scholarly journals ELASTOMERS WITH A HIGH CONTENT OF MODIFIED CARBOXYMETHYLCELLULOSE

Author(s):  
A. F. Puchkov ◽  
M. P. Spiridonova ◽  
D. A. Kutsov ◽  
A. N. Kutsov ◽  
V. A. Drozdev

The use of lactam-containing complex salts (LCS) with the functions of dispersants, apparatuses and crosslinking agents made it possible to obtain elastomers with a high (at least 300 wt.% per 100 wt.h. of rubber), containing modified carboxymethyl cellulose for the cuff of a packer device capable of performing the necessary shut-off functions in contact with highly concentrated, at least 25% aqueous solutions of mineral salts - NaCl and CaCl2. The achieved effect is expressed in the ability of LCS to disperse water-swelling polymers (GNP), to have an appreting effect on GNP particles, thereby preventing their agglomeration, as well as to create additional chemisorption bonds in the rubber matrix. As a result, a developed network of interface boundaries is obtained, which contributes to the rapid penetration of aqueous solutions of mineral salts into the array of elastomeric composition.

Author(s):  
S. S. Lopatina ◽  
M. A. Vaniev ◽  
N. V. Sychev ◽  
D. V. Demidov ◽  
A. A. Cheremisin ◽  
...  

This paper is dedicated to the investigation of water- and oilswelling ability of the elastomeric material based on nonpolar ethylene-propylene rubber, modified by water swelling agents such as combination of copolymer acrylamide with potassium acrylate and sodium-carboxymethyl cellulose. It was found that the maximum volume increase of the sample recorded during it`s exposure in water and is equal 1250 %, in 10 % and 22 % aqueous solutions of sodium chloride is up to 280 % and 210 %, in oil and the Polyekonol-Flora drilling system 70 % and 80 %, respectively.


2019 ◽  
Vol 816 ◽  
pp. 208-213
Author(s):  
Svetlana S. Lopatina ◽  
M.A. Vaniev ◽  
N.V. Sychev ◽  
D.A. Nilidin ◽  
Y.Yu. Savchenko ◽  
...  

This paper reviews water swelling of rubber, based on nitrile-butadiene rubber, modified by polyacrylamide and copolymer acrylamide with potassium acrylate, also their combination with sodium-carboxymethyl cellulose. During the exposure for 14 days at a temperature of 67 °С swelling ratio in water is 200 % and 47 % in 10 % aqueous solution of sodium chloride.


2012 ◽  
Vol 724 ◽  
pp. 61-64
Author(s):  
Ying Li ◽  
Xiao Yan Lin ◽  
Zhe Chen ◽  
Xue Guang Luo ◽  
Wei Li Zuo

A composite membrane of thermoplastic carboxymethyl cellulose (TCMC) /PLA was prepared by electrospinning process, and crossliked by epichlorohydrin solution at different temperature. The cross-linking temperature was optimized by characterizing the morphology and tensile strength of the film. The optimal cross-linking temperature was 50°C. A composite membrane was used to remove Cu2+ from aqueous solutions, and the effects of initial concentration of Cu2+ and contact time on the removal efficiency of Cu2+ were investigated. The removal efficiency of Cu2+ was 13.78%, at the initial concentration of 40 mg·L-1 and contact time of 30s.


RSC Advances ◽  
2015 ◽  
Vol 5 (73) ◽  
pp. 59273-59285 ◽  
Author(s):  
Jing Wang ◽  
Xiaoyan Lin ◽  
Xuegang Luo ◽  
Wenhui Yao

Linked carboxymethyl cellulose microspheres loaded with lanthanum(iii) (linked-CMC–La) were fabricated with glutaraldehyde. The linked-CMC–La had good adsorption properties compared with CMC–La, and also showed better physical properties.


Polymers ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 3054
Author(s):  
Yiming Zhou ◽  
Te Li ◽  
Juanli Shen ◽  
Yu Meng ◽  
Shuhua Tong ◽  
...  

This article reports effective removal of methylene blue (MB) dyes from aqueous solutions using a novel magnetic polymer nanocomposite. The core-shell structured nanosorbents was fabricated via coating Fe3O4 nanoparticles with a layer of hydrogel material, that synthesized by carboxymethyl cellulose cross-linked with poly(acrylic acid-co-acrylamide). Some physico-chemical properties of the nanosorbents were characterized by various testing methods. The nanosorbent could be easily separated from aqueous solutions by an external magnetic field and the mass fraction of outer hydrogel shell was 20.3 wt%. The adsorption performance was investigated as the effects of solution pH, adsorbent content, initial dye concentration, and contact time. The maximum adsorption capacity was obtained at neutral pH of 7 with a sorbent dose of 1.5 g L−1. The experimental data of MB adsorption were fit to Langmuir isotherm model and Pseudo-second-order kinetic model with maximum adsorption of 34.3 mg g−1. XPS technique was applied to study the mechanism of adsorption, electrostatic attraction and physically adsorption may control the adsorption behavior of the composite nanosorbents. In addition, a good reusability of 83.5% MB recovering with adsorption capacity decreasing by 16.5% over five cycles of sorption/desorption was observed.


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