scholarly journals The Micro/elemental Composition of Bottom Sediments of Small Lakes as Indicator of Environmental Risks in Urban Area of Republic of Karelia

2018 ◽  
Author(s):  
Keyword(s):  
Heavy Metals ◽  
Lake Sediments ◽  
Urban Environment ◽  
Bottom Sediments ◽  
Environmental Risks ◽  
Water Bodies ◽  
Individual Species ◽  
Urban Water ◽  
Small Lakes ◽  
Living Organisms

The general questions of the influence of urban environment on the development of deviations in living organisms up to the death of individual species are considered. Using the example of a study of the chemical composition of bottom sediments of six small lakes of the Republic of Karelia, a significant effect of technogenesis on the occurrence of ecological risks on the aquatic flora and fauna of an urbanized environment is shown. We have stated that the upper layers of the bottom sediments of urban lakes have increased concentrations of heavy metals in comparison with the underlying layers. The thickness of technogenically altered lake sediments for urban water bodies of Karelia is established. According to the analysis of the formulas of geochemical associations of bottom sediments of urbanized lakes, we identified priority pollutants (Pb, Sb, Cd, V, Zn, Cu, Ni etc.). These metals are associated with major environmental risks within the urban environment of the region. The patterns of distribution of individual chemical elements in the investigated lake sediments are determined depending on the geochemical specificity of the catchment area and specific sources of heavy metals. Examples of direct negative effects of heavy metals on living organisms of the aquatic environment are benthic organisms and fish. The biogeochemical potential of biota of urban water bodies to accumulate heavy metals and accompanying microelements is shown.

Sedimentation of Pb-210 in Laurentian Shield Lakes

1984 ◽  
Vol 19 (2) ◽  
pp. 97-109 ◽  
Author(s):  
R.J. Cornett ◽  
L. Chant ◽  
D. Link
Keyword(s):  
Lake Sediments ◽  
Water Column ◽  
Rate Constant ◽  
Bottom Sediments ◽  
Atmospheric Fallout ◽  
Small Lakes ◽  
Fractional Rate ◽  
Total Input ◽  
Shield Lakes ◽  
Annual Flux

Abstract The average annual flux of Pb-210 from the atmosphere to lake surfaces and to the bottom sediments was measured in seven small lakes located on the Laurentian Shield. Direct atmospheric fallout of Pb-210 was 136 ± 16 Bq m-2 a-1 Streams from the lakes' catchments input an additional 5 to 473 Bq m-2 a-1. Only 16 to 80 percent of the total input was found in the lake sediments. The fractional rate constant for Pb-210 sedimentation from the water column ranged from 0.25 to 5.3 per annum.

scholarly journals Organochlorine compounds in subarctic small lakes

2020 ◽  
Vol 66 (2) ◽  
pp. 180-197
Author(s):  
E. S. Kolpakova ◽  
A. V. Velyamidova
Keyword(s):  
Lake Sediments ◽  
Bottom Sediments ◽  
Hydrothermal System ◽  
Atmospheric Transport ◽  
Electron Capture Detection ◽  
Adjacent Area ◽  
Chlorinated Phenols ◽  
Natural Boundary ◽  
Small Lakes ◽  
Lake Ecosystems

The article presents the results of studies of the environmental properties of organochlorines which differ in properties and origin, in the lake ecosystems of the Bolshezemelskaya tundra (Nenets Autonomous Okrug, Russia). The purpose of this study was to evaluate and assess the levels, distribution characteristics and composition of organochlorines in the bottom sediments of small lakes located in the Adzva river basin in Pymvashor natural boundary (the northernmost location of the exit of thermal-mineral springs of the continental Europe) and in the adjacent area, outside this unique subarctic hydrothermal zone.In order to meet this goal, multi-method (hydrochemical, geochemical, etc.) research was carried out using standard generally approved laboratory practices with their adaptation to the study goals. The quantitative content and composition of the target individual organochlorines were determined by gas chromatographic method with electron-capture detection.The presence of chlorophenol compounds and polychlorinated benzenes (including persistent organic pollutants) was shown in the lakes sediments. The influence of specific microclimatic conditions of subarctic hydrothermal system on the composition and distribution of chlorophenol compounds in lake sediments was considered. In the small lake sediment core in Pymvashor natural boundary a reducing trend in the levels of organochlorines with depth has been recorded (conditioned among other things by the lithological features of bottom sediments). The chlorophenol compounds were found at highest concentrations (619.3–765.5 ng/g) in the sediment upper layers, rich in organic matter; chlorophenol composition was represented mainly by chlorinated phenols, most likely of biotic origin. A lower concentration (185.0 ng/g) of chlorophenol compounds of predominantly abiogenic origin was determined in the lake sediments outside hydrothermal system. The presence and levels of persistent organochlorine pollutants (pentachlorophenol 0.1–2.4 ng/g; hexa- and pentachlorobenzenes 0.4–3.6 ng/g) in the lake sediments were associated with long-range atmospheric transport from various origin sources in nearby regions and low-latitude territories.

scholarly journals Contamination of bottom sediments by lead, zinc and cadmium in Rzeszow reservoir

2018 ◽  
Vol 29 (4) ◽  
pp. 10-15
Author(s):  
Katarzyna Maj-Zajezierska ◽  
Piotr Koszelnik
Keyword(s):  
Heavy Metals ◽  
Bottom Sediments ◽  
Sediment Quality ◽  
Environmental Risks ◽  
Sediment Classification ◽  
Quality Classification ◽  
Lead Zinc ◽  
Aquatic Sediment ◽  
Positive Effect

Abstract The aim of the present study was to determine the level of contamination of the bottom sediments in the Rzeszow reservoir by the selected heavy metals Pb, Cd and Zn, and to identify the potential environmental risks of heavy metals content basing on available assessments and classification of bottom sediments. The Rzeszow reservoir is situated on the Wisłok River in the Podkarpackie Voivodeship, southeaster Poland, was constructed on 1974. Nowadays, as a result of silting, the reservoir reduced its surface and depth, which does not have a positive effect on the assumed functions it is to perform. The study was conducted in 2016. The samples of sediment were collected in five locations. Samples were taken twice: in June and in October. The following concentrations have been determined: cadmium - 0.01 ÷ 0.92 mg•kg–1, zinc - 54.39 ÷ 128 mg•kg–1, lead - 2.98 ÷ 25.42 mg•kg–1. The decline trend in the sediment is following: Zn > Pb > Cd. For the assessment of sediment contamination, following methods: aquatic sediment quality classification used by the Polish Geological Institute - I class, Regulation of the Minister of Environment of April 16 2002 on the types and concentrations of substances contaminating the excavated material – unpolluted and LAW sediment classification – Pb - I/I-II, Cd - I/I-II/II and Zn - I/I-II. The obtained results were compared with the results obtained by the other authors in earlier years, which led to the estimated changes in the concentration of the tested metals.

scholarly journals Lead compounds in bottom sediments of the Seversky Donets floodplain

2020 ◽  
Vol 169 ◽  
pp. 01004
Author(s):  
Marina Burachevskaya ◽  
Dina Nevidomskaya ◽  
Victoria Tsitsuashvili ◽  
Vishnu Rajput ◽  
Dmitry Bren
Keyword(s):  
Heavy Metals ◽  
Organic Matter ◽  
Bottom Sediments ◽  
Anthropogenic Activities ◽  
High Mobility ◽  
Environmental Risks ◽  
Layered Silicates ◽  
Sequential Fractionation ◽  
Settling Basin ◽  
Lead Compounds

Investigations on heavy metals in water bodies are extremely important in a comprehensive assessment when the anthropogenic activities disturb the natural environment. The present paper studies the composition of Pb compounds in highly contaminated bottom sediments of a natural settling basin of a chemical plant at the Atamanskoye lake in the floodplain of the Seversky Donets River by sequential fractionation. The predominance of the residual Pb fraction, which is represented by layered silicates (hydromuscovite, montmorillonite, kaolinite) is shown. Organic matter and Fe-Mn (hydr)oxides also play an important role in metal interaction. High mobility of Pb is noted, which associated with imposing high environmental risks in the studied area.

scholarly journals Concentration of heavy metals and metalloids in the bottom sediments of the Vilkitsky Island’s lakes (the Kara Sea)

2020 ◽  
Vol 169 ◽  
pp. 01001
Author(s):  
Elena Agbalyan ◽  
Aleksander Krasnenko ◽  
Elena Shinkaruk
Keyword(s):  
Heavy Metals ◽  
Bottom Sediments ◽  
Ecological Status ◽  
Maximum Level ◽  
Kara Sea ◽  
Small Lakes ◽  
Metals And Metalloids ◽  
X Ray ◽  
Remote Areas ◽  
Heavy Metals And Metalloids

We performed this study in order to obtain relevant data about the actual ecological status of the lakes in remote areas of the Russian Arctic. The objective was to determine the level of technogenic pollution of bottom sediments in the lakes on the Vilkitsky island in the Kara Sea. To this end, we examined 8 of the island’s small lakes. The content of heavy metals and metalloids (Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, As, Y, Nb) in the samples of bottom sediments was determined using the method of Energy Dispersive X-ray Fluorescence (EDXRF). The total pollution value in the examined bottom sediments varied from Zc = 9.5 to Zc = 15.3. The maximum level of pollution was found in Lake 4 located in an anthropogenically disturbed area due to the levels of Cr, Co, Ni, As, Y, Nb.

Main criteria for assessing the content of heavy metals in bottom sediments of water bodies

2020 ◽  
pp. 34-40
Author(s):  
Boris Korzhenevskiy ◽  
Gleb Tolkachev ◽  
Nikolay Kolomiycev
Keyword(s):  
Heavy Metals ◽  
Soil Contamination ◽  
Bottom Sediments ◽  
Maximum Permissible Concentration ◽  
Pore Solution ◽  
Solid Phase ◽  
Water Bodies ◽  
Main Criterion ◽  
Important Indicator ◽  
Secondary Pollution

The main criteria for assessing the content of heavy metals in sediments of water bodies. At present, the methodology for rationing pollutants in bottom sediments of surface watercourses is clearly not sufficiently developed. There are various and significantly different approaches to the assessment of soil contamination with heavy metals. The maximum permissible concentration (MAC), which is the main criterion for assessing the levels of pollution, is not perfect and needs to be significantly adjusted. A number of methodological assessments of contamination of bottom sediments with heavy metals with comparative characteristics are considered, of which a method for estimating the anthropogenic load on a reservoir according to its geo-classes has been proposed as one of the best. The gross content of heavy metals in bottom sediments of water bodies does not give a sufficient idea of the possibility of secondary pollution of water masses and, as a result, subsequent toxic effects. A much more important indicator is their content and distribution by forms of existence in the solid phase and pore solution of bottom sediments. As a consequence, this article develops a topic for estimating possible secondary pollution of water bodies by determining the content and distribution of TM by forms of existence in the solid phase and pore sediment solution.

Pressures and impact analysis in the Dnipro river basin within Ukraine

2021 ◽  
Author(s):  
Nataliia Osadcha ◽  
Yurii Nabyvanets ◽  
Volodimir Osadchyi ◽  
Olha Ukhan ◽  
Valeriy Osypov ◽  
...  
Keyword(s):  
Water Pollution ◽  
Heavy Metals ◽  
Surface Water ◽  
River Basin ◽  
Bottom Sediments ◽  
Point Sources ◽  
Water Bodies ◽  
Hazardous Substances ◽  
Organic Substances ◽  
Diffuse Sources

<p>The third largest European river Dnipro covers 48% of Ukraine’s territory. An analysis of the main anthropogenic pressures in the Dnipro Basin was first performed according to the requirements of EU WFD.</p><p>Surface water pollution by organic substances and nutrients is principally attributed with point sources, among which the municipal wastewaters play the dominant role. The main load by organic substances and nutrients is caused by the wastewater discharges of big cities with Population Equivalent >100 000; 89% of such cities are located within the sub-basins of Middle Dnipro and Lower Dnipro. </p><p>Point sources form 33% of nitrogen and 61% of phosphorus loads in the Dnipro Basin. Diffuse sources related to agricultural production cause incoming of 29% of nitrogen and 36% of phosphorus. Phosphorus is transported to the water bodies mainly with erosion particles. </p><p>Natural conditions in the River Basin are one of the reasons of nitrogen load significant share (33%). Humus compounds and nitrogen compounds enter into water bodies due to the high bogginess of the Dnipro Basin upper part, especially the Prypiaty Basin. This leads to winter and summer anoxia in the rivers and upper reservoirs and creates prerequisites for eutrophication of the Dnipro cascade reservoirs. Rivers of the Prypiaty sub-basin, Upper Dnipro, and Desna sub-basins are extremely vulnerable to anthropogenic pollution by nutrients and organic substances that generates the increased background of organic compounds and nitrogen in the Dnipro reservoirs cascade. </p><p>The load of the Dnipro Basin surface water by hazardous substances (especially synthetic) still remains insufficiently studied. Currently, information is only available regarding load by heavy metals included to the list of priority substances and some other ones. Water pollution by metals is noted mostly in the Lower Dnipro sub-basin where the most of the metallurgical enterprises are located. </p><p>The high application of pesticides (> 3 kg/ha) in 4 administrative Rayons leads to the appearance of risk conditions for pollution of xenobiotics in 50 surface water bodies (SWBs). </p><p>The Dnipro reservoirs cascade serves as a powerful geochemical barrier causing heavy metals and pesticides deposition in bottom sediments. The highest pollution by metals is noted in the sediments of the Dnipro reservoirs that receive the metallurgy enterprises wastewaters. Probability of significant secondary remobilization is foremost noted for Cadmium. Organochloride pesticides content in the bottom sediments is 2 to 5 times lower than maximal allowable concentration in soil. </p><p>Water abstraction volume is around 22% of the annual flow of 95% probability. The natural flow of the Dnipro is regulated by 6 large reservoirs. Besides, there are 1072 dams and other cross-sectional artificial installations. Natural morphology changes are observed in a large number of rivers within the Dnipro Basin. </p><p>It was found that 56% of the Dnipro Basin SWBs are at risk of failing the “good” ecological status.</p><p>Hydromorphological alterations cause the main anthropogenic pressure in the Dnipro Basin (concerning 45% of the SWBs). Risks from diffuse sources and point sources are observed in 23% and 5% of SWBs, respectively.</p>

scholarly journals FEATURES OF HEAVY METALS DISTRIBUTION IN BOTTOM SEDIMENTS OF THE RIVERS OF UKRAINE

2018 ◽  
pp. 28-32
Author(s):  
N. G. Lyuta
Keyword(s):  
Heavy Metals ◽  
Chemical Composition ◽  
Bottom Sediments ◽  
Chemical Elements ◽  
River Basins ◽  
Water Bodies ◽  
Geochemical Background ◽  
Metallogenic Province ◽  
Catchment Areas ◽  
Background Content

The chemical composition of bottom sediments is an important indicator of the ecological state of both water systems and watershed areas, since contaminated bottom sediments are a potential source of secondary pollution of aquatic systems. The analysis of recent publications shows that great attention has been paid to the chemical composition of bottom sediments, however, as a rule, these studies are of a local nature, that is, they cover very small areas. This often raises the issue of criteria for assessing the ecological and geochemical status of bottom sediments, since a small number of samples does not allow correctly determining the local geochemical background. In addition, generally accepted norms, for example, the maximum allowable concentrations, do not exist for bottom sediments. In these conditions, data on regional geochemical backgrounds of pollutants are needed. The need for the implementation of the Water Framework Directive in Ukraine, which requires the introduction of water management basin-based, necessitates the determination of the geochemical characteristics of bottom sediments within the river basin territories. To study the distribution of heavy metals and determine their regional backgrounds in the bottom sediments, a database of environmental and geochemical information was used in the GIS, one of the blocks of which is information on the content of chemical elements and compounds in the bottom sediments of watercourses and water bodies of Ukraine, and the electronic map of river basins of Ukraine. Based on the analysis in the GIS of information on the chemical composition of the bottom sediments of the rivers of Ukraine (about 8,1 thousand samples), regional geochemical background of lead, zinc, copper, chromium, nickel and cobalt have been determined. The main regularities of distribution of chemical elements in bottom sediments in the territory of Ukraine are established. For the chemical elements in question, a gradual increase in their content in soils from north to south, that is, from the river basins of the Polissya zone to the basins of the Steppe landscape-climatic zone, is consistent with the geochemical features of the soil cover of the catchment areas. The increased background content of chemical elements in bottom sediments often spatially coincides with the spread of soil differences in the catchment areas, which also have a high content of these elements. The maximum background content of most heavy metals in bottom sediments is naturally clearly recorded within the Carpathian-Crimean metallogenic province. Thus, despite the long and intensive technogenic impact on the surface water bodies of Ukraine, it is necessary to note the priority of natural factors in the formation of the chemical composition of bottom sediments, at least for the heavy metals considered above.

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