scholarly journals Pollution, Sources and Human Health Risk Assessment of Potentially Toxic Elements in Different Land Use Types under the Background of Industrial Cities

2020 ◽  
Vol 12 (5) ◽  
pp. 2121 ◽  
Author(s):  
Qing Xia ◽  
Jiquan Zhang ◽  
Yanan Chen ◽  
Qing Ma ◽  
Jingyao Peng ◽  
...  

Residents in industrial cities may be exposed to potentially toxic elements (PTEs) in soil that increase chronic disease risks. In this study, six types of PTEs (Zn, As, Cr, Ni, Cu, and Pb) in 112 surface soil samples from three land use types—industrial land, residential land, and farmland—in Tonghua City, Jilin Province were measured. The geological accumulation index and pollution load index were calculated to assess the pollution level of metal. Meanwhile, the potential ecological risk index, hazard index, and carcinogenic risk were calculated to assess the environmental risks. The spatial distribution map was determined by the ordinary kriging method, and the sources of PTEs were identified by factor analysis and cluster analysis. The average concentrations of Zn, As, Cr, Ni, Cu, and Pb were 266.57, 15.72, 72.41, 15.04, 20.52, and 16.30 mg/kg, respectively. The results of the geological accumulation index demonstrated the following: Zn pollution was present in all three land use types, As pollution in industrial land cannot be neglected, Cr pollution in farmland was higher than that in the other two land use types. The pollution load index decreased in the order of industrial land > farmland > residential land. Multivariate statistical analysis divided the six PTEs into three groups by source: Zn and As both originated from industrial activities; vehicle emissions were the main source of Pb; and Ni and Cu were derived from natural parent materials. Meanwhile, Cr was found to come from a mixture of artificial and natural sources. The soil environment in the study area faced ecological risk from moderate pollution levels mainly contributed by As. PTEs did not pose a non-carcinogenic risk to humans; however, residents of the three land use types all faced estimated carcinogenic risks caused by Cr, and As in industrial land also posed high estimated carcinogenic risk to human health. The conclusion of this article provides corresponding data support to the government’s policy formulation of remediating different types of land and preventing exposure and related environmental risks.

2021 ◽  
Author(s):  
Shirin Akter ◽  
Mohammad Obidur Rahman ◽  
Mehedi Hasan ◽  
Saiful Islam Tushar ◽  
Mottalib Hossain Sarkar ◽  
...  

Abstract The mean concentrations of heavy metals viz: K, Ca, Mg, Ti, Fe, Co, Cu, As, Zn, Rb, Sr, Zr, Pb and Th were measured in soil samples using Energy Dispersive X-ray Fluorescence (EDXRF) technique and sampling sites as a whole were found highly contaminated by Zn, considerably contaminated by Mg and Pb, while moderately contaminated by Fe, Co, Cu, Rb, Sr, As, Rb, Y, Th. The sampling sites are moderate to strongly polluted by heavy metals according to Enrichment factors value, whereas, Pollution Load Index values for 95% of the sample sites were ≥ 1.5, indicating deterioration of soil quality. Potential Ecological risk (RI) value followed the increasing sequence of Pb > As > Co > Zn > Cu. Non-carcinogenic exposure found higher in children compared to adults,however carcinogenic risk assessment revealed that both groups (adult and children) lied within Grade II category (10− 5 to 10− 6) and considered to be at no risk.


2013 ◽  
Vol 2013 ◽  
pp. 1-15 ◽  
Author(s):  
Yi Huang ◽  
Bin Xia ◽  
Lei Yang

This study attempts to discuss the relationship between land use spatial distribution structure and energy-related carbon emission intensity in Guangdong during 1996–2008. We quantized the spatial distribution structure of five land use types including agricultural land, industrial land, residential and commercial land, traffic land, and other land through applying spatial Lorenz curve and Gini coefficient. Then the corresponding energy-related carbon emissions in each type of land were calculated in the study period. Through building the reasonable regression models, we found that the concentration degree of industrial land is negatively correlated with carbon emission intensity in the long term, whereas the concentration degree is positively correlated with carbon emission intensity in agricultural land, residential and commercial land, traffic land, and other land. The results also indicate that land use spatial distribution structure affects carbon emission intensity more intensively than energy efficiency and production efficiency do. These conclusions provide valuable reference to develop comprehensive policies for energy conservation and carbon emission reduction in a new perspective.


Author(s):  
Abinotami Williams Ebuete ◽  
Andy Etta Bisong ◽  
Okereke Chukuma ◽  
Lucky E. Ndiwari ◽  
Ibim Yarwamara Ebuete

The Kolo Creek is an inland water body in the Niger Delta receiving organic and chemical wastes arising from anthropogenic activities within the catchment area. This study was therefore carried out to investigate the spatial variabilities of heavy metals in surface and sediment and their geochemical factors that influence their presence along the Kolo Creek in 2018 using Geo-accumulation index and pollution load index to extrapolate the level of heavy metal contraction in the two medium. Sediment and Water samples were collected for five (5) months and assessed from eight sampling points (A-h) for seven (7) heavy metals such as  Copper (Cu), Lead (Pb), Iron(Fe), Camium (Cd), Manganese (Mn), Nickel (Ni) and Mercury (Hg). All the heavy metals had geo-accumulation indices below zero which indicates no pollution except Fe which had geo-accumulation index in the range 3.327 in surface water and 7.751 in sediment, furthermore, the pollution load index revealed a toxicity of 0.664 times in surface water as against 1.501 times in sediment exceeding the background concentration in the Kolo Creek. Hence, poor ecological ethics and culture should be discouraged to keep the Kolo Creek water under check for safe domestic water use.


Author(s):  
Yixuan Liu ◽  
Shanshan Li ◽  
Chunyuan Sun ◽  
Mengxi Qi ◽  
Xue Yu ◽  
...  

In order to assess the pollution levels and health risks of PM2.5-bound metals in Baoding City before and after the heating period, samples were collected in 2016 at Hebei University from September 25th to November 14th during the non-heating period, and November 15th to December 26th during the heating period, respectively. ICP-MS was applied to analyze seven heavy metals (Cr, Zn, Cu, Pb, Ni, Cd and Fe). The statistical analysis, enrichment factor (EF), pollution load index method, and Risk Assessment Method proposed by U.S. EPA were used to evaluate the non-carcinogenic risks of six of these heavy metals (Cr, Zn, Cu, Pb, Ni and Cd) and carcinogenic risks of three of these heavy metals (Cr, Ni and Cd). The results showed three main results. First, the average daily PM2.5 concentrations of the national air monitoring stations was 155.66 μg·m−3 which was 2.08 times as high as that of the second level criterion in China (75 μg·m−3) during the observation period. Compared with the non-heating period, all heavy metals concentrations increased during heating period. The growth rates of Pb and Ni were the highest and the lowest, which were 88.03 and 5.11 percent, respectively. Second, the results of enrichment factor indicated that the EF values of all heavy metals were higher during the heating period in comparison with during the non-heating period, but the degree of enrichment of all heavy metals remained unchanged. Not only those, Cr and Ni were minimally enriched and were affected by both human and natural factors, Pb, Cu and Zn were significantly enriched and were mainly affected by human factors, the enrichment of Cd was much higher than that of the other heavy metals, exhibiting extremely high enrichment, mainly due to human factors during the whole sampling period. The results of the pollution load index indicated that the proportions of the number of highly and very highly polluted PM2.5-bound metals were the highest during the heating period, while the proportion of moderately polluted PM2.5-bound metals was the highest during the non-heating period. The combined pollution degree of heavy metals was more serious during the heating period. Third, according to the health risk assessment model, we concluded that the non-carcinogenic and carcinogenic risks caused by inhalation exposure were the highest and by dermal exposure were the lowest for all kinds of people. The overall non-carcinogenic risk of heavy metals via inhalation and subsequent ingestion exposure caused significant harm to children during the non-heating and the heating periods, and the risk values were 2.64, 4.47, 1.20 and 1.47, respectively. Pb and Cr exhibited the biggest contributions to the non-carcinogenic risk. All the above non-carcinogenic risks exceeded the standard limits suggested by EPA (HI or HQ < 1). The carcinogenic risk via inhalation exposure to children, adult men and women were 2.10 × 10−4, 1.80 × 10−4, and 1.03 × 10−4 during the non-heating period, respectively, and 2.52 × 10−4, 2.16 × 10−4 and 1.23 × 10−4 during the heating period, respectively. All the above carcinogenic risks exceeded the threshold ranges (10−6~10−4), and Cr posed a carcinogenic risk to all people.


2018 ◽  
Vol 34 ◽  
pp. 02018
Author(s):  
A.A. Ahmad Zubir ◽  
F.N. Mohd Saad ◽  
F.A. Dahalan

The contamination of heavy metals gives bad implications to the aquatic environment. Thus, a study was conducted to assess the sediment quality by using different contamination indices such as Enrichment Factor (EF), Geo-accumulation Index (Igeo), and Pollution Load Index (PLI). Each sediment sample was collected at the surface (0-15cm) at 5 locations based on the land use activity; jetty port (A), seaside restaurant (B), roadside area (C), power plant (D) and residential area (E). All samples were undergoes acid digestion and analyzed with AAS. Four elements identified from the sediment samples which are Cr, Cu, Pb and Zn were used to calculate the respective indices. Results show that, the highest EF value of Pb which categorized as very severe enrichment was at point E. Meanwhile minor enrichment was detected at point B for Cu while Cr and Zn at point A. Based on Igeo value the sediment quality along Kuala Perlis was in the unpolluted-moderately polluted condition (class 1). As for PLI it shows that the sediment of the coastal area is unpolluted (PLI<1). Therefore, this study revealed that, the main contributor of heavy metals in this area is Pb while the sediment quality of Kuala Perlis was in minor pollution condition.


2016 ◽  
Vol 10 (3) ◽  
pp. 41-46
Author(s):  
Soheil Sobhanardakani ◽  
◽  
Mehrnaz Ghoochian ◽  

Background: Soil and sediment serve as major reservoir for contaminants as they possess ability to bind various chemicals together. In this study the concentrations of heavy metals Cd, Cr and Cu were analyzed in surface sediments of Agh Gel Wetland in west of Iran. Methods: The sediment samples were taken from 10 stations. The samples were subjected to bulk digestion and chemical partitioning and Cd, Cr and Cu concentrations of the sediments were determined by ICP-OES. Geo-accumulation index (I-geo), Contamination factor (CF) and Pollution load index (PLI) were used to evaluate the magnitude of contaminants in the sediment profile. Results: The mean sediment concentrations (mg kg-1 dry weight) ranged within 0.20-0.29 (Cd), 58-71 (Cr) and 23-36 (Cu). According to the I-geo values, the sediments' qualities are classified as unpolluted to moderately polluted category. According to the CF values, the sediments' qualities are classified as low to moderate contamination. Furthermore, the PLI values indicated that there were no metal pollution exists for all sampling stations. Conclusion: The Agh Gel Wetland is potential to be threatened by chemical pollutants such as agricultural effluent. So to preserve the environment of the Agh Gel Wetland from deterioration, periodically monitoring of the water and sediment qualities is recommended.


Toxics ◽  
2020 ◽  
Vol 8 (3) ◽  
pp. 77
Author(s):  
Long Ma ◽  
Jilili Abuduwaili ◽  
Wen Liu

Aiming at the pollution and ecological hazards of the lake sediments of Bosten Lake, once China’s largest inland lake, the spatial distribution and influencing factors of the potentially-toxic elements in its surface sediments were studied with the methods of spatial autocorrelation, two-way cluster analysis, and redundancy analysis. Finally, based on the background value of potentially-toxic elements extracted from a sediment core, a comprehensive evaluation of the risk of these potentially-toxic elements was conducted with the potential-ecological-risk index and the pollution-load index. With data on the grain size, bulk-rock composition, and organic matter content, this comprehensive analysis suggested that with the enrichment of authigenic carbonate minerals, the content of potentially-toxic elements exhibited distinctive characteristics representative of arid regions with lower values than those in humid region. All potentially-toxic elements revealed a significant spatial autocorrelation, and high-value areas mainly occurred in the middle and southwest. The content of potentially-toxic elements is related to Al2O3, K2O, Fe2O3, TiO2, MgO, and MnO, and the storage medium of potentially-toxic elements mainly consists of small particles with a grain size <16 μm. The pollution load index (PLI) for the whole lake due to the potentially-toxic elements was 1.31, and the surface area with a PLI higher than 1 and a moderate pollution level accounted for 87.2% of the total lake area. The research conclusions have an important scientific value for future lake ecological quality assessment and lake environment governance.


2019 ◽  
Vol 1 ◽  
pp. 186-195
Author(s):  
A A Tyovenda ◽  
S I Ikpughul ◽  
T Sombo

Heavy metal pollution of water, sediments and Algae in the upper region of River Benue at Jimeta-Yola, Adamawa state, Nigeria was assessed. The concentrations of the heavy metals (Pb, Hg, Ni, Cu, Cr, Zn, Mn, Fe) in the samples were analyzed using Atomic Adsorption Spectrometer. Pollution parameters such as enrichment factor, contamination factor, pollution load index and geo-accumulation index were evaluated. The result of heavy metal analysis showed that, the concentration (ppm) of the metals in water samples ranged as follows: Pb(0.25-0.50), Hg(0.00-2.00), Ni(0.10-0.31), Cu(0.03-0.13), Cr(0.00-1.33), Zn(0.01-0.04), Mn(0.03-0.06) and Fe(105.15-118.75) respectively. This result when compared with the EPA maximum permissible limits for drinking water showed that, all the metals except Cu and Zn had values above the permissible limits. The evaluation of enrichment factor revealed that, Hg showed extremely high enrichment while Pb showed significant enrichment for Algae, water and sediment samples. The contamination factor showed low contamination for all metals except Hg which showed considerable contamination for sediments, water and Algae samples. The pollution load index for sediments, water and Algae indicated no pollution. The geo-accumulation index of the metals in sediments, water and Algae indicates no or minimal pollution. The samples were enriched with Hg and Pb. These metals are capable of causing various types of cancer, brain and kidney damage among other ailments.


DEPIK ◽  
2020 ◽  
Vol 9 (3) ◽  
pp. 403-410
Author(s):  
Edward Edward

Contamination and pollution of heavy metals in the bottom sediment can pose serious issues to marine organisms and human health. Jakarta Bay which is located adjacent to the capital city of Indonesia is notorious for its pollution problems. The purpose of this research was to assest the contamination levels of heavy metals Hg, Pb, and Cd in sea-bottom sediments based on an index analysis approach (contamination factors, geo accumulation index, pollution load index). Sediment samples were collected from 31 stations in Jakarta Bay. Heavy metal concentration was measured using Atomic Absorption Spectrophotometer (AAS). The results showed that an average mercury (Hg) concentration ranged from 0.150 to 0.530 µg.g-1 with an total average of 0.362 µg.g-1, Lead (Pb) from 14.870 to 35.650 µg.g-1 with an total average of 21.774 µg.g-1, Cadmium (Cd) 0.110-0.280 µg.g-1 with an total average of 0.190 µg.g-1.The average concentration of Hg, Pb, and Cd is still lower than the sediment quality threshold values set by the Office of the State Minister of Environment of Indonesia  2010. The results of the index analysis showed that the average value of contamination factor (CF) are Hg 0.685, Pb 0.558, and Cd 0.380 respectively (low contamination) and geo accumulation index values are Hg 0.237, Pb -1.655, and Cd 0.069 respectively (unpolluted to moderate polluted). Overall, based on the pollution load index value is -0,511 (PLI 1), sediments in these waters are categorized as not yet polluted by Hg, Pb and Cd. This situation  is so necessary to be maintained, that in order for the preservation of marine resources will remain.Keywords: Jakarta Bay, sediment, pollution, heavy metals, assessmentABSTRAKKontaminasi dan pencemaran logam berat pada sedimen dasar dapat menimbulkan masalah yang serius bagi biota laut dan kesehatan manusia. Teluk Jakarta yang terletak berdekatan dengan ibu kota Indonesia terkenal karena masalah pencemarannya yang parah. Tujuan penelitian ini adalah untuk menilai tingkat kontaminasi logam berat Hg, Pb dan Cd dalam sedimen dasar laut berdasarkan pendekatan analisis indeks. Contoh sedimen diambil dari 31 stasiun penelitian di Teluk Jakarta. Kadar logam berat diukur dengan alat Spektrofometer Penyerapan Atom. Hasil penelitian menunjukkan kadar Hg rerata berkisar 0,150-0,530 µg. g-1 dengan rerata total 0,362 µg. g-1, Timbal (Pb) 14,870-35,650 µg. g-1 dengan rerata total 21,774 µg. g-1, Kadmium (Cd) 0,110-0,280 µg. g-1 dengan rerata total 0,190 µg.g-1. Kadar rerata Hg, Pb dan Cd masih lebih rendah dari nilai ambang batas kualitas sedimen yang ditetapkan oleh Kantor Menteri Negara Lingkungan Hidup Indonesia 2010. Hasil analisis indeks menunjukkan nilai rerata faktor kontaminasi (CF) berturut-turut adalah Hg 0,685, Pb 0,352 dan Cd 0,380 (kontaminasi rendah) dan nilai indeks geo akumulasi berturut-turut adalah Hg 0,227, Pb 1,098 dan Cd 0,633 (tidak tercemar sampai tercemar sedang). Secara keseluruhan, berdasarkan nilai indeks beban pencemaran yakni -3.772 (PLI 1), sedimen di perairan ini termasuk kategori belum tercemar oleh Hg, Pb dan Cd. Keadaan ini perlu dipertahankan, agar kelestarian sumberdaya laut tetap terjaga.Kata kunci: Teluk Jakarta, sedimen, pencemaran, logam berat, penilaian


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