scholarly journals A Wide-Range and Calibration-Free Spectrometer Which Combines Wavelength Modulation and Direct Absorption Spectroscopy with Cavity Ringdown Spectroscopy

Sensors ◽  
2020 ◽  
Vol 20 (3) ◽  
pp. 585 ◽  
Author(s):  
Zhen Wang ◽  
Yanjun Du ◽  
Yanjun Ding ◽  
Zhimin Peng
Keyword(s):  
Diode Laser ◽  
Tunable Diode Laser ◽  
Cavity Ringdown Spectroscopy ◽  
Wavelength Modulation ◽  
Direct Absorption ◽  
Cavity Ringdown ◽  
Direct Absorption Spectroscopy ◽  
Ringdown Time ◽  
Wide Range ◽  
Calibration Free

A wide-range, calibration-free tunable diode laser spectrometer is established by combining wavelength modulation and direct absorption spectroscopy (WM-DAS) with continuous wave cavity ringdown spectroscopy (CW-CRDS). This spectrometer combines the benefits of absolute concentration measurements, wide range, and high speed, using WM-DAS with enhanced noise reduction in CW-CRDS. The accurate baseline ringdown time, τ0, is calculated by the absorption peak (measured by WM-DAS) and the ringdown time containing gas absorption information (measured by CW-CRDS at the center wavelength of the spectral line). The gas concentration is obtained without measuring τ0 in real time, thus, greatly improving the measuring speed. A WM-DAS/CW-CRDS spectrometer at 1.57 μm for CO detection was assembled for experimental validation of the multiplexing scheme over a concentration ranging from 4 ppm to 1.09% (0.1 MPa, 298 K). The measured concentration of CO at 6374.406 cm−1 shows that the dynamic range of this tunable diode laser absorption spectrometer is extendable up to five orders of magnitude and the corresponding precision is improved. The measurement speed of this spectrometer can extend up to 10 ms, and the detection limit can reach 35 ppb within 25 s.

Measurement of Total Water with a Tunable Diode Laser Hygrometer: Inlet Analysis, Calibration Procedure, and Ice Water Content Determination

2007 ◽  
Vol 24 (3) ◽  
pp. 463-475 ◽  
Author(s):  
Sean M. Davis ◽  
A. Gannet Hallar ◽  
Linnea M. Avallone ◽  
William Engblom
Keyword(s):  
Particle Size ◽  
Water Vapor ◽  
Water Content ◽  
Diode Laser ◽  
Tunable Diode Laser ◽  
Calibration Data ◽  
Total Water ◽  
Wide Range ◽  
Ice Water Content ◽  
Ice Water

Abstract The University of Colorado closed-path tunable diode laser hygrometer (CLH), a new instrument for the in situ measurement of enhanced total water (eTW, the sum of water vapor and condensed water enhanced by a subisokinetic inlet), has recently been flown aboard the NASA DC-8 and WB-57F aircrafts. The CLH has the sensitivity necessary to quantify the ice water content (IWC) of extremely thin subvisual cirrus clouds (∼0.1 mg m−3), while still providing measurements over a large range of conditions typical of upper-tropospheric cirrus (up to 1 g m−3). A key feature of the CLH is its subisokinetic inlet system, which is described in detail in this paper. The enhancement and evaporation of ice particles that results from the heated subisokinetic inlet is described both analytically and based on computational fluid dynamical simulations of the flow around the aircraft. Laboratory mixtures of water vapor with an accuracy of 2%–10% (2σ) were used to calibrate the CLH over a wide range of water vapor mixing ratios (∼50–50 000 ppm) and pressures (∼100–1000 mb). The water vapor retrieval algorithm, which is based on the CLH instrument properties as well as on the spectroscopic properties of the water absorption line, accurately fits the calibration data to within the uncertainty of the calibration mixtures and instrument signal-to-noise ratio. A method for calculating cirrus IWC from the CLH enhanced total water measurement is presented. In this method, the particle enhancement factor is determined from an independent particle size distribution measurement and the size-dependent CLH inlet efficiency. It is shown that despite the potentially large uncertainty in particle size measurements, the error introduced by this method adds ∼5% error to the IWC calculation. IWC accuracy ranges from 20% at the largest IWC to 50% at small IWC (<5 mg m−3).

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