scholarly journals APPLICATION OF SOME SINGLE AND INTEGRATED INDEX EQUATION TO ASSESS HEAVY METAL IN DIFFERENT SOILS IN ERBIL GOVERNORATE

2021 ◽  
Vol 52 (4) ◽  
pp. 868-875
Author(s):  
Aweez & et al.
Keyword(s):  
Heavy Metal ◽  
Risk Factor ◽  
Ecological Risk ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Soil Samples ◽  
Degree Of Contamination ◽  
Integrated Index ◽  
Very High ◽  
Cu And Zn

The aim of this study was to application of some single and integrated index equation to assess heavy metal in different soil within Erbil governorate. The 15 different locations (Bahare new, Newroz, New Hawler, Hesarok, Azadi1, Zen city, Atconz city, Pank village, Binaslawa, Darato, Qushtapa, Shaways, Kasnazan, Bahirka, Pirzin) were specifically selected to identify the effects of traffic activities on soil properties. Different heavy metal distribution patterns (As, Cd, Cu, Cr and Zn) were determined from distance 5, 25, 50m roadside. Soil pollution was assessed using many indices including: contamination factor (CF), degree of contamination (Cdeg), Ecological Risk Factor and Potential Ecological Risk Index.The results showed that concentrations of As, Cd, Cr, Cu, and Zn in street dust ranged from (4.60, 1.80, 217.83, 62.14 and 215.18) mg.kg-1 which recorded in Qushtapa, Kasnazan, Atconze city, Hasarok5 and Zen city respectively. The contamination factor  and degree of contamination of  the trace elements As, Cd, Cr, Cu ,and Zn of soil samples was indicating considerable contamination factor for Qushtapa moderate contamination factor for Kasnazan, while Atconze city, Hasarok5, Zen city showed very high contamination factor, while degree of contamination considerable low degree of contamination. According to the ecological risk factor and RI results Qwshtapa was indicate as low potential ecological risk, Kasnazan had moderate potential ecological risk while Hasarok5 and Zen city considerable high potential ecological risk, except Atconze considerable very high ecological risk, on the other hand for RI index shown considerable very high ecological risk recorded in Hasarok 5 soil samples.

scholarly journals Contamination and Potential Ecological Risk Factors of Potentially Toxic Elements Present in the Soil of Shooting Range: Comparison with the Global Soils

2020 ◽  
Vol 9 (1) ◽  
pp. 37
Author(s):  
Saba Shoukat ◽  
Shahla Nazneen ◽  
Sardar Khan ◽  
Urooj Zafar
Keyword(s):  
Ecological Risk ◽  
Toxic Elements ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Potentially Toxic Elements ◽  
Soil Samples ◽  
Shooting Range ◽  
Shooting Range Soil ◽  
Ecological Risk Factors ◽  
Very High

This study was carried out to determine potentially toxic element (PTE) contamination and their potential ecological risk factors in shooting range soil. For this purpose soil samples were collected from different locations (left side, right side, shooting point, middle, and stop-butt) from the shooting range of Frontier Corps Training Centre (FCTC) present in Warsak, Peshawar. The soil samples were analyzed for pH, electrical conductivity (EC) and potentially toxic elements including Cd, Cr, Ni, Pb, and Zn. The strong acids digested extracts were analyzed using atomic absorption spectrophotometry to determine the concentrations of selected PTEs. The concentration of Pb was found to be maximum at stop-butt i.e. 2049 mg/kg and exceeded the United States Environmental Protection Agency (US-EPA) critical value of 400 mg/kg, while its concentrations at left, right, shooting point and middle were 14.0 mg/kg, 18.8 mg/kg, 47.4 mg/kg, and 18.2 mg/kg, respectively and exceeded the background level of normal soils which is 10 mg/kg for Pb. This study revealed that the shooting range soil was highly contaminated with Pb, and very high contamination factor and potential ecological risk for Pb was observed at stop-butt, very high contamination factor and potential ecological risk for Cd, while moderate contamination factor for Zn was observed at all locations of the shooting range. In Pakistan, the environmental perspective of shooting range soils is overlooked and there is a need to take steps to avoid such contamination of soils with Pb and other PTEs that can enter into food chains and can also leach to contaminate the aquifer. Replacement of vegetation of shooting range with PTE tolerant species, addition of soil conditioners and uncontaminated soil would reduce the mobility of these contaminants into aerial portions of plants and protect the groundwater contamination.

scholarly journals Industrial Activities and Heavy Metal Pollution: Assessment of Concentration of Zn, Cu, Cd Cr and, Pb in Soil Samples around Dangote Cement Factory Kogi State, Nigeria

2020 ◽  
pp. 75-86
Author(s):  
Sani Daniel Eneji ◽  
Matthew Chijioke Apeh ◽  
Enyojo Samson Okwute ◽  
Alowakennu Micheal ◽  
Kayode Ibrahim Fesomade
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Ecological Risk ◽  
Contamination Factor ◽  
Pollution Assessment ◽  
Soil Samples ◽  
Industrial Activities ◽  
Cement Factory ◽  
The Relationship ◽  
Geo Accumulation

This study aims at determining the concentration of heavy metal contaminants in the soil around Dangote cement factory Kogi State, Nigeria. It also seeks to understand the relationship between the heavy metals and the level of concentration with respect to distance and direction as well as the ecological risk it poses. The monitoring and assessment of soil pollution have over the years become a very important area of study due to the significant threat it poses to the food web. A total of 33 soil samples were collected in the Northern, Eastern and Western axis within a radius of 4km of Dangote cement factory at a depth of 0-15cm using a stainless steel auger. The contamination factor indices for Cr and Cu show moderate pollution across all the samples collected from different axis at a different distance from the factory. Zn also pose a moderate pollution across the samples except for WK4 and NK4 where it is in a low level of contamination. The geo-accumulation indices for Pb and Cr show unpolluted to moderately polluted across all samples at different locations expect for sample location EK4. The results of the ecological risk assessment revealed that Cd poses the highest ecological risk of all the five heavy metals investigated.

scholarly journals Suitability of environmental indices in assessment of soil remediation with conventional and next generation washing agents

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Barbara K. Klik ◽  
Zygmunt M. Gusiatin ◽  
Dorota Kulikowska
Keyword(s):  
Risk Factor ◽  
Soil Pollution ◽  
Soil Quality ◽  
Ecological Risk ◽  
Risk Index ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Next Generation ◽  
Ecological Risk Index ◽  
Metals Removal

AbstractRemediation of soils contaminated with metal must ensure high efficiency of metals removal, reduce bioavailability of residual metals and decrease ecological risk. Thus, for comprehensive environmental soil quality assessment, different indices must be used. In this study, suitability of 8 indices was used for soil highly contaminated with Cu (7874.5 mg kg−1), moderately with Pb (1414.3 mg kg−1) and low with Zn (566.1 mg kg−1), washed in batch and dynamic conditions with both conventional and next-generation washing agents. The following indices were used: modified contamination factor (mCf), modified contamination factor degree (mCdeg), mobility factor (MF), reduced partition index (IR), potential ecological risk factor (Er,Z), modified potential ecological risk factor (Er,m), potential ecological risk index (RIZ) and modified ecological risk index (RIm). For mCf,mCdeg and IR own classification scale was proposed. It was proven that most useful indices for assessment of soil pollution with metals were mCf and mCdeg. The mCf together with the IR allow to simultaneous assessment of soil pollution and stability for individual metals. These indices were appropriate for soil contaminated with different concentrations of metals, washed under both hydrodynamic conditions using various washing agents and different effectiveness of metals removal. Thus, they may be considered as most useful for evaluation of remediation method, feasibility of washing agent and assessing soil quality after washing.

scholarly journals Assessment of Heavy Metal Pollution and Potential Ecological Risk in Sewage Sludge from Municipal Wastewater Treatment Plant Located in the Most Industrialized Region in Poland—Case Study

2019 ◽  
Vol 16 (13) ◽  
pp. 2430 ◽  
Author(s):  
Malwina Tytła
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Wastewater Treatment ◽  
Risk Factor ◽  
Sewage Sludge ◽  
Ecological Risk ◽  
Treatment Plant ◽  
Potential Ecological Risk ◽  
Pollution Level ◽  
Chemical Forms

This study aimed to assess the pollution and potential ecological risk of seven heavy metals (Cd, Cr, Cu, Hg, Ni, Pb, and Zn) in the sewage sludge collected from a wastewater treatment plant (WWTP), located in the most industrialized region of Poland (Silesian Voivodeship). The concentrations of heavy metals were determined using inductively coupled plasma optical spectrometry (ICP-OES) and cold vapor atomic absorption spectrometry (CVAAS). The chemical forms (chemical speciation) of heavy metals were determined using the three-step chemical sequential extraction procedure, developed by the Community Bureau of Reference (BCR). To assess the pollution level and potential ecological risk, the following indices were used: Geoaccumulation Index (Igeo), Potential Ecological Risk Factor (ER), Individual Contamination Factor (ICF), Risk Assessment Code (RAC), and Ecological Risk Factor (ERF)—the author’s index. Sludge samples were collected at successive stages of processing. The results revealed that the activated sludge process and sludge thickening have a significant impact on heavy metal distribution, while anaerobic digestion and dehydration decrease their mobility. The most dominant metals in the sludge samples were Zn and Cu. However, the content of heavy metals in sewage sludge did not exceed the permissible standards for agricultural purposes. The concentrations of heavy metals bound to the immobile fractions exhibited higher concentrations, compared to those bound to mobile fractions (except Zn). The values of the total indices indicated that sludge samples were moderately to highly contaminated with Zn, Hg, Cd, Cu, and Pb, of which only Hg, Cd, and Cu posed a potential ecological risk, while according to the speciation indices, sludge samples were moderately to very highly polluted with Zn, Cu, Cd, Cr, and Ni, of which Zn, Ni, and Cd were environmentally hazardous. The obtained results proved that assessment of the pollution level and potential ecological risk of heavy metals in sewage sludge requires knowledge on both their total concentrations and their chemical forms. Such an approach will help prevent secondary pollution of soils with heavy metals, which may influence the reduction of health risks associated with the consumption of plants characterized by a high metal content.

scholarly journals An Innovative Approach to Assess the Ecotoxicological Risks of Soil Exposed to Solid Waste

2021 ◽  
Vol 13 (11) ◽  
pp. 6141
Author(s):  
Despina-Maria Bordean ◽  
Luminita Pirvulescu ◽  
Mariana-Atena Poiana ◽  
Ersilia Alexa ◽  
Antoanela Cozma ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Heavy Metal ◽  
Soil Contamination ◽  
Hazardous Waste ◽  
Ecological Risk ◽  
Contamination Factor ◽  
Soil Samples ◽  
Waste Dumps ◽  
Hazardous Waste Landfills ◽  
Illegal Waste

The adoption of sustainable waste management strategies is a challenge faced by most European countries, mainly due to the need to generate less waste and replace landfills with new methods of waste treatment, associated with increases in the separate collection of waste and recycling rates. This paper highlights the significance of environmental legislation regarding waste removal to protect ecosystems. The aim was to predict ecological responses to heavy metals in soil exposed to hazardous waste and to identify environmental hazards in landfills, small illegal waste dumps, and litter, in addition to identifying if heavy metal accumulation in the investigated soil samples showed a single or cumulative risk. This is an innovative method to predict the ecological risk generated by hazardous waste landfills. The assessment of ecological risks was based on the evaluation of a heavy metal soil contamination factor, pollution index of soil loadings, a geo-accumulation index for heavy metals, and potential ecological risk. The current study is also the first to attempt to identify the dimension of risk based on the type of waste deposit (landfill, small illegal waste dump, and litter) and to identify potential patterns. The geological index corresponding to cadmium Igeo(Cd) showed heavy contamination in the soil samples from the landfill and moderate contamination for those from the illegal waste dumps. These findings indicate that soil contamination is influenced by contamination time, anthropogenic processes, and a history of industrial activity, and not only by waste composition and storage. The present study shows that cadmium might be considered a latent fingerprint for waste disposal, which is correlated to the industrialization level and rehabilitation procedures.

scholarly journals POLLUTION BLOOM: AN APPRAISAL OF THE HAZARDOUS EFFECTS OF MINING OF PRECIOUS STONES IN ZAMFARA STATE

2020 ◽  
Vol 4 (1) ◽  
pp. 35-41
Author(s):  
Doris Fovwe Ogeleka ◽  
Godswill Igoni Alaminiokuma
Keyword(s):  
Ecological Risk ◽  
Risk Index ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
P Values ◽  
Ecological Risk Index ◽  
Lead Zinc ◽  
Cadmium Lead ◽  
Ph Range ◽  
Very High

In this appraisal, heavy metal concentrations in soils from Zamfara State were enumerated approximately a decade after the lead poisoning saga using indexes of pollution. The area is enhancement with valuable ores and minerals including gold making mining the most lucrative business in the area. The soils were moderate to slightly basic with a pH range from 6.49 ± 0.12 to 7.96 ± 0.15 (water) and 6.15 ± 0.10 to 7.80 ± 0.17 (KCl). Contamination / pollution (C/P) values reported for cadmium, lead, zinc and copper was 42.66, 0.59, 0.85 and 3.04 in the respective order (severe contamination to excessive pollution). The contamination factor (CF) was greater than the highest factor of 6, indicating very high contamination. The calculated values for geochemical accumulation (Igeo) and ecological risk factor (ERf) for Cd, Pb, Zn and Cu was (19.26, 0.27, 0.38, 1.37) and (1280, 2.95, 0.85, 15.2) respectively while the potential ecological risk index (ERi) was 1299, indicating that the soils were perturbed (polluted). Considering the deleterious effects heavy metals could cause and the resultant health implications, there is need to further remediate the polluted areas so as to avert harm to organisms and humans would consume crops grown in such environment.

scholarly journals Evaluation of temporary seasonal variation of heavy metals and their potential ecological risk in Nzhelele River, South Africa

2017 ◽  
Vol 15 (1) ◽  
pp. 272-282 ◽  
Author(s):  
Joshua N. Edokpayi ◽  
John O. Odiyo ◽  
Elizabeth O. Popoola ◽  
Titus A.M. Msagati
Keyword(s):  
Heavy Metals ◽  
Seasonal Variation ◽  
Ecological Risk ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Risk Level ◽  
Contamination Level ◽  
Alternative Source ◽  
The Impact ◽  
Cu And Zn

AbstractSurface water is often used as alternative source of drinking water in many regions of the world where the potable water supply is erratic or not present. The concentration of heavy metals was assessed using an Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES). The impact of temporary seasonal variation on the contamination level was also assessed. Contamination factor (CF) and Hakanson’s potential ecological risk (Er and RI) indices were used to evaluate the toxicity levels of the metals in the sediments of the river. Higher concentrations of Fe, Mn, Pb, Cu and Zn were determined in the dry season in the river water whereas in the sediments higher levels were recorded for Al, Fe, Cd, Cr, Cu and Zn in the wet season. The average CF values for all the metals showed a low contamination level in the sediment, except for Cu and Cd which had moderate and considerable contamination levels, respectively. Similarly, Cu showed a moderate ecological risk level (Er = 62.90) only in March 2014, for other months Cu and the other metals investigated had Er values < 40 which implies low ecological risk. The mean relative abundance of heavy metals in the sediments follows the trend Al>Fe>Mn>u>Zn>Cr>Pb>Cd.

scholarly journals Deposited Particulate Matter Enrichment in Heavy Metals and Related Health Risk: A Case Study of Krakow, Poland

Proceedings ◽  
2019 ◽  
Vol 44 (1) ◽  
pp. 1 ◽  
Author(s):  
Agnieszka Gruszecka-Kosowska
Keyword(s):  
Heavy Metals ◽  
Particulate Matter ◽  
Ecological Risk ◽  
Hazard Quotient ◽  
Risk Index ◽  
Contamination Factor ◽  
Potential Ecological Risk ◽  
Anthropogenic Sources ◽  
The Impact ◽  
Very High

The aim of these investigations was to determine the impact of heavy metals bound with deposited particulate matter (PM) on contamination degree and related toxicological effects by calculating enrichment indices, namely, the geo-accumulation index (Igeo), contamination factor (CF), and enrichment factor (EF), as well as the ecological risk index (ERI) and modified hazard quotient (mHQ). Calculations were made based on the selected element concentrations determined in deposited PM samples in Krakow. The results of the investigations revealed that deposited PM was enriched in heavy metals. As Igeo provides information on the level of metal accumulation, it was found that deposited PM was practically uncontaminated with Be, Cd, and Tl (class 0) but heavily to extremely contaminated (class 5) with Co and Sn and extremely contaminated (class 6) with As, Ba, Cr, Cu, Li, Mn, Ni, Pb, Sr, Ti, V, and Zn. On the other hand, the calculated values of CF revealed very high contamination of deposited PM with Cd and Zn, considerable contamination with Sn, Pb, and As, and moderate contamination with Cu and Li. Values of calculated EF revealed that among the investigated elements, only Zn originated from anthropogenic sources. For Cd, a small influence of anthropogenic sources was observed. For Pb and Sn, non-crustal sources of emission were expected. The calculated ERI values indicated potential ecological risk levels that were very high for Cd and considerable for Zn, as well as low potential ecological risk for As, Co, Cr, Cu, Ni, Pb, and Tl. Moreover, the calculated mHQ values of severity of contamination were extreme for Zn, considerable for Cr, and moderate for As, Cu, and Pb. The analysis revealed that the impact of atmospheric and re-suspended PM on inhabitants constitutes a complex effect of a mixture of heavy metals simultaneously affecting human health.

scholarly journals Health and Ecological Risks Associated with Heavy Metal Contamination in Surface Soils from Lagos Lagoon Wetlands, Lagos, Nigeria

2021 ◽  
Vol 25 (7) ◽  
pp. 1127-1137
Author(s):  
A.A. Adesuyi ◽  
L. Kelechi ◽  
D.N. Olayinka ◽  
O.A. Jimoh ◽  
M.O. Akinola
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Ecological Risk ◽  
Risk Index ◽  
Potential Ecological Risk ◽  
Moderate Degree ◽  
Degree Of Contamination ◽  
Potential Health ◽  
Lagos Lagoon ◽  
Cu And Zn

Wetlands quality and spatial distribution are being threatened by anthropogenic drivers in addition to the emerging threats of climate change. In this study, selected heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) in soils from Lagos lagoon wetlands were investigated to assess spatial distribution, ecological and health risks. The data obtained were subjected to statistical analysis using GraphPad 7.0 and SPSS 22.0. Spatial distribution mapping of heavy metals was performed using ArcGIS10.0 (ESRI, Redlands, CA, USA) with Kriging interpolation. Results showed that heavy metals in the soil varied significantly (p<0.05). The contamination factors (CF) were generally low with the values for Cr, Ni, Cu, and Zn very low (<1). The CF values for some of the sampling points showed that the soils are generally moderately contaminated by Pb, Cd and Cu. The modified degree of contamination of Pb (2.35) indicates a moderate degree of contamination while that of Cd (12.60) indicates a high degree of contamination of these wetland soils. The potential ecological risk index (RI) of Pb, Cd, Cr, Ni, Cu and Zn were 70.40, 2264.40, 0.68, 1.55, 13.65, and 2.29, respectively. The RI for Pb, Cr, Ni, Cu and Zn were less than 100, hence, low, while the RI value of Cd was a very high risk (RI ≥ 400). Soils from this wetland’s areas show serious significant potential ecological risk due to Cd. Additionally, children were more susceptible to the potential health risk irrespective of the carcinogenic or non – carcinogenic risk. There were no significant carcinogenic and non – carcinogenic risks for adults and children. This wetland assessment provided important information for policymaking to reduce the potential effects of soil contamination on humans and the eco-environment.

Spatial Ecological and Health Risk Assessment of Heavy Metal Contamination in Surface Soils From Lagos Lagoon Wetlands, Nigeria

2020 ◽  
Author(s):  
Adeola Alex Adesuyi ◽  
Kelechi L. Njoku ◽  
Modupe O. Akinola ◽  
Dupe N. Olayinka ◽  
Olalekan A. Jimoh
Keyword(s):  
Heavy Metals ◽  
Spatial Distribution ◽  
Health Risk ◽  
Ecological Risk ◽  
Potential Ecological Risk ◽  
Moderate Degree ◽  
Degree Of Contamination ◽  
Potential Health ◽  
Lagos Lagoon ◽  
Cu And Zn

Abstract Wetlands quality and spatial distribution are being threatened by anthropogenic drivers in addition to the emerging threats of climate change. In this study, selected heavy metals (Cd, Cr, Cu, Ni, Pb and Zn) in soils from Lagos lagoon wetlands were investigated to assess spatial distribution, ecological and health risks. The data obtained were subjected to statistical analysis using GraphPad 7.0 and SPSS 22.0. Spatial distribution mapping of heavy metals was performed using ArcGIS10.0 (ESRI, Redlands, CA, USA) with Kriging interpolation. Results showed that heavy metals in the soil varied significantly (p<0.05). The contamination factors (CF) were generally low with the values for Cr, Ni, Cu, and Zn very low (<1). The CF values for some of the sampling points showed that the soils are generally moderately contaminated by Pb, Cd and Cu. The modified degree of contamination of Pb (2.35) indicates a moderate degree of contamination while that of Cd (12.60) indicates a high degree of contamination of these wetland soils. The potential ecological risk index (RI) of Pb, Cd, Cr, Ni, Cu and Zn were 70.40, 2264.40, 0.68, 1.55, 13.65, and 2.29, respectively. The RI for Pb, Cr, Ni, Cu and Zn were less than 100, hence, low, while the RI value of Cd was a very high risk (RI ≥ 400). Soils from this wetland’s areas show serious significant potential ecological risk due to Cd. Additionally, children were more susceptible to the potential health risk irrespective of the carcinogenic or non – carcinogenic risk. There were no significant carcinogenic and non – carcinogenic risks for adults and children. This wetland assessment provided important information for policymaking to reduce the potential effects of soil contamination on humans and the eco-environment.

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