scholarly journals Porosity Effect of the Silver Catalyst in Hydrogen Peroxide Monopropellant Thruster

CFD Letters ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 1-20
Author(s):  
Muhammad Shahrul Nizam Shahrin ◽  
Norazila Othman ◽  
Nik Ahmad Ridhwan Nik Mohd ◽  
Mastura Ab Wahid ◽  
Mohd Zarhamdy Md. Zain
Keyword(s):  
Hydrogen Peroxide ◽  
Pressure Drop ◽  
Transport Model ◽  
Compaction Pressure ◽  
Exothermic Reaction ◽  
Momentum Equation ◽  
Phase Reaction ◽  
Silver Catalyst ◽  
Bed Temperature ◽  
Optimum Porosity

In monopropellant system, hydrogen peroxide is used with catalyst to create an exothermic reaction. Catalyst made of silver among the popular choice for this application. Since the catalyst used is in porous state, the effect of its porosity in the hydrogen peroxide monopropellant thruster performances is yet unknown. The porosity changes depending on factors including catalyst pact compaction pressure, bed dimension, and type of catalyst used. As researches on this topic is relatively small, the optimum porosity value is usually left out. The performance of the thruster indicated by the pressure drop across the catalyst bed. Porosity of the catalyst bed adds additional momentum sink to the momentum equation that contributes to the pressure gradient which lead to pressure loss inside thruster. The effect of porosity influences the performance and precision of the thruster. Study of the pressure drop by the catalyst bed requires a lengthy period and expensive experiments, however, numerical simulation by mean of Computational Fluid Dynamics (CFD) can be an alternative. In this paper, 90 wt% hydrogen peroxide solution with silver catalyst is studied in order to investigate the influence of porosity to the performances of the thruster, and to find the optimum porosity of the thruster. Species transport model is applied in the single-phase reaction simulation using the EDM for turbulence-chemistry interaction. Through this study, the effect of porosity towards the thruster performances represented in term of pressure drop, exit velocity, bed temperature, and thrust, and porosity of 0.4 found to be as an optimal value.

Synthesis of Sic Fine Particles by Gas-Phase Reaction Under Short-Time Microgravity

1992 ◽  
Vol 286 ◽  
Author(s):  
Takeshi Okutani ◽  
Yoshinori Nakata ◽  
Masaakt Suzuki ◽  
Yves Maniette ◽  
Nobuyoshi Goto ◽  
...  
Keyword(s):  
Thermal Decomposition ◽  
Heat Source ◽  
Size Distribution ◽  
Gas Phase ◽  
Fine Particles ◽  
Rapid Heating ◽  
Exothermic Reaction ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Short Time

ABSTRACTSiC fine particles were synthesized by the gas-phase thermal decomposition of tetramethylsilane (Si(CH3)4) in hydrogen under microgravity of 10−4G for 10 sec. Rapid heating to the temperature over 800°C which is required for thermal decomposition of Si(CH3)4) under short-time microgravity was attained using a chemical oven where the heat of exothermic reaction of combustion synthesis of Ti-A1-4B composites was used as the heat source. Monodisperse and spherical SiC fine particles were synthesized under microgravity, whereas aggregates of SiC fine particles were synthesized under 1 G gravity. The SiC particles synthesized under microgravity (150-200 nm) were bigger in size and narrower in size distribution than those under 1 G gravity (100-150 nm).

scholarly journals Highly sensitive non-enzymatic hydrogen peroxide monitoring platform based on nanoporous gold via a modified solid-phase reaction method

RSC Advances ◽  
2021 ◽  
Vol 11 (58) ◽  
pp. 36753-36759
Author(s):  
Zhipeng Yang ◽  
Jun Li ◽  
Panmei Liu ◽  
An Zhang ◽  
Jing Wang ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Solid Phase ◽  
Nanoporous Gold ◽  
Solid Phase Reaction ◽  
Selective Detection ◽  
Phase Reaction ◽  
Reaction Method ◽  
Grain Sizes ◽  
Highly Sensitive ◽  
Monitoring Platform

Ge/Au/Ge triple-layered precursor was proposed to prepare nanoporous gold (NPG) with much smaller grain sizes and nanopores as an electrochemical sensor for highly sensitive and selective detection of hydrogen peroxide.

Implementation of a Pressure Drop Model for the CFD Simulation of Clogged Containment Sump Strainers

2009 ◽  
Author(s):  
Alexander Grahn ◽  
Eckhard Krepper ◽  
Frank-Peter Weiß ◽  
So¨ren Alt ◽  
Wolfgang Ka¨stner ◽  
...  
Keyword(s):  
Pressure Drop ◽  
Cfd Simulation ◽  
Liquid Velocity ◽  
Compaction Pressure ◽  
Three Dimensional ◽  
General Purpose ◽  
Extended Model ◽  
Fibrous Materials ◽  
Loss Of Coolant Accident ◽  
Cake Porosity

The present study aims at modelling the pressure drop of flows across growing cakes of compressible, fibrous materials which may form on the upstream side of containment sump strainers after a loss-of-coolant accident (LOCA). The model developed is based on the coupled solution of a differential equation for the change of the pressure drop in terms of superficial liquid velocity and local porosity of the fibre cake and a material equation that accounts for the compaction pressure dependent cake porosity. Details of its implementation into a general-purpose three-dimensional computational fluid dynamics code (CFD) are given. An extension to this basic model is presented, which simulates the time dependent clogging of the fibre cake due to capturing of suspended particles as they pass trough the cake. The extended model relies on empirical relations which model the change of pressure drop and removal efficiency in terms of particle deposit in the fibre cake.

Modeling of Turbulent Flows Through the Annular Channel with Eccentricity and Rotating Inner Cilinder

2012 ◽  
Vol 7 (4) ◽  
pp. 79-86
Author(s):  
Evgeny Podryabinkin ◽  
Valeriy Rudyak
Keyword(s):  
Pressure Drop ◽  
Turbulent Flows ◽  
Transport Model ◽  
Reverse Flow ◽  
Axial Flow ◽  
Annular Channel ◽  
Rotational Flow ◽  
Concentric Annulus ◽  
Cylindrical Annulus ◽  
Wide Range

In this paper fully developed turbulent flows of Newtonian fluid in cylindrical annulus with eccentricity and rotating inner cylinder has been systematically studied. Modeling has been performed on the base of Menter Shear Transport model of turbulence in a wide range of Reynolds numbers, eccentricity, and radii ratio. As the result dependencies of flow field and pressure drop along the channel on geometrical and flow parameters have been found. It was shown that flow characteristics and dependence of the pressure drop are determined by which flow axial or rotational dominates and caused generation of turbulence. When rotational flow dominates the dependence of the pressure drop is almost linear. When axial flow dominates rotation practically has no impact on the pressure drop in concentric annulus. Appearance of the reverse flow in eccentric channel has a major impact on the pressure drop. In case when rotational flow dominates, appearance of the reverse flow is accompanied by threshold flow restructuring at some critical value of eccentricity. A correlation for determination of the pressure drop in various regimes has been developed for the case of concentric annulus

scholarly journals DMS oxidation and sulfur aerosol formation in the marine troposphere: a focus on reactive halogen and multiphase chemistry

2018 ◽  
Vol 18 (18) ◽  
pp. 13617-13637 ◽  
Author(s):  
Qianjie Chen ◽  
Tomás Sherwen ◽  
Mathew Evans ◽  
Becky Alexander
Keyword(s):  
Gas Phase ◽  
Dimethyl Sulfide ◽  
Transport Model ◽  
Removal Rate ◽  
Sulfur Cycle ◽  
Phase Reaction ◽  
Aerosol Formation ◽  
Cloud Droplets ◽  
Sulfur Chemistry ◽  
Marine Troposphere

Abstract. The oxidation of dimethyl sulfide (DMS) in the troposphere and subsequent chemical conversion into sulfur dioxide (SO2) and methane sulfonic acid (MSA) are key processes for the formation and growth of sulfur-containing aerosol and cloud condensation nuclei (CCN), but are highly simplified in large-scale models of the atmosphere. In this study, we implement a series of gas-phase and multiphase sulfur oxidation mechanisms into the Goddard Earth Observing System-Chemistry (GEOS-Chem) global chemical transport model – including two important intermediates, dimethyl sulfoxide (DMSO) and methane sulphinic acid (MSIA) – to investigate the sulfur cycle in the global marine troposphere. We found that DMS is mainly oxidized in the gas phase by OH (66 %), NO3 (16 %) and BrO (12 %) globally. DMS + BrO is important for the model's ability to reproduce the observed seasonality of surface DMS mixing ratio in the Southern Hemisphere. MSA is mainly produced from multiphase oxidation of MSIA by OH(aq) (66 %) and O3(aq) (30 %) in cloud droplets and aerosols. Aqueous-phase reaction with OH accounts for only 12 % of MSA removal globally, and a higher MSA removal rate is needed to reproduce observations of the MSA ∕ nssSO42- ratio. The modeled conversion yield of DMS into SO2 and MSA is 75 % and 15 %, respectively, compared to 91 % and 9 % in the standard model run that includes only gas-phase oxidation of DMS by OH and NO3. The remaining 10 % of DMS is lost via deposition of intermediates DMSO and MSIA. The largest uncertainties for modeling sulfur chemistry in the marine boundary layer (MBL) are unknown concentrations of reactive halogens (BrO and Cl) and OH(aq) concentrations in cloud droplets and aerosols. To reduce uncertainties in MBL sulfur chemistry, we should prioritize observations of reactive halogens and OH(aq).

Numerical Simulation and Mixing Study of Non-Newtonian Fluids in an Industrial Helical Static Mixer

2004 ◽  
Author(s):  
Ramin K. Rahmani ◽  
Theo G. Keith ◽  
Anahita Ayasoufi
Keyword(s):  
Reynolds Number ◽  
Pressure Drop ◽  
Single Phase ◽  
Engineering Application ◽  
Newtonian Fluids ◽  
Phase Reaction ◽  
Static Mixer ◽  
Fluid Type ◽  
Mixing Processes ◽  
Static Mixers

Static mixers are increasingly being used to perform a variety of mixing tasks in industries, ranging from simple blending to complex multi-phase reaction systems. Use of static mixers to process non-Newtonian fluids is quite common. Data on the pressure drop of non-Newtonian fluids in static mixers and the degree of mixing of materials through the mixer are very useful in the design and engineering application of these tools. This paper extends a previous study by the authors on an industrial helical static mixer and illustrates how static mixing processes of single-phase viscous liquids can be simulated numerically. A further aim is to provide an improved understanding of the flow pattern of non-Newtonian single-phase liquids through the mixer. A three-dimensional finite volume simulation is used to study the performance of the mixer. The non-Newtonian fluid is modeled by the Carreau law model for the shear stress. The effects of the Reynolds number of the flow and also properties of non-Newtonian fluids on the static mixer performance have been studied. The flow velocities, pressure drops, etc. are calculated for various flow rates. The computed pressure drop is in good agreement with existing experimental data. A comparison of the mixer performance for both Newtonian and non-Newtonian fluids is presented. It is shown that for low Reynolds number flows, the fluid type is less effective on the degree of mixing, while as flow Reynolds number increases and the viscosity decreases, it manifests more influence on the downstream mixing. It is also shown that the fluid type has a major impact on the pressure drop across the mixer.

scholarly journals Research on Pressure Drop in the Accelerate Zone of Horizontal Conveying of Concrete Spraying

2019 ◽  
Vol 2019 ◽  
pp. 1-10 ◽  
Author(s):  
Guanguo Ma ◽  
Zhaoxia Liu ◽  
Xiaobing Gong ◽  
Lianjun Chen ◽  
Guoming Liu ◽  
...  
Keyword(s):  
Pressure Drop ◽  
Model Equation ◽  
Approximate Model ◽  
Momentum Equation ◽  
Experimental Results ◽  
Model Research ◽  
Proposed Model ◽  
Specific Position ◽  
Pressure Transmitter ◽  
Working Parameters

A pressure transmitter was installed at a specific position in a concrete conveying line to disclose the pressure drop when compressed air was conveyed during concrete spraying. A statistical analysis of the pressure at different positions was undertaken. Experimental results demonstrated that in the accelerate zone of horizontal conveying of concrete in the line, the pressure drop mainly occurred during the acceleration, collision, and friction processes. The momentum equation was introduced during the experiment, which interpreted the pressure drop caused by the accelerated conveying of concrete. The theoretical equation was corrected based on the results of theoretical experiments by introducing the value of α, and the experimental results were then optimized, thus obtaining an approximate model of pressure drop during the conveying of concrete. In addition, experimental results were compared with a model equation that showed the reliability of the proposed model. Research conclusions are of great significance to regulate the pressure drop in the conveying line of concretes, to design working parameters of concrete spraying devices, and to predict the ultimate distance for the conveying of concrete.

Roughness Effect on Pressure Drop for Electroosmotic (EO) Flow in Microtubes

2008 ◽  
Author(s):  
Hossein Shokouhmand ◽  
Maziar Aghvami ◽  
Mostafa Moghadami ◽  
Hamed Babazadeh
Keyword(s):  
Pressure Drop ◽  
Friction Factor ◽  
Electroosmotic Flow ◽  
Body Force ◽  
Momentum Equation ◽  
Wall Roughness ◽  
Roughness Effect ◽  
Isotropic Distribution ◽  
Poisson Boltzmann ◽  
Poisson Boltzmann Equation

This paper presents a theoretical model of the roughness effect on friction factor and pressure drop of fully developed, laminar flow in microtubes by considering the effect of the electrical double layer. The EDL potential distribution is calculated using the Poisson–Boltzmann equation and then the velocity profile is obtained by solving the fluid momentum equation with a body force term. The wall roughness in microtubes is modeled by utilizing a Gaussian, isotropic distribution. It is found that the effect of roughness is to increase the friction factor and pressure drop of the electroosmotic flow in microtubes.

Sampling and determination of gas-phase hydrogen peroxide following removal of ozone by gas-phase reaction with nitric oxide

1986 ◽  
Vol 58 (8) ◽  
pp. 1857-1865 ◽  
Author(s):  
Roger L. Tanner ◽  
George Y. Markovits ◽  
Eugene M. Ferreri ◽  
Thomas J. Kelly
Keyword(s):  
Nitric Oxide ◽  
Hydrogen Peroxide ◽  
Gas Phase ◽  
Phase Reaction ◽  
Gas Phase Reaction
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