scholarly journals An Innovative Approach to Assess the Ecotoxicological Risks of Soil Exposed to Solid Waste

2021 ◽  
Vol 13 (11) ◽  
pp. 6141
Author(s):  
Despina-Maria Bordean ◽  
Luminita Pirvulescu ◽  
Mariana-Atena Poiana ◽  
Ersilia Alexa ◽  
Antoanela Cozma ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Soil Contamination ◽  
Hazardous Waste ◽  
Ecological Risk ◽  
Contamination Factor ◽  
Soil Samples ◽  
Waste Dumps ◽  
Hazardous Waste Landfills ◽  
Illegal Waste

The adoption of sustainable waste management strategies is a challenge faced by most European countries, mainly due to the need to generate less waste and replace landfills with new methods of waste treatment, associated with increases in the separate collection of waste and recycling rates. This paper highlights the significance of environmental legislation regarding waste removal to protect ecosystems. The aim was to predict ecological responses to heavy metals in soil exposed to hazardous waste and to identify environmental hazards in landfills, small illegal waste dumps, and litter, in addition to identifying if heavy metal accumulation in the investigated soil samples showed a single or cumulative risk. This is an innovative method to predict the ecological risk generated by hazardous waste landfills. The assessment of ecological risks was based on the evaluation of a heavy metal soil contamination factor, pollution index of soil loadings, a geo-accumulation index for heavy metals, and potential ecological risk. The current study is also the first to attempt to identify the dimension of risk based on the type of waste deposit (landfill, small illegal waste dump, and litter) and to identify potential patterns. The geological index corresponding to cadmium Igeo(Cd) showed heavy contamination in the soil samples from the landfill and moderate contamination for those from the illegal waste dumps. These findings indicate that soil contamination is influenced by contamination time, anthropogenic processes, and a history of industrial activity, and not only by waste composition and storage. The present study shows that cadmium might be considered a latent fingerprint for waste disposal, which is correlated to the industrialization level and rehabilitation procedures.

scholarly journals Industrial Activities and Heavy Metal Pollution: Assessment of Concentration of Zn, Cu, Cd Cr and, Pb in Soil Samples around Dangote Cement Factory Kogi State, Nigeria

2020 ◽  
pp. 75-86
Author(s):  
Sani Daniel Eneji ◽  
Matthew Chijioke Apeh ◽  
Enyojo Samson Okwute ◽  
Alowakennu Micheal ◽  
Kayode Ibrahim Fesomade
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Ecological Risk ◽  
Contamination Factor ◽  
Pollution Assessment ◽  
Soil Samples ◽  
Industrial Activities ◽  
Cement Factory ◽  
The Relationship ◽  
Geo Accumulation

This study aims at determining the concentration of heavy metal contaminants in the soil around Dangote cement factory Kogi State, Nigeria. It also seeks to understand the relationship between the heavy metals and the level of concentration with respect to distance and direction as well as the ecological risk it poses. The monitoring and assessment of soil pollution have over the years become a very important area of study due to the significant threat it poses to the food web. A total of 33 soil samples were collected in the Northern, Eastern and Western axis within a radius of 4km of Dangote cement factory at a depth of 0-15cm using a stainless steel auger. The contamination factor indices for Cr and Cu show moderate pollution across all the samples collected from different axis at a different distance from the factory. Zn also pose a moderate pollution across the samples except for WK4 and NK4 where it is in a low level of contamination. The geo-accumulation indices for Pb and Cr show unpolluted to moderately polluted across all samples at different locations expect for sample location EK4. The results of the ecological risk assessment revealed that Cd poses the highest ecological risk of all the five heavy metals investigated.

scholarly journals Status of soil heavy metals contamination using contamination indices in shallot fields

2021 ◽  
Vol 306 ◽  
pp. 04013
Author(s):  
Triyani Dewi ◽  
Edhi Martono ◽  
Eko Hanudin ◽  
Rika Harini
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Contamination ◽  
Contamination Factor ◽  
Soil Samples ◽  
Limit Values ◽  
Central Java ◽  
Contamination Indices ◽  
Heavy Metals Contamination ◽  
The Status

Monitoring and assessment of heavy metal concentrations in shallot fields are needed to evaluate the potential risk of contamination due to heavy metals. This study aims to define the status of heavy metal contamination in shallot fields using contamination indices. A total of 184 soil samples (0-20 cm) were taken from shallot fields in Brebes Regency, Central Java. The soil samples were analyzed for the concentration of five heavy metals (Cd, Pb, Ni, Cr, and Co) with HNO3 and HClO4 extracts and measured using AAS. Assessment of the status of heavy metals contamination in the soil using contaminant factor (CF), geo-accumulation index (I-geo), and pollution load index (PLI). The mean concentration in shallot fields showed the following order Cr > Ni > Pb > Co > Cd and the concentration were still below critical limit values. Four metals are Pb, Cr, Co, and Ni are low contamination (CF<1), while Cd is considerable until very high contamination factor. Based on I-geo values, shallot fields are practically uncontaminated of Pb, Co, Ni, and Cr (I-geo<1), meanwhile the status of Cd is uncontaminated to moderately contaminated (0<I-geo<1). Generally, the shallot fields in Brebes Regency, Central Java is unpolluted with five metals (PLI<1).

scholarly journals APPLICATION OF SOME SINGLE AND INTEGRATED INDEX EQUATION TO ASSESS HEAVY METAL IN DIFFERENT SOILS IN ERBIL GOVERNORATE

2021 ◽  
Vol 52 (4) ◽  
pp. 868-875
Author(s):  
Aweez & et al.
Keyword(s):  
Heavy Metal ◽  
Risk Factor ◽  
Ecological Risk ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Soil Samples ◽  
Degree Of Contamination ◽  
Integrated Index ◽  
Very High ◽  
Cu And Zn

The aim of this study was to application of some single and integrated index equation to assess heavy metal in different soil within Erbil governorate. The 15 different locations (Bahare new, Newroz, New Hawler, Hesarok, Azadi1, Zen city, Atconz city, Pank village, Binaslawa, Darato, Qushtapa, Shaways, Kasnazan, Bahirka, Pirzin) were specifically selected to identify the effects of traffic activities on soil properties. Different heavy metal distribution patterns (As, Cd, Cu, Cr and Zn) were determined from distance 5, 25, 50m roadside. Soil pollution was assessed using many indices including: contamination factor (CF), degree of contamination (Cdeg), Ecological Risk Factor and Potential Ecological Risk Index.The results showed that concentrations of As, Cd, Cr, Cu, and Zn in street dust ranged from (4.60, 1.80, 217.83, 62.14 and 215.18) mg.kg-1 which recorded in Qushtapa, Kasnazan, Atconze city, Hasarok5 and Zen city respectively. The contamination factor  and degree of contamination of  the trace elements As, Cd, Cr, Cu ,and Zn of soil samples was indicating considerable contamination factor for Qushtapa moderate contamination factor for Kasnazan, while Atconze city, Hasarok5, Zen city showed very high contamination factor, while degree of contamination considerable low degree of contamination. According to the ecological risk factor and RI results Qwshtapa was indicate as low potential ecological risk, Kasnazan had moderate potential ecological risk while Hasarok5 and Zen city considerable high potential ecological risk, except Atconze considerable very high ecological risk, on the other hand for RI index shown considerable very high ecological risk recorded in Hasarok 5 soil samples.

scholarly journals Evaluation and Ecological Risk Assessment of Selected Heavy Metal Pollution of Soils and Amaranthus cruentus and Telfairia occidentalis Grown Around Dump Site in Chanchaga Minna, Niger State, Nigeria

2019 ◽  
pp. 1-16 ◽  
Author(s):  
Oguh C. Egwu ◽  
Uzoefuna C. Casmir ◽  
Ugwu C. Victor ◽  
Ubani C. Samuel ◽  
Musa A. Dickson ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Heavy Metal ◽  
Ecological Risk ◽  
Control Site ◽  
Soil Samples ◽  
Amaranthus Cruentus ◽  
Dump Site ◽  
Telfairia Occidentalis ◽  
Heavy Metals In Soils

The study investigate a series of selected heavy metal pollution of soil, the extent of their uptake by Telfairia occidentalis and Amaranthus cruentus as well as their ecological risk around dumpsite in Chanchaga Minna, Niger State, Nigeria. Soil samples were collected at 15 cm depth with the aid of soil auger and vegetable samples were collected from dumpsite and other samples with no activities served as control. The soil samples were collected at random and their physicochemical parameters such as pH, total nitrogen, total phosphorus, organic matter, total carbon and exchangeable cations (i.e., K+, Mg2+ and Na+) using a standard method and concentrations of the heavy metals in soils and vegetables, As, Cd, Cr, Cu, Hg and Pb were analyzed using flame Atomic Absorption Spectrometer (AAS). The ecological health risk assessment from the consumption of these vegetables was calculated using standard methods. The result showed a significant (p-value) increase of AC and TO in test soil samples relative to the control soils. The pH of the soil in dumpsite and control site was 5.93, and 7.35 respectively. Mean concentrations of As, Cd, Cr, Cu, Hg and Pb in the dump site were 6.35, 4.84, 6.67, 7.35, 5.72 and 4.96 mg/kg while the control site were 1.18, 0.28, 1.26, 6.83, 1.19 and 3.54 mg/kg respectively which was below the WHO/FAO limits of As (20), Cd (3.0), Cr (100), Cu (100), Hg (2.00) and Pb (50 mg/kg) for soil. The concentrations of As, Cd, Cr, Cu, Hg and Pb recorded in AC dump site were As (6.13), Cd (3.67), Cr (5.37), Cu (4.28), Hg (3.46), and Pb (4.52) and in TO As (5.67), Cd (3.13), Cr (4.67), Cu (3.65), Hg (3.19) and Pb (4.27 mg/kg) which were above the WHO/FAO permissible limits (0.5, 0.20, 0.3, 3.0, 0.1 and 0.3 mg/kg) respectively for edible vegetable. The concentrations of heavy metals in soils and vegetables from the dumpsite soil were significant (p < 0.05) from the controls. The bioaccumulation factor (BAF) for the vegetable showed that they exclude the element from soil. The Hazard Quotient (HQ) and Hazard index (HI) show that there is no harmful effect since the values obtain were not greater than >1. But continuous consumption can accumulate in the food chain especially for children. This study showed that the soils and vegetables within the vicinity of the dumpsites were polluted by heavy metals which can pose health risk. The study also calls for proper waste management practices and policy implementation.

scholarly journals Heavy Metals in Agricultural Soils of National Capital Region, Delhi: Levels and Ecological Risk

2021 ◽  
Vol 16 (3) ◽  
pp. 804-817
Author(s):  
Jyoti Rani ◽  
Tripti Agarwal ◽  
Sudesh Chaudhary
Keyword(s):  
Heavy Metals ◽  
Organic Carbon ◽  
Ecological Risk ◽  
Agricultural Soils ◽  
Contamination Factor ◽  
Soil Samples ◽  
National Capital Region ◽  
Capital Region ◽  
National Capital ◽  
Irrigated Soils

This study was conducted to assess heavy metals concentrations in agricultural soils in the National Capital Region, Delhi. A total of 84 soil samples were collected from selected agricultural areas located near industries, national highways, state highways, Yamuna floodplain, residential complexes, and wastewater irrigated soils. Heavy metal concentrations, pH, and organic carbon (%) were analyzed in the collected soil samples. The average value of pH, and organic carbon (%) in the soil samples were 7.79±0.49 and 0.53±0.17 percent respectively. Average concentrations of heavy metals (mg kg-1) in the agricultural soils were found in the order of Fe > Al > Mn > Zn > Ni > Cr > Cu > Pb > Co > Cd with value as 14916.92, 13538.87, 277.16, 74.53, 35.34, 33.68, 22.94, 18.45, 1.88, and 0.92 . The concentrations of Zn, Ni, and Mn reported in the present study were several times higher than their concentration in Indian natural background soils. A significant potential ecological risk has been noticed in nearly all the agricultural soil samples except for the samples collected nearby residential areas. The contamination factor has shown that most of the soil samples were moderately contaminated with Mn, Ni, Fe, and Cr and some soil samples were considerably to strongly contaminated with Zn, Pb, Cd, and Ni. Wastewater irrigated soils showed a moderate to a strong degree of accumulation of Zn, Cd, and Ni.

scholarly journals Evaluation of heavy metals in agricultural soils from Katsina state Nigeria

2020 ◽  
Vol 8 (2) ◽  
Author(s):  
Aliyu Ibrahim Yaradua ◽  
Adamu Jibrin Alhassan ◽  
Abdullahi Nasir ◽  
Kabir Ibrahim Matazu ◽  
Aminu Usman ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Enrichment Factor ◽  
Agricultural Soil ◽  
Agricultural Soils ◽  
Sampling Site ◽  
Contamination Factor ◽  
Pollution Load Index ◽  
Soil Samples ◽  
Pollution Load

This work contributes to the monitoring of Agricultural soil pollution in Katsina State, North western Nigeria by assessing the degree of heavy metal pollution in Agricultural soil samples. The study was conducted in the year 2017 within some catchment areas located within the 3 senatorial zones that constitute to make up the state (Katsina senatorial zone: Birchi, Dutsinma and Katsina; Daura senatorial zone: Daura, Ingawa and Zango; Funtua senatorial zone: Dabai, Funtua, Kafur, Malunfashi and Matazu).  Analysis for the concentration of these heavy metals; Cr, Cd, Fe, Ni, Mn, Pb and Zn was conducted by the use of AAS (by Atomic Absorption Spectrophotometry) method. . Several indices were used to assess the metal contamination levels in the Agricultural soil samples, namely; Geo-accumulation Index (Igeo), Enrichment Factor (EF), Contamination Factor (CF), Degree of Contamination (Cd) and Pollution Load Index (PLI). The result of this study has shown that generally among the heavy metals evaluated, the highest concentration was observed for Fe (range: 20.195-38.347 ppm), followed by Zn (range: 0.528-1.134 ppm), Pb (range: 0.256-0.627 ppm), Mn (range: 0.261-0.572 ppm) and Cr (range: 0.093-0.344 ppm). While Cd has the lowest concentration (range: 0.022-0.043 ppm). For all the site sampled the heavy metal Ni was below detection level (BDL). From the results of heavy metals I-geo values, according to Muller’s classification,  soil samples from Birchi, Daura, Dutsinma, Kafur and Zango were unpolluted (class 0) while soil samples from Dabai, Funtua, Ingawa, Katsina, Malunfashi and Matazu are moderately polluted (class 1). The result for the enrichment factor has shown that with the exception of the heavy metal Fe, which shows significant enrichment for all the sites sampled all the other heavy metals show deficiency to minimal enrichment. Also based on the contamination factors for all soil samples the heavy metal Fe has a CF values range of 1.2861-2.3240, indicating that the Agricultural soil samples are moderately contaminated with Fe. In contrast, the rest of the heavy metals exhibit low contamination in general. The value of PLI ranges from 0.2408 to 0.4935, indicating unpolluted to moderate pollution, with the sampling site for Katsina displaying the highest PLI value while the sampling site of Ingawa has the lowest PLI. The Eri values for all samples are all < 40, presenting low ecological risk.  The results suggest that the Agricultural soils samples from Katsina state has low contamination by the heavy metals evaluated.Key words: Agricultural soils, Heavy metals, Katsina state, Pollution load index, Contamination factor.

scholarly journals Soil Contamination Assessment by Trace Elements in Barapukuria Coal Mine Region, Bangladesh

2021 ◽  
Vol 8 (1) ◽  
pp. 1-10
Author(s):  
Subrota Kumar Saha ◽  
Md. Yousuf Gazi ◽  
Mahir Tajwar ◽  
Suzal Kumar
Keyword(s):  
Heavy Metal ◽  
Soil Contamination ◽  
Coal Mine ◽  
Contamination Factor ◽  
Pollution Index ◽  
Soil Samples ◽  
Contamination Level ◽  
Contamination Assessment ◽  
Element Analysis ◽  
Barapukuria Coal Mine

Coal mining areas in Bangladesh are exposing to extreme environmental problems due to the mobilization of heavy metals in the surrounding region. To assess the persisting risk, several soil samples were collected from the nearby coal mine areas. The amount of pollution of heavy metal has been calculated to determine the extent of the contamination. Soil contamination assessment was carried out using pollution evaluation indices such as heavy metal pollution index (HPI), the degree of contamination (Cd), and the contamination factor (CF). The concentration of S, As, Ba and, F exceeded the maximum concentration level in some soil samples. The HPI and the Cd yield similar results. The CF shows strong similarities with the Cd and gives a better evaluation of pollution levels. HPI indicates that about 71.42% of samples exceed the high level. Cd and CF show that about 71.42% sample is highly contaminated by trace element and 14.28% sample is highly contaminated by S, Cl, and F. Based on radioactive element analysis about 14.28% samples show medium contamination level. The findings of this research help us to assess the level of soil contamination and the extent of environmental and health concerns in the region of the Barapukuria coal mine.

Potential Ecological Risk Assessment of Heavy Metals Contamination in Surface Sediments of Ikpoba River, Southern Nigeria

2020 ◽  
Vol 3 (1) ◽  
pp. 33-41
Author(s):  
AA Enuneku ◽  
F Ineh
Keyword(s):  
Heavy Metals ◽  
Risk Assessment ◽  
Heavy Metal ◽  
Ecological Risk ◽  
Ecological Risk Assessment ◽  
Surface Sediments ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Potential Ecological Risk Assessment ◽  
Heavy Metals Contamination

The potential ecological risk assessment of heavy metals contamination in surface sediments of Ikpoba River, Edo State was estimated in this study after assessment of heavy metal concentrations in surface sediments from seven stations of the study area. Heavy metals were analyzed in the sediments using Atomic Absorption Spectrophotometer. The index of geo-accumulation for the metals (Lead (Pb); Iron (Fe); Nickel (Ni) and Copper (Cu)) studied were less than zero showing that the stations sampled were unpolluted with heavy metals. Contamination factor followed same pattern. Generally, there was a low potential ecological risk for heavy metal contamination to sediment dwelling organisms. However, station 4 (Capitol) was moderately contaminated and extremely enriched with Cu. Heavy metal values in this study were below the EPA limits for sediments except station 4 which was heavily polluted with Cu following the EPA guidelines. Regular monitoring and assessment of pollution load of Ikpoba River is recommended.

scholarly journals INDEX MODELS ASSESSMENT OF HEAVY METAL CONTAMINATION IN SOIL SAMPLES OF SELECTED MOTOR PARKS WITHIN MAIDUGURI, BORNO STATE, NIGERIA

2021 ◽  
Vol 3 (1) ◽  
pp. 6-14
Author(s):  
A.I. Mohammed ◽  
A.A. Ahmed ◽  
J.U. Jibrin
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Heavy Metal Contamination ◽  
Anthropogenic Activities ◽  
Contamination Factor ◽  
Pollution Index ◽  
Pollution Load Index ◽  
Soil Samples ◽  
World Health ◽  
Potential Threat

Heavy metal pollution is a global issue of concern which results from both biogenic and anthropogenic activities. Hence, an investigation of soil pollution is pertinent because of its potential threat to human health. The present study examined the concentrations, contamination and pollution load index cum ecological risk factor for some heavy metals in soil samples collected from Borno Express (BOEXP), Tashan Kano (TASKP) and Tashan Bama (TASBP) motor parks within Maiduguri, Borno state of Nigeria. The data obtained showed mean concentration range of 0.34 - 1.18 mg/kg, 0.04 - 0.15 mg/kg, 0.07 - 0.41 and 0.18 - 0.29 mg/kg for Zn, Cr, Cd and Cu respectively. Nonetheless, lead was not detected in any and all samples analyzed. The increasing order of concentrations in the soils followed: Zn > Cu > Cr > Cd, Cu > Cd > Zn > Cr and Cd > Zn > Cu > Cr for BOEXP, TASKP and TASBP motor parks respectively. Notwithstanding, the results showed lower concentrations to the allowable limits of World Health Organization (WHO). Furthermore, the contamination factor of cadmium in the TASKP fell within the (0.10 – 0.25) category, indicative of slight contamination whereas in TASBP, the calculated value 0.5125 was within (0.51 -0.75) category implying severe contamination. The other heavy metals analyzed showed contamination factor as well as pollution index values < 0.1 indicative of very slight contamination.Keywords: Borno Express, Tashan Kano, Tashan Bama, Motor Parks, Contamination Index.

Distribution and Contamination Status of Heavy Metals in the Surface Sediments along Western Coast of Bali Strait, Banyuwangi

2018 ◽  
Vol 1 (2) ◽  
Author(s):  
Defri Yona ◽  
Syarifah Hikmah Julinda Sari ◽  
Anedathama Kretarta ◽  
Citra Ravena Putri Effendy ◽  
Misba Nur Aini ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Metal Pollution ◽  
Contamination Factor ◽  
Pollution Index ◽  
Western Coast ◽  
Sampling Locations ◽  
Accumulation Index ◽  
Geo Accumulation Index ◽  
Geo Accumulation

This study attempted to analyze the distribution and contamination status of heavy metals (Cu, Fe and Zn) along western coast of Bali Strait in Banyuwangi, East Java. Bali Strait is one of the many straits in Indonesia with high fisheries activities that could potentially contributed to high heavy metal pollution. There were five sampling areas from the north to south: Pantai Watu Dodol, Pantai Kalipuro, Ketapang Port, Pantai Boom and Muncar as the fish landing area. Heavy metal pollution in these locations comes from many different activities such as tourism, fish capture and fish industry and also domestic activities. Contamination factor (CF), geo-accumulation index (Igeo) and enrichment factor (EF) of each heavy metal were calculated to obtain contamination status of the research area. The concentrations of Fe were observed the highest (1.5-129.9 mg/kg) followed by Zn (13.2-23.5 mg/kg) and Cu (2.2-7.8 mg/kg). The distribution of Cu, Fe and Zn showed variability among the sampling locations in which high concentrations of Cu and Zn were higher in Ketapang Port, whereas high concentration of Fe was high in almost all sampling locations. According to the pollution index, contamination factors of Cu, Fe and Zn were low (CF < 1 and Igeo < 1). However, high index of EF (> 50) showed high influence of the anthropogenic activities to the contribution of the metals to the environment. This could also because of the high background value used in the calculation of the index due to the difficulties in finding background value from the sampling areas.Keywords: heavy metals, pollution index, contamination factor, geo-accumulation index, Bali Strait

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