A Combined Electrocoagulation-Electrooxidation Treatment on CTMP Wastewater

2011 ◽  
Vol 233-235 ◽  
pp. 619-622 ◽  
Author(s):  
Zhi Jun Hu ◽  
You Ming Li

A synergistic combination of electrocoagulation and electrooxidation was introduced for the treatment of CTMP wastewater in which most of the colloids and charged species had been removed by electrocoagulatio, then small organics could be mineralized by electrooxidation effectively.The mainly influencing factors for electrocoagulation such as electrolyte, sodium chloride dosage, voltage intensity, current intensity and reaction time were assessed. The optimum conditions were obtained, and the results showed that sodium chloride dosage of 1g/L, voltage intensity of 7.5V, current intensity of 0.6A, 60 min reaction time, its color removal rate was above 90% and CODCr removal rate was about 40%. After electrocoagulation the electrooxidation could further reduce CODCr above 80%.

2012 ◽  
Vol 433-440 ◽  
pp. 4751-4756 ◽  
Author(s):  
Hao Wu ◽  
Zi Fu Li ◽  
Xin Jin ◽  
Xin Zhao ◽  
Fu Rong Deng

Secondary effluent from WWTPS still contains a large number of microorganisms, therefore, disinfection is essential. There are many disadvantages in using traditional disinfection methods, so the combination of disinfection techniques is a new research direction. Ozone combined with ultrasound is one of them. In this experiment, the inactivation of the total coli forms, color removal and UV254 removal of secondary effluent by a combination of ultrasonic (frequency20 kHz; power100W) and ozone disinfection was investigated. The results show that the effect of the synergistic action of 30s US and ozone disinfection is superior to the effect of individual ozone disinfection. After 15min synergistic disinfection, the total coli forms inactivation rate is up to 99.9%, simultaneously color removal rate to 80% and UV254 removal rate to 52%. Compared with individual ozone disinfection, reaction time was reduced by 5 min.


2014 ◽  
Vol 522-524 ◽  
pp. 192-195 ◽  
Author(s):  
Shan Hong Lan ◽  
Ping Ma ◽  
Hui Xia Lan ◽  
Heng Zhang ◽  
Xiu Wen Wu ◽  
...  

The laboratory-made dicyandiamide formaldehyde polymer is used to study the effect of the flocculation treatment of simulated wastewater of You Li Su-hong EB. And the influencing factors mainly include flocculant dosage, pH and temperature. The experimental results show that when the dicyandiamide formaldehyde flocculant dosage is 8mL / L and pH is acidic or neutral, COD and color removal rate are the highest that have reached more than 70%. Besides, temperature has little effect on the flocculation treatment, and room temperature is enough to make the treatment effect good. Finally compared with the commonly used flocculant PAC, dicyandiamide formaldehyde polymer treatment effect is better with less addition.


2011 ◽  
Vol 415-417 ◽  
pp. 438-441
Author(s):  
Jin Xia Yan ◽  
Dong Fang Li ◽  
Shao Feng Dong

The printing and dyeing wastewater was treated by internal electrolysis method. The results show the chromaticity removal rate was up to 98.53 percent and COD removal rate 85.98 percent under the optimum conditions of wastewater pH 4, reaction time 30 minutes, the electric conductivity 1450μm/cm, the value BOD5/COD increases from 0.34 to 0.51. Moreover, the pH, Fe2+ concentration and absorbance of wastewater changed in the process, the mechanism of that was also analyzed.


2012 ◽  
Vol 610-613 ◽  
pp. 2367-2371 ◽  
Author(s):  
Ming Zhong Hu ◽  
Zhen He Shi ◽  
Hong Yan Zhao

The effects of the oxidation of potassium ferrate and the flocculation on cresol wastewater water were evaluated. This research aimed at determining the optimum conditions for the COD removal rate duing cresol wastewater water process. The results showed that potassium ferrate dosage of 1.1g/L, the pH value of 5, reaction time 15min, m-cresol initial concentration of 200 mg/L were the optimum conditions. Under the optimum conditions, COD removal rate was over 67%.


2016 ◽  
Vol 5 (3) ◽  
Author(s):  
Hongzhou Ma ◽  
Chao Yan ◽  
Yaoning Wang

AbstractIn this paper, the removal of arsenic from arsenic-bearing gold ore through air oxidation and sodium hydroxide leaching with microwave irradiation was studied. Firstly, single-factor experiments were carried out. The results indicated that the removal rate of arsenic was influenced by the sodium hydroxide concentration, ratio of liquid to solid, microwave power, and reaction time. Then, orthogonal experiments were done to determine the main influencing factors. The results obtained from the experiments of orthogonal arrays showed that reaction time and microwave power were the important influencing factors, and the optimum conditions of sodium hydroxide concentration, reaction time, microwave power, and ratio of liquid to solid were 18 wt.%, 60 min, 700 W, and 5, respectively. Under the optimal conditions, the removal of arsenic could reach approximately 81.46 wt.% and, at the same conditions, the sulfur removal rate was about 55.56 wt.%. The results of X-ray diffraction analysis revealed that AsS and FeAsS were decomposed during the leaching process, while FeS


2014 ◽  
Vol 1015 ◽  
pp. 369-372
Author(s):  
Chang You Song ◽  
Ai Bing Wu

In this paper, graft copolymer of starch-acrylamid-propylene hydroxamic acid was synthesized by inverse emulsion polymerization. Effects of the dosage of the graft copolymer, pH value and reaction time on the capability of trapping heavy metal ion Pb2+ were investigated. The results showed that the optimum conditions for treating lead-containing wastewater were: pH=7-9, reaction time≧30min , the dosage of polymeric ferric sulfate and graft copolymer in wastewater were 10mg·L-1 and 250-300mg·L-1, respectively. The Pb2+ removal rate is not less than 99.8% and meanwhile the copolymer possess good removal performance of turbidity.


2013 ◽  
Vol 726-731 ◽  
pp. 2515-2520 ◽  
Author(s):  
De Min Yang ◽  
Jian Mei Yuan

Advanced treatment of biochemical treated coking wastewater was studied experimentally with ozonation process. The effects of initial pH value, ozone concentration, reaction temperature, and reaction time on the COD and color removal rate were investigated. The results showed that ozonation was an effective method for advanced treatment of biochemical treated coking wastewater. The increasing of initial pH value, ozone concentration, reaction temperature, and reaction time has enhanced the removal rate of COD and color. Meanwhile, the results also revealed that the maximal COD and color removal rate of 69.65% and 92.27% could be reached under the optimal conditions of the initial pH value is 10.5, ozone concentration is 150 mg/L, reaction temperature is 298 K, and reaction time is 30 min.


2013 ◽  
Vol 838-841 ◽  
pp. 2445-2448 ◽  
Author(s):  
Zheng Hua Wang ◽  
Bo Zhi Ren ◽  
Pu Wang

Decolorization of the Mordant red 15 dye in water was investigated in laboratory-scale experiments using potassium ferrate (VI). The effect of corresponding parameters such as reaction time, concentration of potassium ferrate, pH values and the addition of H2O2 were considered in the experiments. The results indicated that about 78% dye decolorization was obtained in less than 30 min under optimum conditions. The pH values and concentration of ferrate (VI) were correlated with color removal rate of Mordant red 15 dye. The optimum pH value and ferrate (VI) concentration are 5 and 450 mg/L, respectively. Addition of H2O2 could initiate the Fenton reaction and result in 84.46% decolorization of dye in 30 min. Due to high ability of oxidizing and flocculation, potassium ferrate (VI) is an effect way for treatment of dyes in water.


Water ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 1732
Author(s):  
Yuanyuan Yu ◽  
Yongjun Sun ◽  
Jun Zhou ◽  
Aowen Chen ◽  
Kinjal J. Shah

In this study, a high-efficiency magnetic heavy metal flocculant MF@AA was prepared based on carboxymethyl chitosan and magnetic Fe3O4. It was characterized by SEM, FTIR, XPS, XRD and VSM, and the Cu(II) removal rate was used as the evaluation basis for the preparation process. The effects of AMPS content, total monomer concentration, photoinitiator concentration and reaction time on the performance of MF@AA flocculation to remove Cu(II) were studied. The characterization results show that MF@AA has been successfully prepared and exhibits good magnetic induction characteristics. The synthesis results show that under the conditions of 10% AMPS content, 35% total monomer concentration, 0.04% photoinitiator concentration, and 1.5 h reaction time, the best yield of MF@AA is 77.69%. The best removal rate is 87.65%. In addition, the response surface optimization of the synthesis process of MF@AA was performed. The optimal synthesis ratio was finally determined as iron content 6.5%, CMFS: 29.5%, AM: 53.9%, AMPS: 10.1%. High-efficiency magnetic heavy metal flocculant MF@AA shows excellent flocculation performance in removing Cu(II). This research provides guidance and ideas for the development of efficient and low-cost flocculation technology to remove Cu(II) in wastewater.


Agriculture ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 377
Author(s):  
Moo-Joon Shim ◽  
Seung-Mok Lee

Cu and Zn are known to be abundant in swine feces; hence, concentrations of these metals need to be lowered before swine feces are applied to land in order to prevent potential environmental problems. The main objective of this study was to develop an appropriate chemical process to remove Cu and Zn from swine feces using acid extractions. The removal efficiencies of Cu and Zn decreased in the order of H2SO4 > HNO3 > organic acids (citric and oxalic acids). Owing to the highest removal efficiencies of Cu and Zn by using H2SO4, it was selected for further elimination of Cu and Zn from swine feces. By using H2SO4, the optimal concentration, solid-to-liquid ratio, and reaction time were 2%, 1:50, and 8 h, respectively. At the optimum conditions, Cu concentration was decreased from 198 mg/kg to 40.1 mg/kg and Zn concentration from 474 mg/kg to 80.0 mg/kg, with removal rates of 79.7% and 83.1%, respectively. The low Cu removal efficiency, resulting from the strong complexation between Cu and organic matter of swine feces, was improved by the increase in the reaction time and H2SO4 solution concentrations. However, about half of the total nitrogen (TN) was also removed by using H2SO4, indicating that the swine feces treated with H2SO4 may have poor value as fertilizer. Additional studies are required to find an optimal method to maintain TN concentrations while simultaneously removing Cu and Zn.


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