scholarly journals Outstanding Graphene Quantum Dots from Carbon Source for Biomedical and Corrosion Inhibition Applications: A Review

2021 ◽  
Vol 13 (4) ◽  
pp. 2127 ◽  
Author(s):  
Badreah Ali Al Jahdaly ◽  
Mohamed Farouk Elsadek ◽  
Badreldin Mohamed Ahmed ◽  
Mohamed Fawzy Farahat ◽  
Mohamed M. Taher ◽  
...  

Graphene quantum dots (GQD) is an efficient nanomaterial composed of one or more layers of graphene with unique properties that combine both graphene and carbon dots (CDs). It can be synthesized using carbon-rich materials as precursors, such as graphite, macromolecules polysaccharides, and fullerene. This contribution emphasizes the utilization of GQD-based materials in the fields of sensing, bioimaging, energy storage, and corrosion inhibitors. Inspired by these numerous applications, various synthetic approaches have been developed to design and fabricate GQD, particularly bottom-up and top-down processes. In this context, the prime goal of this review is to emphasize possible eco-friendly and sustainable methodologies that have been successfully employed in the fabrication of GQDs. Furthermore, the fundamental and experimental aspects associated with GQDs such as possible mechanisms, the impact of size, surface alteration, and doping with other elements, together with their technological and industrial applications have been envisaged. Till now, understanding simple photo luminance (PL) operations in GQDs is very critical as well as there are various methods derived from the optical properties of manufactured GQDs can differ. Lack of determining exact size and morphology is highly required without loss of their optical features. Finally, GQDs are promising candidates in the after-mentioned application fields.

2019 ◽  
Vol 5 (4) ◽  
Author(s):  
Sumana Kundu ◽  
Vijayamohanan K. Pillai

Abstract Conventional inorganic semiconductor quantum dots (QDs) have numerous applications ranging from energy harvesting to optoelectronic and bio-sensing devices primarily due to their unique size and shape tunable band-gap and also surface functionalization capability and consequently, have received significant interest in the last few decades. However, the high market cost of these QDs, on the order of thousands of USD/g and toxicity limit their practical utility in many industrial applications. In this context, graphene quantum dot (GQD), a nanocarbon material and a new entrant in the quantum-confined semiconductors could be a promising alternative to the conventional toxic QDs due to its potential tunability in optical and electronic properties and film processing capability for realizing many of the applications. Variation in optical as well as electronic properties as a function of size, shape, doping and functionalization would be discussed with relevant theoretical backgrounds along with available experimental results and limitations. The review deals with various methods available so far towards the synthesis of GQDs along with special emphasis on characterization techniques starting from spectroscopic, optical and microscopic techniques along with their the working principles, and advantages and limitations. Finally, we will comment on the environmental impact and toxicity limitations of these GQDs and their hybrid nanomaterials to facilitate their future prospects. Graphical Abstract: Structure of doped, functionalized and hybrid GQDs


RSC Advances ◽  
2017 ◽  
Vol 7 (76) ◽  
pp. 48263-48267 ◽  
Author(s):  
Timothy Pillar-Little ◽  
Doo Young Kim

The optical properties of top-down synthesized oxidized graphene quantum dots (ox-GQDs) and nitrogen-incorporating graphene quantum dots (N-GQDs) along a range of hydrothermal treatment temperatures were observed.


2016 ◽  
Vol 31 (4) ◽  
pp. 337 ◽  
Author(s):  
SUN Xiao-Dan ◽  
LIU Zhong-Qun ◽  
YAN Hao

2014 ◽  
Vol 35 (4) ◽  
pp. 372
Author(s):  
Yong-qiang MA ◽  
Zhen-guo WANG ◽  
Xue-li GOU ◽  
Na LI ◽  
Ya-qiang FENG ◽  
...  

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