Analysis of Carbon Black Particles Dispersion and Aggregation Behavior in Aqueous Suspension by using Colloid Probe AFM Method

2012 ◽  
Author(s):  
Hidehiro Kamiya ◽  
Youko Hanada ◽  
Syouichi Masuda ◽  
Motoyuki Iijima ◽  
Esko Kauppinen
Keyword(s):  
Carbon Black ◽  
Aqueous Suspension ◽  
Aggregation Behavior

scholarly journals MAS-NMR of [Pyr13][Tf2N] and [Pyr16][Tf2N] Ionic Liquids Confined to Carbon Black: Insights and Pitfalls

Molecules ◽  
2021 ◽  
Vol 26 (21) ◽  
pp. 6690
Author(s):  
Steffen Merz ◽  
Jie Wang ◽  
Petrik Galvosas ◽  
Josef Granwehr
Keyword(s):  
Ionic Liquids ◽  
Carbon Black ◽  
Porous Electrode ◽  
Magic Angle Spinning ◽  
Mas Nmr ◽  
Porous Electrodes ◽  
Aggregation Behavior ◽  
Magic Angle ◽  
Additional Parameter ◽  
Inversion Algorithm

Electrolytes based on ionic liquids (IL) are promising candidates to replace traditional liquid electrolytes in electrochemical systems, particularly in combination with carbon-based porous electrodes. Insight into the dynamics of such systems is imperative for tailoring electrochemical performance. In this work, 1-Methyl-1-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide and 1-Hexyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide were studied in a carbon black (CB) host using spectrally resolved Carr-Purcell-Meiboom-Gill (CPMG) and 13-interval Pulsed Field Gradient Stimulated Echo (PFGSTE) Magic Angle Spinning Nuclear Magnetic Resonance (MAS-NMR). Data were processed using a sensitivity weighted Laplace inversion algorithm without non-negativity constraint. Previously found relations between the alkyl length and the aggregation behavior of pyrrolidinium-based cations were confirmed and characterized in more detail. For the IL in CB, a different aggregation behavior was found compared to the neat IL, adding the surface of a porous electrode as an additional parameter for the optimization of IL-based electrolytes. Finally, the suitability of MAS was assessed and critically discussed for investigations of this class of samples.

Effect of Attapulgite and Carbon Black on the Properties of Natural Rubber

2010 ◽  
Vol 178 ◽  
pp. 92-96
Author(s):  
Mei Yang ◽  
Sheng Hu ◽  
Shang Yue Shen ◽  
Tie Li
Keyword(s):  
Electron Microscope ◽  
Carbon Black ◽  
Scanning Electron Microscope ◽  
Natural Rubber ◽  
Aqueous Suspension ◽  
Tensile Modulus ◽  
Rubber Composites ◽  
Natural Rubber Composites ◽  
Modified Attapulgite ◽  
Scanning Electron

The modified attapulgite / natural rubber composites (MANRC), attapulgite / natural rubber composites (ANRC) and carbon black N330 / natural rubber composites (CBNRC) were prepared by co-coagulating rubber latex and clay aqueous suspension,respectively. The modified attapulgite was attained by dispersion with an ultrasonic cell pulverizer first and then modification with cetyltrimethylammonium bromide (CTAB). The micrographs of field emission scanning electron microscope (FESEM) and environmental scanning electron microscope (ESEM) showed that the CTAB-modified attapulgite have the best dispersibility in the composites. The mechanical properties of MANRC are the best. The best properties of MANRC can be obtained when 20phrCTAB-modified attapulgite was added, the tensile strength, the 200% tensile modulus, the tear strength and Shore A hardness increased by 58.2%, 109.3%, 46.0%, 27.8%, respectively, compared with CBNRC.

Aggregation behavior of single-walled carbon nanotubes in dilute aqueous suspension

2004 ◽  
Vol 280 (1) ◽  
pp. 91-97 ◽  
Author(s):  
Quan Chen ◽  
Craig Saltiel ◽  
Siva Manickavasagam ◽  
Linda S. Schadler ◽  
Richard W. Siegel ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Aqueous Suspension ◽  
Single Walled Carbon Nanotubes ◽  
Aggregation Behavior ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

A Preparation of High Resolution Standards for Electron Microscopy. Part II

1971 ◽  
Vol 29 ◽  
pp. 160-161
Author(s):  
Akira Tanaka ◽  
David F. Harling
Keyword(s):  
Electron Microscopy ◽  
High Resolution ◽  
Carbon Black ◽  
Single Crystal ◽  
Dark Field ◽  
Graphitized Carbon Black ◽  
Graphitized Carbon ◽  
Dark Field Imaging ◽  
Crystal Films ◽  
Micro Holes

In the previous paper, the author reported on a technique for preparing vapor-deposited single crystal films as high resolution standards for electron microscopy. The present paper is intended to describe the preparation of several high resolution standards for dark field microscopy and also to mention some results obtained from these studies. Three preparations were used initially: 1.) Graphitized carbon black, 2.) Epitaxially grown particles of different metals prepared by vapor deposition, and 3.) Particles grown epitaxially on the edge of micro-holes formed in a gold single crystal film.The authors successfully obtained dark field micrographs demonstrating the 3.4Å lattice spacing of graphitized carbon black and the Au single crystal (111) lattice of 2.35Å. The latter spacing is especially suitable for dark field imaging because of its preparation, as in 3.), above. After the deposited film of Au (001) orientation is prepared at 400°C the substrate temperature is raised, resulting in the formation of many square micro-holes caused by partial evaporation of the Au film.

Extraction and identification of fillers and pigments from pyrolyzed rubber and tire samples

1996 ◽  
Vol 54 ◽  
pp. 174-175
Author(s):  
P. Sadhukhan ◽  
J. B. Zimmerman
Keyword(s):  
Zinc Oxide ◽  
Electron Microscope ◽  
Carbon Black ◽  
Natural Rubber ◽  
Transmission Electron Microscope ◽  
Rolling Resistance ◽  
Synthetic Polymers ◽  
Nitrogen Atmosphere ◽  
Transmission Electron ◽  
Curing Agents

Rubber stocks, specially tires, are composed of natural rubber and synthetic polymers and also of several compounding ingredients, such as carbon black, silica, zinc oxide etc. These are generally mixed and vulcanized with additional curing agents, mainly organic in nature, to achieve certain “designing properties” including wear, traction, rolling resistance and handling of tires. Considerable importance is, therefore, attached both by the manufacturers and their competitors to be able to extract, identify and characterize various types of fillers and pigments. Several analytical procedures have been in use to extract, preferentially, these fillers and pigments and subsequently identify and characterize them under a transmission electron microscope.Rubber stocks and tire sections are subjected to heat under nitrogen atmosphere to 550°C for one hour and then cooled under nitrogen to remove polymers, leaving behind carbon black, silica and zinc oxide and 650°C to eliminate carbon blacks, leaving only silica and zinc oxide.

TEM observation of iron oxide pillars in montmorillonite

1990 ◽  
Vol 48 (4) ◽  
pp. 882-883
Author(s):  
H. Mori ◽  
Y. Murata ◽  
H. Yoneyama ◽  
H. Fujita
Keyword(s):  
Aqueous Solution ◽  
Iron Oxide ◽  
Fine Particles ◽  
Aqueous Suspension ◽  
Volume Ratio ◽  
Exchange Capacity ◽  
Nano Composites ◽  
Pillared Montmorillonite ◽  
Topographic Features ◽  
Transmission Electron

Recently, a new sort of nano-composites has been prepared by incorporating such fine particles as metal oxide microcrystallites and organic polymers into the interlayer space of montmorillonite. Owing to their extremely large specific surface area, the nano-composites are finding wide application[1∼3]. However, the topographic features of the microstructures have not been elucidated as yet In the present work, the microstructures of iron oxide-pillared montmorillonite have been investigated by high-resolution transmission electron microscopy.Iron oxide-pillared montmorillonite was prepared through the procedure essentially the same as that reported by Yamanaka et al. Firstly, 0.125 M aqueous solution of trinuclear acetato-hydroxo iron(III) nitrate, [Fe3(OCOCH3)7 OH.2H2O]NO3, was prepared and then the solution was mixed with an aqueous suspension of 1 wt% clay by continuously stirring at 308 K. The final volume ratio of the latter aqueous solution to the former was 0.4. The clay used was sodium montmorillonite (Kunimine Industrial Co.), having a cation exchange capacity of 100 mequiv/100g. The montmorillonite in the mixed suspension was then centrifuged, followed by washing with deionized water. The washed samples were spread on glass plates, air dried, and then annealed at 673 K for 72 ks in air. The resultant film products were approximately 20 μm in thickness and brown in color.

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