scholarly journals Chemical characterization of commercial and single-variety avocado oils

2018 ◽  
Vol 69 (2) ◽  
pp. 256 ◽  
Author(s):  
G. D. Fernandes ◽  
R. B. Gómez-Coca ◽  
M. C. Pérez-Camino ◽  
W. Moreda ◽  
D. Barrera-Arellano
Keyword(s):  
Fatty Acids ◽  
Chemical Characterization ◽  
Complete Characterization ◽  
The Other ◽  
Principal Minor ◽  
Avocado Oil ◽  
Terpenic Alcohols ◽  
Minor Compounds ◽  
Single Variety

This work aimed to determine the major and minor compounds of avocado oils. Mono-varietal oils from the Bacon, Fuerte, Hass, and Pinkerton cultivars were obtained by means of an Abencor® system, while commercial oils from Brazil, Chile, Ecuador and New Zealand were purchased locally. The content of triacylglycerols, fatty acids, aliphatic and terpenic alcohols, desmethyl- methyl- and dimethyl-sterols, squalene and tocopherols were determined. The main triacylglycerols were those with ECN48. In addition, the oleic, palmitic and linoleic acids prevailed. Desmethyl-sterols were the principal minor compounds. Low amounts of aliphatic and terpenic alcohols were also found. Squalene concentrations were higher in Bacon, Fuerte and Pinkerton oils than in the other oils. The most abundant tocopherol was α-tocopherol. Partial least squares discriminant analysis made it possible to express the differences among the samples. To summarize, this work brings a different approach to the complete characterization of avocado oil.

scholarly journals Chemical Characterization of Major and Minor Compounds of Nut Oils: Almond, Hazelnut, and Pecan Nut

2017 ◽  
Vol 2017 ◽  
pp. 1-11 ◽  
Author(s):  
Gabriel D. Fernandes ◽  
Raquel B. Gómez-Coca ◽  
María del Carmen Pérez-Camino ◽  
Wenceslao Moreda ◽  
Daniel Barrera-Arellano
Keyword(s):  
Fatty Acids ◽  
Chemical Characterization ◽  
Principal Component ◽  
Principal Minor ◽  
New Approach ◽  
Terpenic Alcohols ◽  
Pecan Nut Oil ◽  
Minor Compounds ◽  
Sweet Almond

The aim of this work was to characterize the major and minor compounds of laboratory-extracted and commercial oils from sweet almond, hazelnut, and pecan nut. Oils from sweet almond, hazelnut, and pecan nut were obtained by means of an expeller system, while the corresponding commercial oils were provided from Vital Âtman (BR). The contents of triacylglycerols, fatty acids, aliphatic and terpenic alcohols, desmethyl-, methyl-, and dimethylsterols, squalene, and tocopherols were determined. Oleic, palmitic, and linoleic acids were the main fatty acids. Desmethylsterols were the principal minor compounds withβ-sitosterol being the most abundant component. Low amounts of aliphatic and terpenic alcohols were also found. The major tocopherol in hazelnut and sweet almond oils wasα-tocopherol, whereasγ-tocopherol prevailed in pecan nut oil. Principal component analysis made it possible for us to differentiate among samples, as well as to distinguish between commercial and laboratory-extracted oils. Heatmap highlighted the main variables featuring each sample. Globally, these results have brought a new approach on nut oil characterization.

Structural role of copper in the minerals of the pearceite-polybasite group: the case of the new minerals cupropearceite and cupropolybasite

2007 ◽  
Vol 71 (06) ◽  
pp. 641-650 ◽  
Author(s):  
L. Bindi ◽  
M. Evain ◽  
P. G. Spry ◽  
K. T. Tait ◽  
S. Menchetti
Keyword(s):  
Chemical Characterization ◽  
Sample Space ◽  
The Other ◽  
Crystal Chemical ◽  
Structural Position ◽  
Space Group ◽  
Cu Content ◽  
Own Name

Abstract The pearceite-polybasite group of minerals, general formula [M6T2S7][Ag9CuS4] with M = Ag, Cu; and T = As, Sb, show a crystal structure which can be described as the succession, along the c axis, of two pseudo-layer modules: a [M6T2S7]2– A module layer and a [Ag9CuS4]2+ B module layer. Copper is present in one structural position of the B module layer and replaces Ag in the only fully occupied M position of the A module layer. When the Cu content is >4.00 a.p.f.u., the structural position of the A module layer becomes Cu-dominant and, consequently, the mineral deserves its own name. In this paper we report the crystal-chemical characterization of two Cu-rich members exhibiting the 111 unitcell type (corresponding to the Tac polytype). One sample (space group (P )m1, a 7.3218(8), c 11.8877(13) Å, V 551.90(10) Å3, Z = 1) having As >Sb and with the structural position of the A module layer dominated by Cu, has been named cupropearceite and the other sample (space group (P3̄)m1, a 7.3277(3), c 11.7752(6) Å, V 547.56(8) Å3, Z = 1) having Sb >As has been named cupropolybasite. Both the new minerals and mineral names have been approved by the IMA-CNMNC.

Wastewater effluent characteristics from Moroccan textile industry

2013 ◽  
Vol 67 (12) ◽  
pp. 2791-2799 ◽  
Author(s):  
Y. Mountassir ◽  
A. Benyaich ◽  
M. Rezrazi ◽  
P. Berçot ◽  
L. Gebrati
Keyword(s):  
Textile Industry ◽  
Chemical Characterization ◽  
Textile Wastewater ◽  
Complete Characterization ◽  
Wastewater Effluent ◽  
The European Union ◽  
Physico Chemical ◽  
Standard Limit ◽  
Effluent Characteristics

The objectives of this work were to carry out a complete characterization of textile wastewater, resulting from a textile unit located in the Marrakesh region. A physico-chemical characterization has been performed, focused on organic and toxicological aspects. The cladoceran Daphnia magna was used as the sensor organism and lethal concentration as a criterion to measure the toxicity of textile wastewater. The physico-chemical and toxicological status of a local textile effluent showed considerable values limitation, when compared to the European Union standard limit and Moroccan guide level and other studies. In view of those characteristics, the wastewater effluent from the textile industry should be considered to be treated before discharge to the environment.

scholarly journals Chemical characterization of effective and ineffective strains of Rhizobium leguminosarum bv. viciae.

1999 ◽  
Vol 46 (4) ◽  
pp. 1001-1009
Author(s):  
S F Izmailov ◽  
G Y Zhiznevskaya ◽  
L V Kosenko ◽  
G N Troitskaya ◽  
N N Kudryavtseva ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Rhizobium Leguminosarum ◽  
Unsaturated Fatty Acids ◽  
Effective Strain ◽  
Chemical Characterization ◽  
Unsaturation Index ◽  
Fa Composition ◽  
Sds Page ◽  
Lower Molecular Mass

Chemical composition of lipopolysaccharide (LPS) isolated from an effective (97) and ineffective (87) strains of R. l. viciae has been determined. LPS preparations from the two strains contained: glucose, galactose, mannose, fucose, arabinose, heptose, glucosamine, galactosamine, quinovosamine, and 3-N-methyl-3,6-dideoxyhexose, as well as glucuronic, galacturonic and 3-deoxyoctulosonic acid. The following fatty acids were identified: 3-OH 14:0, 3-OH 15:0, 3-OH 16:0, 3-OH 18:0 and 27-OH 28:0. The ratio of 3-OH 14:0 to other major fatty acids in LPS 87 was higher that in LPS 97. SDS/PAGE profiles of LPS indicated that, in lipopolysaccharides, relative content of S form LPS I to that of lower molecular mass (LPS II) was much higher in the effective strain 97 than in 87. All types of polysaccharides exo-, capsular-, lipo, (EPS, CPS, LPS, respectively) examined possessed the ability to bind faba bean lectin. The degree of affinity of the host lectin to LPS 87 was half that to LPS 97. Fatty acids (FA) composition from bacteroids and peribacteroid membrane (PBM) was determined. Palmitic, stearic and hexadecenoic acids were common components found in both strains. There was a high content of unsaturated fatty acids in bacteroids as well as in PBM lipids. The unsaturation index in the PBM formed by strain 87 was lower than in the case of strain 97. Higher ratio of 16:0 to 18:1 fatty acids was characteristic for PMB of the ineffective strain.

Fine-grained weathering products in waste disposal from two sulphide mines in the northern Apennines, Italy

Clay Minerals ◽  
1998 ◽  
Vol 33 (3) ◽  
pp. 423-433 ◽  
Author(s):  
E. Dinelli ◽  
N. Morandi ◽  
F. Tateo
Keyword(s):  
Acidic Solution ◽  
Chemical Characterization ◽  
Northern Apennines ◽  
The Other ◽  
Blue Colour ◽  
Fine Grained ◽  
Surrounding Environment ◽  
Waste Rock Piles ◽  
Cu And Zn

AbstractFrom mineralogical and chemical characterization of two waste-rock piles from Vigonzano and Libiola sulphide mines in the northern Apennines, two types of fine-grained weathering products were recognized, One, from the Vigonzano mine, has a typical blue colour and consists of the Cu-Al sulphate of the woodwardite group. Its formation is related to an alkaline geochemical barrier, it is rather stable in acidic solution, and it controls Cu and Zn dispersion in the surrounding environment. The other group of sediments has a typical ochreous colour. Vigonzano samples consist mostly of goethite, whereas ferrihydrite is abundant in the Libiola sample. The ochreous sediments are enriched in Co, As, Mo, Se and Mn, thus significantly reducing the potential environmental hazard of the site, whereas solubility tests indicated possible problems due to AI dissolution at Libiola.

Chemical Characterization of the Essential Oils of Eucalyptus.grandis×Eucalyptus.urophylla Hybrids and Six Pure Eucalyptus species Grown in Guangxi (China)

2014 ◽  
Vol 1033-1034 ◽  
pp. 200-208
Author(s):  
Feng Lai Lu ◽  
Yue Yuan Chen ◽  
Jiao Hong Wei ◽  
Yong Lin Huang ◽  
Dian Peng Li ◽  
...  
Keyword(s):  
Essential Oils ◽  
Chemical Characterization ◽  
Hierarchical Cluster ◽  
The Other ◽  
Eucalyptus Species ◽  
Oil Composition ◽  
Pure Species ◽  
Species Analysis ◽  
Total Oil

Hydrodistillation of the fresh leaves of E.grandis×E.urophylla hybrids and pure species E.grandis, E.urophylla, E.pellita, E.camaldulensis, E. dunni, and E.saligna collected from the trees grown in Guangxi Huangmian Forest (China), afforded essential oils in yields varying from 0.24±0.15% to 5.36±0.28%, according to the species. Analysis by GC (FID) and GC/MS allowed the identification of 67 compounds, representing 82.55% to 91.03% of the total oil composition. The dominant compounds were 1,8-cineole in E.saligna, E.urophylla, E.grandis×E.urophylla, E.grandis, E.pellita and E. dunni (67.48, 57.12, 48.21, 23.64, 20.34, 20.22%), p-Cymene in E.camaldulensis,E. dunni and E.grandis(21.32, 14.74, 13.38%), α-pinene in E.grandis and E.grandis×E.urophylla (21.77, 15.55%), α-terpinene in E. dunni and E.grandis (17.96, 9.35%), α-terpineol in E.pellita and E.saligna (19.24,11.54%), respectively. Hierarchical Cluster Analysis separated the characterized essential oils into two groups, each constituting a chemotype. E.grandis×E.urophylla and E.urophylla were classified in the same group, while E.grandis in the other.

scholarly journals Quality characteristics and thermal behavior of buriti (Mauritia flexuosa L.) oil

2018 ◽  
Vol 68 (4) ◽  
pp. 220 ◽  
Author(s):  
M. L.F. Freitas ◽  
R. C. Chisté ◽  
T. C. Polachini ◽  
L. A.C.Z. Sardella ◽  
C. P.M. Aranha ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Thermal Behavior ◽  
Monounsaturated Fatty Acids ◽  
Complete Characterization ◽  
Total Carotenoids ◽  
Electronic Density ◽  
Mauritia Flexuosa ◽  
Buriti Oil ◽  
Β Carotene

This work reports a complete characterization of buriti oil. Physicochemical properties were determined according to AOCS methodologies and thermophysical properties were measured using a controlled stress rheometer and a digital electronic density meter. β-carotene and tocopherol contents were obtained using HPLC systems. Fatty acids and acylglycerol classes were determined using GC and HPSEC systems, respectively, while triacylglycerol composition was estimated using the software PrOleos. Thermal behavior (crystallization and melting) was analyzed using a DSC. The results attested high levels of total carotenoids with β-carotene as the major one; total tocopherols contained α- and β-tocopherols which accounted for 91% of the total; and monounsaturated fatty acids were mainly represented by oleic acid. The results showed close agreement between density and viscosity of buriti and olive oils. The crystallization and melting peaks occurred at -43.06 °C and -2.73 °C, respectively. These properties enable Buriti oil to be recommended as an excellent alternative for enriching foods with bioactive compounds.

scholarly journals Towards a Valorization of Corn Bioethanol Side Streams: Chemical Characterization of Post Fermentation Corn Oil and Thin Stillage

Molecules ◽  
2020 ◽  
Vol 25 (15) ◽  
pp. 3549 ◽  
Author(s):  
Gabriella Di Lena ◽  
Petra Ondrejíčková ◽  
Josè Sanchez del Pulgar ◽  
Veronika Cyprichová ◽  
Tomáš Ježovič ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Fatty Acid ◽  
Corn Oil ◽  
Chemical Characterization ◽  
Acid Value ◽  
Operating Conditions ◽  
Thin Stillage ◽  
Long Term Study ◽  
Starting Point

First-generation biofuel biorefineries may be a starting point for the development of new value chains, as their by-products and side streams retain nutrients and valuable molecules that may be recovered and valorized for high-value applications. This study provides a chemical characterization of post-fermentation corn oil and thin stillage, side streams of dry-grind corn bioethanol production, in view of their valorization. An overall long-term study was conducted on the two co-products collected over 1 year from a bioethanol plant. Water content, acid value, sedimentation, mineral composition, and fatty acid profiles were analyzed on post-fermentation corn oil. Results highlighted that its acid value was high (19.72–24.29 mg KOH/g), indicating high levels of free fatty acids, but stable over the year due to standardized operating conditions. The fatty acid profile was that typical of corn oil, with a prevalence of linoleic (54–59% of total fatty acids) over oleic (23–27%) and palmitic (12–17%) acids. Macronutrients, fatty acid, and mineral profiles were investigated in thin stillage. Results revealed the acidic pH (4.05–4.68) and high dilution (90–93% water) of this side stream. The dry mass was composed of fats (19–30%), proteins (8.8–12.8%), ash (8.7–9.5%), and fiber (7.3–9.8%). The concomitant presence of a variegate complex of molecules of nutritional interest in corn bioethanol co-products, with several potential high-value market applications, make the perspective of their recovery a promising strategy to create new cross-sector interconnections according to circular economy principles.

scholarly journals Complete Characterization of Extracts of Onopordum illyricum L. (Asteraceae) by HPLC/PDA/ESIMS and NMR

2008 ◽  
Vol 3 (12) ◽  
pp. 1934578X0800301 ◽  
Author(s):  
Luisella Verotta ◽  
Laura Belvisi ◽  
Vittorio Bertacche ◽  
Maria Cecilia Loi
Keyword(s):  
Fatty Acids ◽  
Nutritional Value ◽  
Biological Activities ◽  
Sesquiterpene Lactones ◽  
Mediterranean Area ◽  
Complete Characterization ◽  
Plant Metabolism ◽  
Aerial Parts ◽  
Different Parts

The aerial parts of Onopordum illyricum L. (Asteraceae) are eaten raw in salad in the Mediterranean area, representing a food of good nutritional value. Extracts of different parts of this plant have been analyzed by HPLC/DAD/ESIMS and the major compounds identified by NMR spectroscopy. Fatty acids, sesquiterpene lactones, triterpenes and polyphenols (flavones and caffeoyl quinic acids) fully describe the plant metabolism during the vegetation year. All the metabolites are non toxic nutrients, and are reported in the literature to possess biological activities positive for health, confirming the beneficial use in the diet of this thistle

Can letter position encoding be modified by visual perceptual elements?

2018 ◽  
Vol 72 (6) ◽  
pp. 1344-1353 ◽  
Author(s):  
Ana Marcet ◽  
Manuel Perea ◽  
Ana Baciero ◽  
Pablo Gomez
Keyword(s):  
Lexical Decision ◽  
Letter Position ◽  
Complete Characterization ◽  
The Other ◽  
Letter Position Coding ◽  
Position Coding ◽  
Visual Characteristics ◽  
Abstract Component ◽  
Perceptual Locus

A plethora of studies has revealed that letter position coding is relatively flexible during word recognition (e.g., the transposed-letter [TL] pseudoword CHOLOCATE is frequently misread as CHOCOLATE). A plausible explanation of this phenomenon is that letter identity and location are not perfectly bound as a consequence of the limitations of the visual system. Thus, a complete characterization of letter position coding requires an examination of how letter position coding can be modulated by visual perceptual elements. Here we conducted three lexical decision experiments with TL and replacement-letter pseudowords that manipulated the visual characteristics of the stimuli. In Experiment 1, each syllable was presented either in a different colour or monochromatically (e.g., [Formula: see text] vs. [Formula: see text]) with the transposition occurring across syllables. In Experiment 2, the critical letters had a consistent contrast or not (e.g., [Formula: see text] vs. [Formula: see text]). In Experiment 3, the stimuli were presented either simultaneously or serially, letter by letter (i.e., as occurs in braille reading). Results showed that whereas colouring differently each syllable only produced a small nonsignificant reduction of the TL effect, the other two manipulations—presenting the two critical letters with an altered contrast and presenting the letters one at a time—reduced, but did not eliminate, the magnitude of the TL effect relative to the regular format. Although these findings are consistent with models that postulate an early perceptual locus of the TL effect, the robustness of the TL effect suggests that letter position coding also has an orthographic abstract component.

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