Adsorption of Cu(II) Ions from an Aqueous Solution by Cross-Linked Carboxymethyl Konjac Glucomannan

2011 ◽  
Vol 239-242 ◽  
pp. 2310-2316 ◽  
Author(s):  
Chun Mei Niu ◽  
Shao Ying Li ◽  
Dong Huang
Keyword(s):  
Adsorption Capacity ◽  
Copper Nitrate ◽  
Konjac Glucomannan ◽  
Ion Adsorption ◽  
Adsorption Time ◽  
Isotherm Equation ◽  
Langmuir Isotherm Equation ◽  
Effects Of Ph ◽  
The Relationship ◽  
Carboxymethyl Konjac Glucomannan

Crosslinked Carboxymethyl Konjac Glucomannan(CMKGM) with substitution degrees ofcarboxymethyl group（DS）0.265, 0.457 and 0.586 were prepared through reaction of monochloroacetic acid, konjac glucomannan(KGM) and epichlorohydrin and used to adsorb Cu(II) from the aqueous solutions of copper nitrate. The effects of pH, adsorbent dose, initial concentration of Cu(II), adsorption time and temperature on adsorption capacity were investigated. The results showed that adsorption capacity increased with an increasing DS of the carboxymethyl groups. Equilibrium adsorption time was 20 min or so and was independent on DS. The adsorption followed Langmuir isotherm equation. Ligand ion adsorption between carboxymethyl group and Cu(II) was thought to be predominate in the process of adsorption according to the relationship between DS and thermodynamic parameters. CMKGM can be used as cheaper and more effective adsorbents.

The Effectiveness Adsorption of Au(III) and Cu(II) Ion by Mangosteen Rind (Garcinia mangostana L.) Using Point of Zero Charge Calculation

2020 ◽  
Vol 840 ◽  
pp. 10-15
Author(s):  
Dian Hana Saraswati ◽  
Mellia Harumi ◽  
Triyono Triyono ◽  
Sri Sudiono
Keyword(s):  
Adsorption Capacity ◽  
Ph Value ◽  
Point Of Zero Charge ◽  
Garcinia Mangostana ◽  
Isotherm Equation ◽  
Solid Adsorbent ◽  
Zero Charge ◽  
Before And After ◽  
Langmuir Isotherm Equation ◽  
Gold Metal

Adsorption of Au(III) and Cu(II) by mangosteen rind adsorbent had been carried out. Mangosteen rind has several functional groups including –OH phenolics, ‒C=C‒ aromatics, and ethers. Dried mangosteen rind which was obtained from maceration was used to determine Point of Zero Charge (PZC). The most effective pH adsorption was determined by mixing adsorbent with Au(III) or Cu(II) solutions with various pH. The adsorption capacity was affected by the interaction between adsorbent and adsorbate. The solid adsorbent before and after interaction was characterized by FTIR, XRD, and microphotography. The PZC pH value of adsorbent was 3.7 while the optimum pH for Au(III) and Cu(II) were at pH 2 and pH 5, respectively. The adsorption capacity (qmax) value was 333.33 mg/g by following the Langmuir isotherm equation. The crystalline structure of adsorbent was analyzed using XRD and gave 4 peaks characteristics of gold metal on 2ϴ = 38º, 44º, 64º, and 77º after adsorption which indicated the reduction of Au(III) ions into Au(0).

Adsorption Study of Reactive Dyes on Cotton Fabric in Non-Aqueous Systems

2012 ◽  
Vol 550-553 ◽  
pp. 671-675 ◽  
Author(s):  
Shi Xiong Yi ◽  
Yong Chun Dong
Keyword(s):  
Adsorption Capacity ◽  
Cotton Fabric ◽  
Reverse Micelle ◽  
Adsorption Property ◽  
Reactive Dyes ◽  
Reactive Dye ◽  
Water Soluble ◽  
Ionic Surfactant ◽  
Isotherm Equation ◽  
Langmuir Isotherm Equation

Abstract: The non-ionic reverse micelles used for dyeing cotton fabric were prepared with a non-ionic surfactant Triton X-100 (TX-100) by injecting small amount of reactive dye aqueous solution. The effect of electrolyte on the adsorption capacity of reactive dyes onto cotton fabric in this system was studied. And the adsorption properties of three water-soluble anionic azo dyes including Reactive Blue 222, Reactive Red 195 and Reactive Yellow 145 onto cotton fabric in TX-100 reverse micelle were also studied and compared. The results indicated that reactive dyes showed a better adsorption property on cotton fabric in TX-100 reverse micelle without the addition of NaCl. The adsorption of the dyes onto cotton showed better agreement with Langmuir isotherm equation. Reactive Yellow 145 with lower negative charge and higher hydrophilicity exhibited the higher adsorption capacity than the other dyes. The adsorption process follows by the chemical adsorption.

Preparation and Chelating Properties of Polystyrene Modified Ethoxycarbonyl Thiourea Resin

2011 ◽  
Vol 239-242 ◽  
pp. 781-785 ◽  
Author(s):  
Shuai Wang ◽  
Hong Zhong ◽  
Liu Yin Xia ◽  
Zhong Nan Wang ◽  
Qian Zhang
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Capacity ◽  
Maximum Adsorption Capacity ◽  
Polymer Grafting ◽  
Isotherm Equation ◽  
Adsorption Capacities ◽  
Adsorption Data ◽  
Separation Factors ◽  
Langmuir Isotherm Equation ◽  
Freundlich Adsorption Isotherm

A novel polystyrene modified ethoxycarbonyl thiourea resin(PSETU) was synthesized by polymer grafting of aminated polystyrene and ethoxycarbonyl isothiocyanate. The adsorption capacities of PSETU follow the order: Au(III) > Cu(II) > Zn(II) > Ni(II) > Fe(III) > Ca(II) ≈ Mg(II). The adsorption capacity for Au(III) increases with the increase of contact time, temperature and initial concentration of Au(III). The adsorption data fit Boyd’s diffusion equation of liquid film, Langmuir adsorption isotherm and Freundlich adsorption isotherm. The maximum adsorption capacity of PSETU calculated by Langmuir isotherm equation is 3.485 mmol/g, and the separation factors of PSETU for Au(III)-base metal ions are above 380. According to XPS results, the functional atoms of PSETU coordinate with Au(III) during the adsorption process.

scholarly journals Removal of Pb(II) in Aqueous Solutions Using Synthesized Zeolite X from Ecuadorian Clay

2021 ◽  
Vol 41 (2) ◽  
pp. e89671
Author(s):  
Daniel F Medina ◽  
Delly M San Martin ◽  
Carmen Milena López ◽  
Luis V García ◽  
Silvio D Aguilar ◽  
...  
Keyword(s):  
Aqueous Solutions ◽  
Kinetic Mechanism ◽  
Fusion Method ◽  
X Ray Diffraction ◽  
Zeolite X ◽  
X Ray ◽  
Isotherm Equation ◽  
Langmuir Isotherm Equation ◽  
Effects Of Ph ◽  
Equilibrium Data

Zeolite X was synthesized from clay using the alkaline fusion method and hydrothermal treatment to remove Pb(II) in aqueous solutions. Clay and zeolite were characterized through X-ray diffraction and fluorescence (XRD, FRX), as well as through specific surface area (SSA). The adsorbents were prepared as cylindrical extrudates using clay and a clay-zeolite combination (60-40%, respectively). The effects of pH, isotherm, and adsorption kinetics on the removal of Pb(II) in solutions of 80 mg Pb(II)/L were studied. It was possible to obtain a zeolite X from clay, with an SSA of 376 m2/g, 30 times greater than that of clay (12 m2/g). In the combined extrudate was present the zeolitic structure, with an SSA 12 times higher compared to the clay extrudate. The adsorption capacity, at 30 °C and V/m ratio of 1 g/L, is almost double compared to the clay extrudate (24 mg Pb(II)/g vs. 13 mg Pb(II)/g). Adsorption follows second order kinetics, and the Langmuir isotherm equation showed a good fit with the experimental equilibrium data for the two extrudates. The Webber-Morris and Bangham-Burt’s models suggest that pore and film diffusion influence the kinetic mechanism.

scholarly journals MODEL ISOTERM FREUNDLICH DAN LANGMUIR OLEH ADSORBEN ARANG AKTIF BAMBU ANDONG (G. verticillata (Wild) Munro) DAN BAMBU ATER (G. atter (Hassk) Kurz ex Munro)

2017 ◽  
Vol 2 (1) ◽  
pp. 17 ◽  
Author(s):  
Murtihapsari Murtihapsari ◽  
Bertha Mangallo ◽  
Dini Dwi Handyani
Keyword(s):  
Adsorption Capacity ◽  
Activated Charcoal ◽  
Langmuir Isotherm ◽  
Physical Adsorption ◽  
Regression Coefficients ◽  
Maximum Adsorption Capacity ◽  
Optimum Conditions ◽  
Isotherm Equation ◽  
Freundlich Isotherms ◽  
Langmuir Isotherm Equation

Freundlich and Langmuir Isotherms Model by Active Chorcoal Adsorbent Bamboo Andong  (G. verticillata (Wild) Munro) and Bamboo Ater (G. atter (Hassk) Kurz ex Munro)          Diazinon insecticide adsorption by two types of adsorbent, namely activated charcoal bamboo andong (G. verticillata (Wild) Munro) and bamboo ater (G. atter (Hassk) Kurzex Munro) at optimum conditions determined the maximum adsorption capacity of both types of adsorbent. Data analysison the effect of concentration on the adsorption capacity was used Langmuir and Freundlich isotherms equation. It was obtained. That  the curve of adsorption isotherms of the Langmuir isotherm better modeled with linear regression coefficients were relatively more approach 1 is R2 = 0,996 for both types of adsorbents. Langmuir isotherm equation obtained from adsorpsi maximum capacity of activated charcoal bamboo andong (G. verticillata (Wild) Munro) of  4.630 mg/g (1,433.10-5 mol/g) with K = 0,332 (Kmol/L)-1 and Eads at -2,750 kJ/mol, while the activated charcoal bamboo ater (G. atter (Hassk) Kurzex Munro) produce the maximum adsorption capacity of 1,786 mg/g (5,868.10-6 mol/g) with K = 0,202 (Kmol/L)-1 and Eads = -3,898 kJ/mol, so the adsorption of both types of adsorbents indicated experiencing a physical adsorption (physisorption / fisisorpsi).Keyword: G. verticillata (Wild) Munro, G. atter (Hassk) Kurz ex Munro, Adsorption, Diazinon,  actived charcoal  ABSTRAK          Adsorpsi insektisida diazinon oleh dua jenis adsorben, yaitu arang aktif bambu andong (G. verticillata (Wild) Munro) dan bambu ater (G. atter (Hassk) Kurz ex Munro) pada kondisi optimum bertujuan untuk menentukan kapasitas adsorpsi maksimum dari kedua jenis adsorben. Analisis data pengaruh konsentrasi terhadap kapasitas adsorpsi digunakan persamaan isoterm Langmuir dan Freundlich. Berdasarkan data yang diperoleh, kurva isoterm adsorpsi lebih mengikuti model isoterm Langmuir dengan koefisien regresi linier yang relatif lebih mendekati 1 yaitu R2 = 0,996 untuk kedua jenis adsorben. Dari persamaan isoterm Langmuir diperoleh kapasitas adsorpsi maksimum arang aktif bambu andong (G. verticillata (Wild) Munro) sebesar 4,630 mg/g (1,433.10-5 mol/g) dengan K = 0,332 (Kmol/L)-1 dan Eads sebesar -2,750 kJ/mol, sedangkan arang aktif bambu ater (G. atter (Hassk) Kurz ex Munro) menghasilkan kapasitas adsorpsi maksimum sebesar 1,786 mg/g (5,868.10-6 mol/g) dengan K = 0,202 (Kmol/L)-1 dan Eads = -3,898 kJ/mol, sehingga adsorpsi kedua jenis adsorben diindikasikan mengalami adsorpsi secara fisik (physisorption/ fisisorpsi).Kata kunci : G. verticillata (Wild) Munro, G. atter (Hassk) Kurz ex Munro Adsorpsi, Diazinon, Arang aktif

Kinetic Study on Phosphorus Adsorption, Phosphorus Desorption, Nitrification, and Denitrification by Using Mineralized Refuse

2011 ◽  
Vol 340 ◽  
pp. 461-466
Author(s):  
Ding Long Li ◽  
Jing Si Tian ◽  
Hou Hu Zhang ◽  
Yi Min Zhang ◽  
Yue Xiang Gao
Keyword(s):  
Adsorption Capacity ◽  
Langmuir Isotherm ◽  
Maximum Adsorption Capacity ◽  
Phosphorus Adsorption ◽  
K Value ◽  
Isotherm Equation ◽  
Zero Order Kinetics ◽  
Langmuir Isotherm Equation ◽  
Nitrification And Denitrification ◽  
Phosphorus Desorption

The mineralized refuse has a well particle size distribution and is similar asirregularly polyhedron with the high contents of Fe, Al, and Ca, which might be thephosphorus pool. The absorption and desorption of phosphorus, nitrification, and denitrification in the mineralized refuse and clay has been investigated by using batch incubation, respectively. The variation of phosphorous adsorption in the mineralized refuse and clay is fitted the Langmuir isotherm equation. The maximum phosphorus adsorption capacity in the mineralized refuse calculated based on the Langmuir isotherm equation is 2914 mg kg-1. Both the maximum adsorption capacity and adsorption rate of phosphorus in the mineralized refuse are over 2.0-fold more than that of the clay. The desorption rate of phosphorus in the mineralized refuse is only about 30%. NH4+-N contents in the mineralized refuse samples fell from 129 mg N kg-1 to 83.0 mg N kg-1 within the first 24 h during the nitrification process. Accordingly, the NO3--N content in the mineralized increased from 137 mg N kg-1 to 170 mg N kg-1. While the decrease of NH4+-N contents and the increase of NO3--N contents in the clay was only 1/2 and 1/6 as large as in the mineralized refuse, respectively. During the denitrification process, the K-value of the fitted zero-order kinetics for NO3--N denitrification in the mineralized refuse was 6.5-fold higher than in the clay.

Study on the Adsorption of Mixed Cd(II) and Pb(II) Ions by N,O-Carboxymethyl-Chitosan

2011 ◽  
Vol 236-238 ◽  
pp. 2523-2528
Author(s):  
Shan Shan Cheng ◽  
Chao Hua Zhang ◽  
Xi Hong Yang ◽  
Wan Cui Xie
Keyword(s):  
Metal Ions ◽  
Adsorption Capacity ◽  
Metal Ion ◽  
Ph Value ◽  
Carboxymethyl Chitosan ◽  
Effect Of Temperature ◽  
Mixed Solution ◽  
Isotherm Equation ◽  
Mixed Aqueous Solution ◽  
Langmuir Isotherm Equation

TheN,O-carboxymethyl-chitosan (N,O-CMC) was used to investigate the adsorptions of two metals of Cd(Ⅱ) and Pb(Ⅱ) ions in an mixed aqueous solution. The effects on adsorption capacities such as pH value, temperature, adsorbent dose and initial metal ion concentrations were investigated, and the dialysis method was applied to separate the materials after adsorption. The results revealed that the better adsorption ofN,O-CMC for Cd(Ⅱ) and Pb(Ⅱ) ions at the pH 7-8; the effect of temperature on the adsorption was not significant; the absorption of Cd(Ⅱ) and Pb(Ⅱ) ions was enhanced with the increase ofN,O-CMC amount; the adsorption capacity increasesed with the addition of the concentration of initial metal ions in the aqueous phase. The adsorption of Pb(Ⅱ) ion in Cd-Pb mixed solution on theN,O-CMC was well followed as the Langmuir isotherm equation under the concentration range studied, and Cd(Ⅱ) ion was corresponding to Langmuir adsorption equation in 100-200 mg/L and 200-500 mg/L, respectively. Conclusion:N,O-CMC was suitable for adsorbent to removal Cd(Ⅱ) and Pb(Ⅱ) ions, but it can selectively adsorption ions from the mixed solution, the adsorption capacity (Qm) for two metal ions was as follows: Pb(Ⅱ) > Cd(Ⅱ).

Adsorption Characteristics of Directly Modified Bentonite

2013 ◽  
Vol 826 ◽  
pp. 263-266
Author(s):  
Gui Ping Wang ◽  
Gui Yan Wang ◽  
Chun Yan Cao
Keyword(s):  
Methylene Blue ◽  
Methyl Orange ◽  
Classical Method ◽  
Equilibrium Concentration ◽  
Ammonium Bromide ◽  
Modified Bentonite ◽  
Isotherm Equation ◽  
Langmuir Isotherm Equation ◽  
Cetyl Trimethyl Ammonium ◽  
The Relationship

Directly modified bentonite was obtained by directly adding modifier cetyl trimethyl ammonium bromide (CTMAB) to sodium bentonite.The modified bentonites adsorption performance to methyl orange and methylene blue was studied, and it was compared with modified bentonite prepared by classical method. The results show that directly modified bentonite has a greater and faster absorption for both methyl orange and methylene blue; the relationship between adsorption quantity and equilibrium concentration conforms to the Langmuir isotherm equation; absorption kinetics is in accordance with the secondary dynamics equation.

Study on Synthesis and Properties of Spinel Structure Li1+xMn2-xO4 for Lithium Ion-Sieve Precursor

2013 ◽  
Vol 437 ◽  
pp. 560-563
Author(s):  
Shi Tao Song ◽  
Su Xia Wu ◽  
You Shun Peng ◽  
Xue Fang Zheng ◽  
Qi Lian
Keyword(s):  
Adsorption Capacity ◽  
Spinel Structure ◽  
Ph Value ◽  
Lithium Ion ◽  
Molar Ratio ◽  
Ion Adsorption ◽  
Solid State Method ◽  
Adsorption Time ◽  
Adsorption Performance ◽  
Structure Morphology

Spinel structure Li1+xMn2-xO4 materials for lithium ion-sieve precursor were synthesized by high temperature solid state method and their adsorption properties were improved by adjusting the molar ratio of lithium to manganese. The structure, morphology and adsorption performance of the synthetic samples were characterized by XRD, SEM, and lithium ion adsorption experiments. The influences of pH value and adsorption time on adsorption capacity were discussed. The results showed that the Li1.3Mn1.7O4 material had the largest adsorption capacity and it reached up to 24.06 mg·g-1 when the pH value was 12 and the adsorption time was 10 h.

scholarly journals KEMAMPUAN ADSORBEN LIMBAH LATEKS KARET ALAM TERHADAP MINYAK PELUMAS DALAM AIR

2012 ◽  
Vol 1 (2) ◽  
pp. 34-38
Author(s):  
Edward Tandy ◽  
Ismail Fahmi Hasibuan ◽  
Hamidah Harahap
Keyword(s):  
Natural Rubber ◽  
Adsorption Capacity ◽  
Natural Rubber Latex ◽  
Equation Model ◽  
Adsorption Model ◽  
Rubber Latex ◽  
Adsorption Ability ◽  
Isotherm Equation ◽  
Lubricant Oil ◽  
Langmuir Isotherm Equation

Natural rubber latex waste usually throw away to be unused materials and caused environment issue. One of the ways to handle this environment issue by using natural rubber latex waste as oil adsorbent. Natural rubber latex waste also had oleophilic and hydrophobic properties that are suitable to being used as oil adsorbent. In this research, researchers found out adsorption capacity of natural rubber latex waste to oil and oil from water, also the characteristics of it’s adsorption with Langmuir and Freundlich isoterm adsorption model. The adsorption characteristics of lubricant oil from water with natural rubber latex waste more fitted well with Langmuir isotherm equation model and the maximum adsorption ability of lubricant oil from water with natural rubber latex waste also significantly increased with the contact time till reached the equilibrium. The results of this study concluded that natural rubber latex waste had a great adsorption capacity and suitabled for being used as oil adsorbent.

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