initial dye concentration, contact time and temperature on the dye uptake ability of silicalite-1 was investigated. The operating parameters for the maximum adsorption are silicalite-1 dosage (0.1 wt%), contact time (240 min), initial dye concentration (10 ppm) and temperature (30 ℃). The MB dye removal onto mesoporous silicalite-1 followed pseudo-second-order kinetic and Freundlich isotherm. The silicalite-1 exhibits 86% removal efficiency even after six adsorption–desorption cycle. Therefore, the developed mesoporous silicalite-1 is an effective eco-friendly adsorbent for MB dye removal from aqueous environment.

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