scholarly journals The Effect of Various Nanofluids on Absorption Intensification of CO2/SO2 in a Single-Bubble Column

Processes ◽  
2019 ◽  
Vol 7 (7) ◽  
pp. 393 ◽  
Author(s):  
Karamian ◽  
Mowla ◽  
Esmaeilzadeh

Application of nanoparticles in aqueous base-fluids for intensification of absorption rate is an efficient method for absorption progress within the system incorporating bubble-liquid process. In this research, SO2 and CO2 were separately injected as single raising bubbles containing nanofluids to study the impact of nanoparticle effects on acidic gases absorption. In order to do this, comprehensive experimental studies were done. These works also tried to investigate the effect of different nanofluids such as water/Al2O3 or water/Fe2O3 or water/SiO2 on the absorption rate. The results showed that the absorption of CO2 and SO2 in nanofluids significantly increases up to 77 percent in comparison with base fluid. It was also observed that the type of gas molecules and nanoparticles determine the mechanism of mass transfer enhancement by nanofluids. Additionally, our findings indicated that the values of mass transfer coefficient of SO2 in water/Al2O3, water/Fe2O3 and water/SiO2 nanofluids are, respectively, 50%, 42% and 71% more than those of SO2 in pure water (kLSO2-water=1.45×10-4 m/s). Moreover, the values for CO2 in above nanofluids were, respectively, 117%, 103% and 88% more than those of CO2 in water alone (kLCO2-water=1.03×10-4 m/s). Finally, this study tries to offer a new comprehensive correlation for mass transfer coefficient and absorption rate prediction.

2010 ◽  
Vol 4 (7) ◽  
Author(s):  
D. Devakumar ◽  
K. Saravanan ◽  
T. Kannadasan ◽  
B. Meenakshipriya

2015 ◽  
Vol 69 (5) ◽  
pp. 553-559 ◽  
Author(s):  
Milica Djekovic-Sevic ◽  
Nevenka Boskovic-Vragolovic ◽  
Ljiljana Takic ◽  
Radmila Garic-Grulovic ◽  
Srdjan Pejanovic

Experimental investigation of gas-liquid mass transfer of ozone in water, in bubble column with two-fluid nozzle gas distributor (BKDM), under different operating conditions, are presented in this work. The main objective was to determine the ozone volumetric mass transfer coefficient, kL a, in calm uniform section of the column, under different values of gas and liquid flow rates. Obtained values of these coefficients were compared with the values in countercurrent bubble column. The critical liquid flowrate, when gas hold up reaches its maximum, was experimentally determined. It was shown that the maximum value of the ozone volumetric mass transfer coefficient is obtained just when liquid flowrate is at its critical value.


2012 ◽  
Vol 461 ◽  
pp. 151-154
Author(s):  
Dai Yong Jia ◽  
Lu Yan Sui ◽  
Ming Lai He

In this study, an experiment platform was built up to determine the key parameter, mass transfer coefficient, of the ventilation and dehumidification process in main cable of suspension bridge. On the basis of experimental studies, an empirical formula of the mass transfer coefficient was obtained, which can greatly contribute to control the content of moisture in the main cable of suspension bridges.


2018 ◽  
Vol 78 (3) ◽  
pp. 622-633 ◽  
Author(s):  
Yujia Song ◽  
Xiaodong Wang ◽  
Haiying Zhang

Abstract To study dynamic laws of ammonia nitrogen retention in a typical rural–urban fringe canal, NaBr was selected as a conservative tracer agent, and NH4Cl as an additive nutritive salt to conduct an instantaneously added tracer experiment outdoors. On this basis, tracer additions for spiralling curve characterisation (TASCC) method and nutritive spiral indexes were used for the quantitative depiction of retention dynamics of NH4+-N. The Michaelis–Menten (M-M) model was used to simulate absorption dynamic characteristics of NH4+-N. Results showed that the variation range of absorption length of NH4+-N under background concentration was 93.94–295.54 m with an average value of 177.41 m, the variation range of mass transfer coefficient was 0.16–0.38 mm/s with an average value of 0.26 mm/s, and the variation range of absorption rate was 0.16–0.38 mg/(m2⋅s) with an average value of 0.26 mg/(m2⋅s). The maximum absorption rate of NH4+-N obtained via M-M equation simulation was 0.59–1.38 mg/(m2⋅s), and the subsaturation constant was 1.10–5.03 mg/L. The variability of the dynamic absorption length, overall dynamic absorption rate, and overall dynamic mass transfer coefficient shown by NH4+-N within the range from background concentration to saturation concentration certified that TASCC could analyse the dynamic process of NH4+-N retention and absorption by the canal.


2021 ◽  
Vol 7 (1) ◽  
pp. 25
Author(s):  
Pao-Chi Chen ◽  
Hsun-Huang Cho ◽  
Jyun-Hong Jhuang ◽  
Cheng-Hao Ku

In order to select the best mixed amines in the CO2 capture process, the absorption of CO2 in mixed amines was explored at the required concentrations by using monoethanolamine (MEA) as a basic solvent, mixed with diisopropanolamine (DIPA), triethanolamine (TEA), 2-amino-2-methyl-1-propanol (AMP), and piperazine (PZ). Here, a bubble column was used as the scrubber, and a continuous operation was adopted. The Taguchi method was used for the experimental design. The conditional factors included the type of mixed amine (A), the ratio of the mixed amines (B), the liquid feed flow (C), the gas-flow rate (D), and the concentration of mixed amines (E). There were four levels, respectively, and a total of 16 experiments. The absorption efficiency (EF), absorption rate (RA), overall mass transfer coefficient (KGa), and scrubbing factor (ϕ) were used as indicators and were determined in a steady-state by the mass balance and two-film models. According to the Taguchi analysis, the importance of the parameters and the optimum conditions were obtained. In terms of the absorption efficiency (EF), the absorption rate (absorption factor) (RA/ϕ), and the overall mass transfer coefficient (KGa), the order of importance is D > E > A > B > C, D > E > C > B > A, and D > E > C > A > B, respectively, and the optimum conditions are A1B4C4D3E3, A1B3C4D4E2, A4B2C3D4E4, and A1B1C1D4E1. The optimum condition validation results showed that the optimal values of EF, RA, and KGa are 100%, 30.69 × 10−4 mol/s·L, 1.540 l/s, and 0.269, respectively. With regard to the selection of mixed amine, it was found that the mixed amine (MEA + AMP) performed the best in the CO2 capture process.


Author(s):  
Keshav C Ruthiya ◽  
John van der Schaaf ◽  
Ben F.M. Kuster ◽  
Jaap C Schouten

In this paper, the influence of carbon and silica particle slurry concentration up to 20 g/l (4 vol%) on regime transition, gas hold-up, and volumetric mass transfer coefficient is studied in a 2-dimensional slurry bubble column. From high speed video image analysis, the average large bubble diameter, the frequency of occurrence of large bubbles, the gas-liquid interfacial area, and the large bubble hold-up are obtained. The liquid side mass transfer coefficient is calculated from the volumetric mass transfer coefficient and the gas-liquid interfacial area. The lyophilic silica particles are rendered lyophobic by a methylation process to study the influence of particle wettability. The influence of organic electrolyte (sodium gluconate) and the combination of electrolyte and particles is also studied. It is found that lyophilic silica, lyophobic silica, and lyophobic carbon particles at concentrations larger than 2 g/l (0.4 vol%) decrease the gas hold-up and shift the regime transition point (where the first large bubbles appear) to a lower gas velocity. The volumetric mass transfer coefficient increases with gas velocity, increases with electrolyte concentration, decreases with slurry concentration, and is higher for lyophobic particles. The liquid side mass transfer coefficient increases with gas velocity, bubble diameter, and is higher for lyophobic particles. A correlation for the mass transfer coefficient based on dimensionless numbers is proposed for the heterogeneous regime.


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