scholarly journals Improving Storage Stability and Physicochemical Performance of Styrene-Butadiene-Styrene Asphalt Binder Modified with Nanosilica

2020 ◽  
Vol 12 (21) ◽  
pp. 8968
Author(s):  
Nonde Lushinga ◽  
Liping Cao ◽  
Zejiao Dong ◽  
Cyriaque O. Assogba
Keyword(s):  
Storage Stability ◽  
Storage Temperature ◽  
Asphalt Binder ◽  
Fatigue Cracking ◽  
Proton Nuclear Magnetic Resonance ◽  
Creep Recovery ◽  
Modified Binders ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Due to storage stability drawbacks of polymer-modified bitumen (PMB), this study investigated the storage stability and physicochemical performance of Styrene-Butadiene-Styrene (SBS) asphalt binders (herein PMB) modified with Silicone surface-treated nanosilica (SNS). Dosages 0% (control), 1.5%, 3% and 5% SNS powder were added to PMB to prepare modified binders. Hot storage, Viscosity, Multiple Stress Creep Recovery (MSCR), Scanning Electron Microscopy (SEM), Fluorescence Microscopy (FM), Linear Amplitude Sweep (LAS), Fourier Transform Infrared (FTIR), and Proton Nuclear Magnetic Resonance (1H-NMR) tests were conducted using modified binders. The study found that adding nanosilica powder to PMB improved storage stability, increased viscosity and complex modulus, and reduced rutting of binders. However, this bitumen modification was not beneficial to fatigue cracking. The performance improvement was because of the interaction between the polymer and nanosilica, creating a new polymer-nanosilica network which lowered the dynamics around the SNS particles, thereby reducing phase separation. Further, the Silicone Si–O–Si backbone bond present in SNS modified asphalt binder reduced temperature sensitivity thereby preventing thermal degradation at high storage temperature. Nanosilica modified binders presented well-dispersed nanosilica particles in the asphalt matrix. The modification mechanism was predominantly physical. Overall, the study concluded that nanosilica improves storage stability, rutting, and morphology of PMB binders.

Compatibility and Storage Stability of Asphalt Binder Modified by Styrene-Butadiene-Styrene (SBS) Graft Copolymer

2021 ◽  
Vol 1036 ◽  
pp. 459-470
Author(s):  
Hong Gang Zhang ◽  
Qiang Huai Zhang ◽  
Xue Ting Wang ◽  
Hua Tan ◽  
Li Ning Gao ◽  
...  
Keyword(s):  
Triblock Copolymer ◽  
Storage Stability ◽  
Asphalt Binder ◽  
Solubility Parameters ◽  
Suitable Alternative ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
Butadiene Styrene

A styrene-butadiene-styrene triblock copolymer (SBS) was grafted with an unsaturated polar monomer (monomer A) composed of maleic anhydride (MAH) and methoxy polyethylene (MPEG) via a ring-opening reaction after epoxidizing styrene-butadiene-styrene triblock copolymer (ESBS). The microscopic changes of SBS before and after grafting has been characterized with Fourier transform infrared spectrum (FT-IR), X-ray photoelectron spectroscopy (XPS) and gel permeation chromatography (GPC). The results revealed that the monomer A was successfully grafted on SBS backbone, and the maximum graft ratio (GR) was 20.32%. To verify the compatibility between SBS and asphalt, solubility parameters and surface free energy (SFE) of SBS, grafted SBS and asphalt were measured. It was found that the solubility parameter and SFE of grafted SBS were closer to asphalt compared with SBS. It also has been confirmed from storage stability that the temperature susceptibility of grafted SBS modified asphalt was reduced in compare with SBS modified asphalt binder. As consequence, the use of grafted copolymer can be considered a suitable alternative for modification of asphalt binder in pavement.

scholarly journals Effect of Gilsonite Use on Storage Stability of Styrene-butadiene-styrene Modified Bitumen

2019 ◽  
Author(s):  
Erkut Yalcın ◽  
Muhammed Ertuğrul Çeloğlu ◽  
Mustafa Akpolat ◽  
Özge Erdoğan Yamaç ◽  
Taner Alataş ◽  
...  
Keyword(s):  
Storage Stability ◽  
Performance Level ◽  
Asphalt Pavements ◽  
Modified Bitumen ◽  
Rotational Viscometer ◽  
Rich Phase ◽  
Modified Binders ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Styrene-butadiene-styrene (SBS) polymer is one of the most preferred additives to improve performance in hot mix asphalt pavements. The storage instability, in other words, the separation of a polymer-rich phase from the bitumen-rich phase in the course of storage and transportation is one of the prevalent problems in SBS modified bitumen. The present study attempted to obtain modified bitumen at the same performance level with the SBS modified bitumen, but stable with respect to the storage stability. For this purpose, both SBS and American Gilsonite (AG) were used in modified bitumen production. It was determined that modified bitumen at the same performance level was obtained with the use of 5 % SBS or 18 % AG in bitumen modification. It was also determined that the performance levels of the modified bitumen obtained with the use of 2 % SBS + 13 % AG, 3 % SBS + 10 % AG and 4 % SBS + 6 % AG were similar. Additionally, 2 %, 3 % and 4 % SBS modified bitumen were used for the assessment of storage stability properties of the SBS modified binders. These 8 different modified bitumen samples were tested for storage stability based on the EN 13399 standard. Penetration, softening point, rotational viscometer, bending beam rheometer, and dynamic shear rheometer tests were conducted on the samples. Based on all conducted tests, it was determined that more stable binders were obtained with the use of AG and SBS in terms of storage stability compared to solely SBS modified bitumen.

scholarly journals Evaluating the Physical and Rheological Properties of Rejuvenated Styrene-Butadiene-Styrene-Modified Asphalt Binders

2020 ◽  
Vol 2020 ◽  
pp. 1-14
Author(s):  
Xiaobing Chen ◽  
Juntian Wang ◽  
Xiaorui Zhang ◽  
Han Liu ◽  
Jinhu Tong ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Fatigue Cracking ◽  
Creep Recovery ◽  
Optimal Dosage ◽  
Type I ◽  
Yield Strain ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

To evaluate the physical and rheological properties of rejuvenated styrene-butadiene-styrene-modified asphalt (SBSMA) binders designed for rapid in-place pavement recycling, an aged SBSMA binder was rejuvenated with three rejuvenators (i.e., Types I, II, and III) in different dosages. The physical properties of rejuvenated SBSMA were obtained to determine the optimal type and dosage of rejuvenators for the first and second rejuvenation. Performance grade (PG) tests, multiple stress creep recovery (MSCR) tests, and linear amplitude sweep (LAS) tests were conducted to measure the rheological properties using the dynamic shear rheometer (DSR) and bending beam rheometer (BBR). The results exhibited that the rejuvenators could soften the multiple aged binder and enhance its high- and low-temperature performance. The rejuvenation effect of rejuvenator Type I with the optimal dosage of 6∼8% was the most appropriate for the first rejuvenation. The optimal dosage of the second rejuvenation was 10∼12%. The addition of rejuvenators decreased the rutting factor G∗/sin δ, creep stiffness (S), delta Tc (ΔTc) parameter, recovery response (R), and yield stress of rejuvenated SBSMA. On the other hand, an increase in the rate of relaxation (m-value), nonrecoverable creep compliance (Jnr), and yield strain of rejuvenated SBSMA was recorded. Overall, the study findings indicated an improvement in the elastic properties of rejuvenated SBSMA, which contributes to improving the rutting, thermal, and fatigue cracking resistance of asphalt binder and ultimately the response of asphalt pavements.

The effects of base binder and styrene–butadiene–styrene structure on rutting resistance of polymer–nanocomposite asphalt mixture

2017 ◽  
Vol 50 (3) ◽  
pp. 256-275 ◽  
Author(s):  
Mahdi Delaviz Bayekolaei ◽  
Koorosh Naderi ◽  
Fereidoon Moghadas Nejad
Keyword(s):  
Asphalt Mixture ◽  
Polymer Nanocomposite ◽  
Asphalt Mixtures ◽  
Asphalt Binders ◽  
Rutting Resistance ◽  
Modified Asphalt ◽  
Modified Binders ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

In recent years, the use of nano materials for improving various mechanical and performance-related properties of polymer-modified asphalt binders has been growing rapidly. However, few researches investigated the effects of base binder and styrene–butadiene–styrene (SBS) structure on rutting resistance of polymer-nanocomposite-modified asphalt mixtures. This study investigated the effect of polymer–nanocomposite modification, using two different penetration grade asphalt binders and two types of SBS, on rutting properties of asphalt mixtures. Rheological properties of modified binders, Marshall stability, resilient modulus, and rut depth in wheel-tracking tests were used to evaluate the rutting performance of the modified binders and mixtures. The results indicated that both base binder type and SBS structure had significant effect on rutting resistance of polymer-nanocomposite-modified asphalt mixtures.

scholarly journals Study on Styrene-Butadiene-Styrene Modified Asphalt Binders Relaxation at Low Temperature

Materials ◽  
2021 ◽  
Vol 14 (11) ◽  
pp. 2888
Author(s):  
Sylwia Dziadosz ◽  
Mieczysław Słowik ◽  
Filip Niwczyk ◽  
Marcin Bilski
Keyword(s):  
Low Temperature ◽  
Force Measurement ◽  
Asphalt Binder ◽  
Asphalt Binders ◽  
Short Term ◽  
Modified Bitumen ◽  
Modified Asphalt ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

The paper presents the results of laboratory investigation on asphalt binders relaxation at low temperature, carried out in a ductilometer using the tensile test with continuous force measurement. Polymer modified asphalt binder samples consisting of a 50/70 penetration grade bitumen mixed with a concentrate of styrene-butadiene-styrene (SBS) modified bitumen—a 160/220 penetration grade bitumen modified with a SBS copolymer in the amount of 9%—were tested. Therefore, polymer modified binders containing 3%, 4.5%, 6% and 7.5% SBS, respectively, were obtained and investigated. Tensile tests were performed at −16 °C on samples before aging and subjected to short-term aging (RTFOT). Test results in the form of relaxation curves have been mathematically described using a modified generalized Maxwell model. Based on the acquired results, it was shown that the increase of the SBS copolymer content in asphalt binder precipitates the relaxation process, while aging slows down this phenomenon. It has also been proven that with increased content of SBS elastomer in asphalt binder, the effect of short-term aging on binder’s stress relaxation ability at low temperatures is reduced.

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