Effect of Al2O3 and CaF2 on Melting Temperature of High Calcium Ladle Desulfurization Slag

2015 ◽  
Vol 1094 ◽  
pp. 325-328
Author(s):  
Wei Fan ◽  
Jin Zhu Zhang ◽  
Wan Zhong Ao ◽  
Jun Huang
Keyword(s):  
Melting Temperature ◽  
Orthogonal Design ◽  
Molten Iron ◽  
Iron And Steel ◽  
Melting Temperatures ◽  
High Calcium ◽  
Analytical Reagent ◽  
The Impact

The external desulphurization of molten iron has become an important step in the production of steel and iron. The melting temperatures of high calcium desulfurization slag, which were taken from Shougang Shuicheng Iron and Steel (Group) Co. Limited, were investigated on basis of the method of hemisphaerium temperature. The contents of CaO, Al2O3 and CaF2 in the slag were adjusted in 47%-53%, 14%-20% and 2%-10% respectively by adding analytical reagent Ca (OH)2, Al2O3 and CaF2 using orthogonal design. The results show that the melting temperature of desulfurization slag decreases obviously with the increase of the content of Al2O3 between 14% and 20%, and decreased markedly with the increase of the content of CaF2 lower than 8%. The impact to the melting temperature of the high calcium slag is as follows: Al2O3 > CaF2 > CaO.

Study on Viscosity of Titania Bearing Blast Furnace Slag

2011 ◽  
Vol 467-469 ◽  
pp. 1742-1745 ◽  
Author(s):  
Jin Zhu Zhang ◽  
Ling Wen ◽  
Ming Hua Long ◽  
Bi Neng Yang
Keyword(s):  
Blast Furnace ◽  
Blast Furnace Slag ◽  
Orthogonal Design ◽  
Al2o3 Content ◽  
Slag Viscosity ◽  
Iron And Steel ◽  
Analytical Reagent ◽  
Bf Slag ◽  
Furnace Slag

The viscosity of blast furnace slag which was taken from Shuicheng Iron and Steel Group Co. Limited was experimentally measured by column whirling method using the ND-II slag viscosity tester. By adding analytical reagent CaO, SiO2, Al2O3, MgO and TiO2 in accordance with orthogonal design, the contents of compositions in slag were adjusted in CaO/SiO2=1.16-1.24, 14.06-17.06mass%Al2O3, 5-7mass%TiO2, 8.96-9.96mass%MgO. The results showed that the viscosity of BF slag decreased with increasing TiO2; when the Al2O3 content in the slag was 14.06%, the viscosity of BF slag had a lowest value, a highest value had for 15.56% Al2O3 content, and a lower value for 17.06% Al2O3 content. There is no significant effect on the viscosity by both the magnesia and the binary basicity.

Effect of Calcium Fluoride and Magnesia on the Performance of Tundish Coverture Fluxes Made of Blast Furnace Slag

2013 ◽  
Vol 813 ◽  
pp. 96-99
Author(s):  
Zhao Hui Zhang ◽  
Bai Long Liu ◽  
Yun Ren
Keyword(s):  
Surface Tension ◽  
Blast Furnace ◽  
Melting Temperature ◽  
Calcium Fluoride ◽  
Blast Furnace Slag ◽  
Iron And Steel ◽  
Basic Performance ◽  
The Difference ◽  
The Impact ◽  
Furnace Slag

Preparation of the tundish coverture fluxes by the blast furnace slag can recycle utilization of solid wastes discharged from iron and steel industry. Calcium fluoride and magnesia can play an important role for the basic performance of tundish coverture fluxes. The impact on the melting temperature, viscosities and surface tension of the tundish coverture fluxes from the content of calcium fluoride and magnesia were studied. The results showed that: When the content of CaF2 increased from 10% to 25%, the melting temperature, the viscosity and the surface tension were decreased by 50°C, 0.3 Pa·S and 0.039 N/m respectively. The viscosity was brought down of 0.02 Pa·S, the surface tension was increased by 0.03 N/m, and the difference between the lowest and highest melting temperature was about 3°C when the content of MgO changed from 5% to 11%.

scholarly journals Management of Lime in Steel

Metals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 686 ◽  
Author(s):  
Sanjeev Manocha ◽  
François Ponchon
Keyword(s):  
Critical Role ◽  
Steel Production ◽  
Developed Countries ◽  
Basic Oxygen Furnace ◽  
Environmental Benefits ◽  
Steelmaking Process ◽  
Iron And Steel ◽  
Refractory Life ◽  
The Impact ◽  
Local Sourcing

The EU28 total lime demand in 2017 was estimated at about 20 million tons, out of which about 40% are consumed in the iron and steel industry. Steel remains the major consumer after environment and construction. The lime industry is quite mature and consolidated in developed countries, with enough reserves and production to serve regional markets while being fragmented in developing nations where steel producers rely on local sourcing. There is relatively very little trade for lime worldwide. Lime has a critical role at different steps of the steelmaking process, and especially to make a good slag facilitating the removal of sulphur and phosphorus, and for providing a safer platform to withstand high intensity arc plasma in the electric arc furnace (EAF), and violent reactions in the basic oxygen furnace (BOF). Lime quality and quantity has a direct effect on slag quality, which affects metallurgical results, refractory life, liquid metal yield, and productivity, and therefore the total cost of the steel production. In this paper, we present the importance of careful selection in the limestone and calcination process, which influences critical lime quality characteristics. We shall further elaborate on the impact of lime characteristics in the optimization of the steelmaking process, metallurgical benefits, overall cost impact, potential savings, and environmental benefits.

scholarly journals Does Emission Trading Improve Carbon Emission Efficiency of China’s Iron and Steel Industry? An Exploration Using a DEA-SBM and Difference-In-Differences Approach

2021 ◽  
Author(s):  
Xiping Wang ◽  
Sujing Wang
Keyword(s):  
Steel Industry ◽  
Carbon Emission ◽  
Emission Trading ◽  
Energy Structure ◽  
Iron And Steel Industry ◽  
Low Carbon ◽  
Difference In Differences ◽  
Iron And Steel ◽  
Emission Efficiency ◽  
The Impact

Abstract As an effective tool of carbon emission reduction, emission trading has been widely used in many countries. Since 2013, China implemented carbon emission trading in seven provinces and cities, with iron and steel industry included in the first batch of pilot industries. This study attempts to explore the policy effect of emission trading on iron and steel industry in order to provide data and theoretical support for the low-carbon development of iron and steel industry as well as the optimization of carbon market. With panel data of China’s 29 provinces from 2006 to 2017, this study adopted a DEA-SBM model to measure carbon emission efficiency of China’s iron and steel industry (CEI) and a difference-in-differences (DID) method to explore the impact of emission trading on CEI. Moreover, regional heterogeneity and influencing mechanisms were further investigated, respectively. The results indicate that: (1) China's emission trading has a significant and sustained effect on carbon abatement of iron and steel industry, increasing the annual average CEI by 12.6% in pilot provinces. (2) The policy effects are heterogeneous across diverse regions. Higher impacts are found in the western and eastern regions, whereas the central region is not significant. (3) Emission trading improves CEI by stimulating technology innovation, reducing energy intensity, and adjusting energy structure. (4) Economic level and industrial structure are negatively related to CEI, while environmental governance and openness degree have no obvious impacts. Finally, according to the results and conclusions, some specific suggestions are proposed.

The U. S.-Canada Free Trade Agreement: Impact on the U. S. Steel Industry

1994 ◽  
Vol 38 (1) ◽  
pp. 53-61 ◽  
Author(s):  
Harold R. Williams ◽  
Thomas J. Botzman
Keyword(s):  
Free Trade ◽  
Multiple Linear Regression Model ◽  
Trade Agreement ◽  
Single Equation ◽  
Steel Mill ◽  
Iron And Steel ◽  
Explanatory Variables ◽  
Income Elasticities ◽  
Price And Income Elasticities ◽  
The Impact

This study empirically estimates the impact of the U. S.-Canada FTA on specific iron and steel exports and imports using quarterly data for the period January 1981 to December 1990. A single equation multiple linear regression model is used to quantify at the industry and industry segment levels the impact of the agreement. The dependent variables are the quantities of major steel products traded between the two nations. The explanatory variables include foreign price adjusted for the exchange rate and tariff rate, domestic price, and the industrial production index. Results include calculation of price and income elasticities, which vary considerably by industry segments. The impact of free trade, as modeled, varies widely from product to product. As such it has important implications not only for government policy and employment but also for the adjustment problems faced by both the large integrated steel mill and the minimill producers.

The Impact of Technological Change on Incentive Provision

2009 ◽  
pp. 5-36
Author(s):  
Maurizio Lisciandra
Keyword(s):  
Technological Change ◽  
New Technology ◽  
Agency Problem ◽  
Optimal Solution ◽  
Jel Classification ◽  
High Rate ◽  
Incentive Pay ◽  
Iron And Steel ◽  
Piece Rate ◽  
The Impact

- The simple trade-off between incentive and risk, which is crucial to the agency problem, is not a sufficient explanation for the ineffectiveness of a specific output-related pay such as the contract system adopted in the US iron and steel industry during the second half of the nineteenth-century. The high rate of technological innovation along with workers' extensive bargaining power made output-related pay a sub-optimal solution. This stylised fact unveils the conflicting nature of piece-rate pay compared to fixed pay as new technology is introduced and stimulates an analysis of the interaction between technological change, bargaining powers, and payment systems which can be conducive to a better understanding of the agency problem and the use of incentive pay. Key words: Incentive Contracts, Inside Contracting, Unions, Technological Change. JEL Classification: J33, J51, N31, O33

Preparation by solution mixing and characterization of condensation type poly(dimethyl siloxane)/graphene nanoplatelets composites

2021 ◽  
pp. 002199832110558
Author(s):  
Panayiotis Ketikis ◽  
Efthimios Damopoulos ◽  
Georgios Pilatos ◽  
Panagiotis Klonos ◽  
Apostolos Kyritsis ◽  
...  
Keyword(s):  
Graphene Nanoplatelets ◽  
Matrix Composites ◽  
Dielectric Relaxation Spectroscopy ◽  
X Ray Diffraction ◽  
Scanning Calorimetry ◽  
Melting Temperatures ◽  
Dimethyl Siloxane ◽  
Diffraction Patterns ◽  
The Impact

The impact of the incorporation of graphene nanoplatelets (GN) on the properties of hydroxyl-terminated poly(dimethylsiloxane) (PDMS) matrices was investigated. The composites were prepared by solution mixing, using tetrahydrofuran (THF) as a solvent. Brookfield viscosimetry, implemented during the vulcanization process, revealed that GN increases the viscosity of the system, compared to pristine PDMS, proportionally to its concentration. X-ray diffraction patterns suggested an efficient dispersion of GN in the polysiloxane matrix. The D and G bands ratio (ID/IG) calculation, based on RAMAN spectra of GN/PDMS specimens, revealed more defects in graphene nanoplatelets when incorporated in the PDMS matrix. By differential scanning calorimetry (DSC), a marginal increase in crystallization, glass transition and melting temperatures of PDMS in GN/PDMS composites was observed. Improvement of the thermal stability of LMW PDMS composites, especially for higher GN concentrations (3 and 5 phr), was noticed by thermogravimetric analysis (TGA). Additionally, GN enhanced the tensile strength of composites, up to 73% for the 3 phr GN/LMW PDMS composite. A significant increase in the elongation at break was recorded, whereas no effect on the modulus of elasticity was recorded. The decrease in toluene-swelling, for the LMW PDMS matrix composites, was attributed to the increase in the tortuosity path because of the efficient dispersion of GN. A decrease in oxygen permeability of 55–65% and 44–58% was measured in membranes made of PDMS composites containing 0.5 phr and 1 phr GN, respectively. Dielectric relaxation spectroscopy (DRS) measurements recorded a significant increase in the conductivity of the higher graphene content composites.

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